| 7343 |
12 |
CeO2@ZIF-8 NPs |
275 |
|
nm |
TEM |
the average |
651.2260 |
|
|
|
|
|
|
|
| 7369 |
56 |
MOF-546(Fe) |
|
|
|
SEM |
a length of about 1–2 μm and a diameter of about 0.5–1 μm |
|
|
|
μmol/min |
6 |
-2 |
μmol glucose/(mg GOx·min) |
|
| 7401 |
98 |
Tb-OBBA-Hemin |
200-1500 |
|
nm |
SEM |
As shown in Figure 1a, the as-prepared Tb-OBBA-Hemin has spherical particles with a size of 200 nm to 1.5 μm |
21.38 |
|
|
|
|
|
|
|
| 7403 |
103 |
CeO2NRs-MOF |
120 |
|
nm |
TEM |
the length of the prepared CeO2NRs is about 120 nm |
|
|
|
|
|
|
|
|
| 7404 |
105 |
AU-1 |
|
|
|
|
|
|
|
|
|
|
|
|
|
| 7406 |
108 |
HP-MIL-88B-BA |
|
|
|
|
|
|
|
|
|
|
|
|
|
| 7411 |
113 |
PB |
|
|
|
|
|
|
|
|
|
|
|
|
|
| 7416 |
119 |
ZIF-67 |
400 |
|
nm |
SEM |
|
1833.26 m2/g |
|
|
|
|
|
|
|
| 7429 |
137 |
Zr-MOF |
60 |
|
nm |
SEM |
As demonstrated by Fig. 1C, the synthesized Zr-MOF presents a uniform spherical morphology, and the diameter is ∼60 nm. |
217.5 |
|
|
|
|
|
|
|
| 7441 |
151 |
Hf-DBP-Fe |
82.1 |
2.1 |
nm |
DLS |
Dynamic light scattering (DLS) showed similar number-averaged sizes of 82.1 ± 2.1 for Hf-DBP-Fe and 81.6 ± 3.6 nm for Hf-DBP (Fig. 2d). |
|
|
|
|
|
|
|
|
| 7456 |
164 |
PBNPs in TiNM |
|
|
|
SEM |
the TiNM was composed of parallel nanochannels, and these nanochannels have conical shape with an average diameter of a large base entrance of -200 nm and small tip entrance of -50 nm |
|
|
|
|
|
|
|
|
| 7460 |
168 |
MIL-101(Fe) |
500 |
|
nm |
SEM |
SEM images showed that MIL-101(Fe) had the well-defined octahedral morphology with an average diagonal length of approximately 500 nm |
2702.9 |
|
|
|
|
|
|
|
| 7469 |
179 |
PMOF（Fe） |
300 |
|
nm |
SEM |
The low-magnification SEM images revealed that PMOF(Fe) was of uniform ellipsoidal shape with an average diameter of 300 nm (Figure 1A). TEM images in Figure 1B further show the morphology and size of PMOF(Fe), which was consistent with the result of SEM. After modifying the Pt NPs on the surface of PMOF(Fe), Pt@PMOF(Fe) kept the morphology of PMOF(Fe) (Figure 1C) and with a lot of Pt NPs. The size of Pt NPs is around 2 nm (Figure 1D, inset). These Pt NPs were modified on the surface of PMOF(Fe) uniformly. |
|
|
|
|
|
|
|
|
| 7504 |
224 |
oxidized UiO-66(Ce/Zr) |
|
|
|
|
|
|
|
|
|
|
|
|
Correspondingly, the strong adsorption of Pi onto oxidized UiO-66(Ce/Zr) decreases the specific surface area and pore size of the latter |
| 7509 |
231 |
HKUST-1 |
85 |
|
nm |
TEM |
And the obtained HKUST-1 with blue color shows a regular sphere morphology with the average particle size of ∼85 nm in TEM imaging (Figure 1a) and a larger value of 140 nm in the DLS dispersed in water (Figure 1b). |
|
|
|
|
|
|
|
|
| 7556 |
313 |
Fe-Loaded MOF-545(Fe) |
3.7 |
|
nm |
SEM |
The SEM results showed that the crystal (Fe-loaded MOF-545(Fe)) exhibited a rod-like morphology in size (3.7 nm) with hexagonal edge, which was the same as the published results |
2368 |
|
|
|
|
|
|
|
| 7557 |
314 |
Fe-MOF |
500-700 |
|
nm |
SEM |
FE-SEM images in Fig. S1A&B show that Fe-MOFs (Fig. S1A) and Zr-MOFs (Fig. S1B) are in octahedral crystal shape with around 500–700 nm and 100–300 nm diameter, respectively, while Cu-MOFs (Fig. S1C) is in spherical shape with a size of 400–700 nm diameter. |
|
|
|
|
|
|
|
|
| 7558 |
316 |
Fe-MIL-88B |
270 |
|
nm |
TEM |
MIL-88 with an average diameter of 270 nm was synthesized by the hydrothermal method |
13.40 m2 ·g−1. |
|
|
|
|
|
|
|
| 7571 |
331 |
Fe-MOFs |
100 |
|
nm |
TEM |
Diameter |
|
|
|
|
|
|
|
|
| 7572 |
331 |
Fe-MOFs |
185 |
|
nm |
TEM |
length |
|
|
|
|
|
|
|
|
| 7585 |
345 |
MIL-53 (Fe) |
less than 250 nm |
|
nm |
SEM |
|
|
|
|
|
|
|
|
|
| 7586 |
346 |
MoS2/rGO |
5 |
|
μm |
SEM |
thickness |
|
|
|
|
|
|
|
|
| 7592 |
350 |
AuNP@Fe-TCPP-MOF |
1.1 |
|
μm |
SEM |
|
|
|
|
|
|
|
|
|
| 7648 |
414 |
PBA NCs |
60 |
|
nm |
TEM |
|
60.12 |
|
|
|
|
|
|
|
| 7651 |
419 |
Hollow MnFeO oxide |
|
|
|
|
|
241.291 |
|
|
|
|
|
|
|
| 7698 |
464 |
FePorMOFs |
150 |
|
nm |
SEM |
The SEM image showed the as prepared FePorMOFs were uniform in a rod-like structure with a 600 nm length and 150 nm width (Figure 3B). |
|
|
|
|
|
|
|
|
| 7703 |
470 |
Tα-MOF |
65 |
|
nm |
TEM |
These results are consistent with the data obtained from TEM image. Homogeneous size distribution and an average size of 65 nm observed in Fig. 2b. |
|
|
|
|
|
|
|
|
| 7775 |
546 |
NH2-MIL-101(Fe) |
|
|
|
|
|
|
|
|
|
12 |
|
|
|
| 7776 |
546 |
MIL-101(Fe) |
600-800 |
|
nm |
TEM |
|
|
|
|
|
5 |
|
|
|
| 7777 |
546 |
NO2-MIL-101(Fe) |
|
|
|
|
|
|
|
|
|
36 |
|
|
|
| 7786 |
556 |
UiO-66 |
200-300 |
|
nm |
SEM |
Figure 3. Scanning electron microscopy (SEM) images of the as-synthesized UiO-66 MOFs (particle size is around 200−300 nm for all the samples). |
861 |
|
|
|
|
|
|
|
| 7805 |
577 |
Zn-TCPP(Fe) |
|
|
|
TEM |
And the TEM image in Figure S1b clearly reveals the 2D Zn-TCPP(Fe) MOF with well-defined ultrathin sheet-like structures. |
|
|
|
|
|
|
|
|
| 7831 |
605 |
Ce-MOF |
|
|
|
|
|
|
|
|
|
|
|
|
|
| 7837 |
613 |
NH2-MIL-53(Fe) |
300-500 |
|
nm |
SEM |
The average size is approximately 300–500 nm |
|
|
|
|
|
|
|
|
| 7850 |
628 |
MIL-100 |
60 |
|
nm |
SEM |
|
538.2 |
|
|
|
|
|
|
|
| 7855 |
635 |
NEQC-340 |
70-200 |
|
nm |
TEM |
112 |
|
|
|
|
|
|
|
|
| 7904 |
690 |
Cu2+-NMOFs |
350 |
|
nm |
SEM |
The Cu2+-NMOFs are in a good crystal morphology with a uniform size of around 350 nm |
|
|
|
|
|
|
|
|
| 7929 |
719 |
Fe-BTC |
|
|
|
SEM |
The size of Fe-BTC was about 2.6 μm × 2.1 μm (length × width |
|
|
|
|
|
|
|
|
| 7930 |
719 |
Fe-BTC |
77 |
|
nm |
AFM |
AFM characterization shows that the average thickness of the 2D Fe-BTC nanosheets was about 77 nm |
|
|
|
|
|
|
|
|
| 7936 |
726 |
NH2-MIL-88B(Fe)-Ag |
~300 |
|
nm |
SEM |
As shown in Figure 1B, the SEM revealed that NH2-MIL-88B(Fe)-Ag was produced with the morphology of fusiform and length of ∼300 nm, identical to that of NH2- MIL-88B(Fe) in Figure 1A. |
|
|
|
|
|
|
|
|
| 7982 |
776 |
Ti8-Cu2 |
|
|
μm |
SEM |
Transmission electron microscopy (TEM) and scanning electron microscope (SEM) indicated that Ti8-Cu2 maintained the disk-like morphology of Ti8-OH of ∼1 μm in diameter and ∼0.4 μm in thickness |
1245 |
|
|
|
|
|
|
|
| 8025 |
825 |
Cu-hemin-MOF |
6 |
|
μm |
SEM |
As shown in Fig. 2a, Cu-hemin-MOF presents 3D ball-flower shape with the dimension of about 6 μm. |
|
|
|
|
|
|
|
|
| 8046 |
850 |
PCN-222(Mn) |
|
|
|
|
|
2217 |
|
|
|
|
|
|
|
| 8059 |
864 |
2D Cu-TCPP nanofilm |
|
|
μm |
TEM, SEM |
|
|
|
|
|
|
|
|
|
| 8066 |
871 |
Cu-MOF |
|
|
|
TEM, SEM |
The morphology of prepared Cu-MOF NPs was characterized by TEMand SEManalysis. As displayed in Fig. 2a, b, the Cu- MOF NPs have a spherical shape with uniform particle distribution. |
|
|
|
|
|
|
|
|
| 8072 |
877 |
ZIF-67/Cu0.76Co2.24O4 NSs |
100 to 250 |
|
nm |
TEM |
SEM and TEM images are shown in Figure 1B,C with the size range of about 100−250 nm |
|
|
|
|
|
|
|
|
| 8091 |
899 |
hemin@UiO-66-NH2 |
100―190 |
|
nm |
TEM |
Fig.2 SEM(A, B) and TEM images(C, D) of UiO-66- NH2(A, C) and hemin@UiO-66-NH2(B, D) |
|
|
|
|
|
|
|
|
| 8107 |
915 |
UiO-66(Fe/Zr)-NH2 |
2.0-3.0 |
|
μm |
SEM |
|
|
|
|
|
|
|
|
|
| 8110 |
918 |
Prussian blue (PB) |
|
|
|
|
|
|
|
|
|
|
|
|
|
| 8122 |
1059 |
MAF-5-CoII NS |
|
|
|
|
|
1155 |
|
|
|
|
|
|
|
| 8151 |
1084 |
CuMnFe-ATP |
5-10 |
|
nm |
TEM |
The specific surface area and pore-size distribution of CuMnFe-ATP were calculated based on nitrogen adsorption–desorption results. As Fig. 3C shows, the CuMnFe-ATP NPs exhibited a type IV isotherm, which possessed significant hysteresis at the range of 0.4–1.0 P/P0. The surface area was calculated as 37.31 m2 g− 1 , according to the Brunauer-EmmettTeller model. The large surface area may be induced by the collapse of the CuMnFe-ATP NP structures after drying in vacuum. From Fig. 3D, although the pore-size distribution of CuMnFe-ATP NPs was majorly in the range of 5–10 nm, some pore sizes were about 27.5 nm. The generation of larger pores suggests the collapse of the CuFeMn-ATP NPs. Also, the SEM micrograph indicates the existence of large pores in the CuMnFe-ATP NPs, which also proves the structure collapse. |
37.31 |
|
|
|
|
|
|
|
| 8168 |
1106 |
UCZN |
120 |
|
nm |
SEM |
The SEM (Figure 1(b)) and TEM (Figure 1(c, d)) imagesdemonstrated that UCZN exhibited a uniform size of ap-proximately 120 nm |
|
|
|
|
|
|
|
|
| 8184 |
1121 |
CPMP |
330 |
|
nm |
TEM |
It can be seen from Figure S3, Supporting Information, that 9.5% CPMP had an average particle size of about 330 nm with good dispersity (the polydispersity index of 9.5% CPMP in water and phosphate buffer solution [PBS], as well as cell medium is 0.221, 0.213, and 0.116, respectively), which is suitable for biological applications and can achieve good therapeutic results. |
|
|
|
|
|
|
|
|
| 8185 |
1122 |
V-POD-M |
1.43 |
|
nm |
TEM |
To simplify the calculation model, we first create a penetration simulation model using the cytomembrane surrounded by H2O molecules and nanostructures with a flat surface (size: 12.53 nm ×12.53 nm) and epitaxial nanotubes-based spiky surface (diameter: 1.43 nm), respectively. |
|
|
|
|
|
|
|
|
| 8192 |
1133 |
NH2-MIL-101(Fe) |
1 |
|
μm |
SEM |
the prepared NH2-MIL-101(Fe) has a relatively uniform spindle-shaped shape with a length of several micrometers and a width of about 1 μm |
|
|
|
|
|
|
|
|
| 8204 |
1157 |
MOF-199 |
110 |
|
nm |
TEM |
the average diameter was approximately 110 nm with a narrow size distribution and highly crystalline morphology. |
1674.3 |
|
|
|
|
|
|
|
| 8223 |
1179 |
CeOx@fMIL |
112 |
|
nm |
DLS |
After coating with MIL, the dynamic light scattering (DLS) of CeOx indicated an increase in the mean hydrodynamic diameter particle size from 17 to 112 nm. |
|
|
|
|
|
|
|
|
| 8224 |
1182 |
Az@MOF |
|
|
|
|
Scanning electron microscopy (SEM) imaging indicated the extremely homogeneous morphology with a length of 200 nm and a width of 75 nm (Fig. 1a). Furthermore, transmission electron microscopy (TEM) images of Mn-MOFs in Fig. 1b directly displayed a pore size of 1.25 nm, which is in accordance with the result of N2 adsorption–desorption (1.25 nm) in Fig. S7.† The pore size of 1.25 nm permitted the encapsulation and release of AcManNAz (MW = 430). |
|
|
|
|
|
|
|
|
| 8228 |
1187 |
Ag-PBA |
225 |
25 |
nm |
SEM |
Scanning electron microscopy (SEM) images (Fig. 2) of Ag-PBAs and PBAs showed essentially the same cubic morphology, with a diameter of 200–250 nm, confirming the successful synthesis of Ag-PBA nanoparticles that retained a cubic crystalline structure and a similar size to PBA. |
|
|
|
|
|
|
|
|
| 8236 |
1203 |
Cu-MOGs |
|
|
|
|
|
|
|
|
|
|
|
|
|
| 8253 |
1229 |
MIL-53(Fe) |
|
|
|
|
|
|
|
|
|
|
|
|
|
| 8276 |
1261 |
GOx@Fe-ZIF-8 |
91-633 |
|
|
SEM |
The scanning electron microscopy (SEM) images (Figure S3A) showed that when the ratio was between 1:0.25 and 1:2, the Fe-ZIF-8 nanoparticles all grew into a typical ZIF-8-like rhombohedron dodecahedron morphology with the average particle size from 91 to 633 nm (Figure S3B) |
|
|
|
|
|
|
|
|
| 8278 |
1263 |
USPBNPs |
3.4 |
|
nm |
TEM |
Transmission electron microscopy (TEM) image (Figure 1a) shows that when the ethanol concentration was 75% in volume, USPBNPs with sizes of about 3.4 nm were obtained (Figure 1b) |
|
|
|
|
466 |
|
U/mg |
|
| 8299 |
1289 |
GOx@CuBDC |
221 |
|
nm |
SEM |
Average |
|
|
|
|
|
|
|
|
| 8331 |
1324 |
PBBA |
45 |
|
nm |
SEM |
|
|
|
|
|
|
|
|
|
| 8336 |
1328 |
Fe-MIL-88NH2 nanozyme |
1~2 |
|
μm |
SEM |
length |
|
|
|
|
|
|
|
|
| 8337 |
1328 |
Fe-MIL-88NH2 nanozyme |
0.1~3 |
|
μm |
SEM |
width |
|
|
|
|
|
|
|
|
| 8341 |
1334 |
MIL-101(Fe)@Fe3O4 |
243 |
|
nm |
TEM |
the nanoparticles are spherical with a diameter of ~ 243 nm. The shell thickness of the MOF layer was approximately 25 nm. |
726.8 |
|
|
|
|
|
|
|
| 8342 |
1334 |
Fe3O4 |
|
|
|
|
|
25.8 |
|
|
|
|
|
|
|
| 8343 |
1336 |
Eu-pydc |
1~2 |
|
μm |
SEM |
the MOF shows regular particles with a size of about 1–2 μm which depended on the regulation of the new method |
|
|
|
|
|
|
|
|
| 8350 |
1346 |
Cu-MOF |
90 |
10 |
nm |
TEM |
Uniform octahedral crystalline structures with average particle sizes about 80–100 nm were observed according to the SEM and TEM images. |
|
|
|
|
|
|
|
|
| 8351 |
1346 |
Cu-MOF |
90 |
10 |
nm |
SEM |
Uniform octahedral crystalline structures with average particle sizes about 80–100 nm were observed according to the SEM and TEM images. |
|
|
|
|
|
|
|
|
| 8418 |
1408 |
Cu-MOF(3) |
220 |
|
nm |
DLS |
hydrodynamic diameter |
|
|
|
|
|
|
|
|
| 8437 |
1432 |
MIL-53(Fe) |
1 |
|
μm |
SEM |
The average |
|
|
|
|
|
|
|
|
| 8453 |
1454 |
MIL-47(V)-X |
|
|
|
TEM, SEM |
As shown in Figure S2 with different magnifications, the synthesized MOF particles are discrete with different sizes of 20–1000 nm. |
|
|
|
|
|
|
|
|