Coupling Two Sequential Biocatalysts with Close Proximity into Metal–Organic Frameworks for Enhanced Cascade Catalysis

References

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DOI
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235Coupling Two Sequential Biocatalysts with Close Proximity into Metal–Organic Frameworks for Enhanced Cascade Catalysishttps://doi.org/10.1021/acsami.0c04317CompositeGOx&PVI-hemin@ZIF-8 composite

Materials

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size
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BET
b nanozyme
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specific act
sa 10n
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235GOx&PVI-Hemin@ZIF-8270nmTEMThe TEM image in Figure 1d displays a typical GOx&PVI-hemin@ZIF-8 particle with a diameter of ca. 270 nm.Compared to pure ZIF-8, the GOx&PVI-hemin@ ZIF-8 composite shows an obvious decrement of the Brunauer−Emmett−Teller surface areas, attributed to the encapsulation of nonporous GOx&PVI-hemin.

Kinetics

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substrate
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kcat
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kcat 10n
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kcat/km
kcat/km 10n
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235GOx&PVI-Hemin@ZIF-8PODH2O26.037235

Applications

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method
linear range
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235GOx&PVI-Hemin@ZIF-8enhanced cascade catalysis to detect glucoseglucoseColor0-200μM0.4μM