Pd−Ir core-shell nanoparticles

Materials

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366Pd−Ir core-shell nanoparticles3.3–13.0nmTEMPd−Ir nanoparticles with four different sizes (3.3, 5.9, 9.8 and 13.0 nm), but identical shapes and surface structures, were designed and synthesized.atalytic activity of individual Pd−Ir NPs increases as particle size increases. Area-specific catalytic activity is similar for Pd−Ir NPs of 3.3–9.8 nm, but is slightly decreased when particle size reached to 13.0 nm.

Kinetics

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Applications

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366Pd−Ir core-shell nanoparticlesThis work not only demonstrates the size effect, but also provides an effective strategy to enhance the performance of nanozymes in certain applications.10- 2000pg/mL8.2, 4.6, and 3.7pg/mLthe limit of detection (LOD, which was defined by the 3SD method33) for the ELISAs were lowered from 9.3, to 8.2, 4.6, and 3.7 pg/mL when the size of Pd−Ir NPs was reduced from 13.0 to 9.8, 5.9, and 3.3 nm, respectively.
366Pd−Ir core-shell nanoparticlesThis work not only demonstrates the size effect, but also provides an effective strategy to enhance the performance of nanozymes in certain applications.10- 2000pg/mL8.2, 4.6, and 3.7pg/mL

References

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366Size Effect in Pd− Ir Core‐Shell Nanoparticles as Nanozymeshttps://doi.org/10.1002/cbic.202000147MetalPd−Ir core-shell nanoparticles