CeO2

Materials

ref material size size err size unit size type size comment BET b nanozyme b 10n b unit specific act sa 10n sa unit comment
7779 548 CeO2 7.8 0.2 nm TEM
7819 593 CeO2 TEM The resulting CeO2 nanozymes obtained by a simple solvothermal protocol are in highly morphological uniformity and dispersity (Fig. 1a and S1a) with an average size of 31.1 ±3.9 nm (Fig. 1c). The STEM image (Fig. 1b) shows a flower-like morphology assembled by tiny nanoparticles with an average size of 6.1 ± 1.6 nm.
7872 656 CeO2 3~4 nm XRD The synthesized CeO2 were uniform in size and the estimated average diameter was between 3 and 4 nm. The small and uniform particle size provides a larger specific surface area and more active sites, leading to superior enhanced performance in electrochemical detection.
7983 777 CeO2 SEM Hollow CeO2 microspheres were shown to range in size from 1 to 3 µm, with the outer shell composed of smaller CeO2 particles of 20 nm average size (Figure 1). 28.0
7985 778 CeO2 92.04 nm DLS The Fig. 2I showed that the average size of CeO2, CeO2@APTES and CeO2@Ce6 was respectively 92.04 nm, 100.37 nm and 124.48 nm.
8156 1090 CeO2 2、10 nm TEM TEM images (Figure S1) reveal the presence of well-defined nearly monodisperse nanoparticles with average sizes of 2 and 10 nm, respectively.
8172 1108 CeO2 5 nm TEM All around 5 nm as determined from high-resolution transmission electron microscopy (HRTEM) and dynamic light scattering (DLS) (Figure 1a–e).
8177 1112 CeO2 SEM As presented in Fig. 1a, the as-prepared CeO2 shows rod-like and porous characteristics with a diameter of ~7 nm and a length of 40~70 nm. 82.5
8251 1227 CeO2 5 nm TEM CeO2 nanoparticles were around 5 nm in size
8264 1245 CeO2 80-200 nm TEM The particle size distributions and potentials of the nanovesicles are presented in Figure 2I,J, respectively. The DLS analysis indicated that the nanovesicles ranged between 80 and 200 nm in size
8381 1370 CeO2 3-5 nm TEM 73.9
8419 1409 CeO2 44625 nm TEM Average size

Kinetics

ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment
6090 196 CeO2 OXD 3,5-DTBC 8.0 1262 μM 0.182 μM/s 6.28 -4 1/s 196 M-1 s-1 196
6101 203 CeO2 POD H2O2 20.13 mM 203 As shown in Figure 4A–C, when H2O2 was used as the substrate, the Km value of Au@CD, CeO2, and the mixture of Au@CD and CeO2 were 100.01, 20.13, and 800.34 mM, respectively.
6475 593 CeO2 POD TMB 0.07 mM 0.10 -6 M/s 593 593
6537 656 CeO2 hydrolase 656
6905 993 CeO2 POD H2O2 4 14.9 mM 74.4 -8 M/s 993
6910 993 CeO2 POD 993
7081 1115 CeO2 POD H2O2 4.5 RT 2.5 mM 4.56 -8 M/s 1115 1115
7082 1115 CeO2 POD H2O2 7.4 RT 0.5 mM 2.9 -8 M/s 1115 1115
7165 1227 CeO2 OXD TMB 1227
7181 1245 CeO2 CAT H2O2 1245

Applications

ref material application target method linear range linear ran unit LOD lod unit recovery comment
5584 656 CeO2 pesticide detection. Methyl-paraoxon E-chem 0.1-100 and 0.1-10 μM/L 0.06 μM/L What's more, the oxidation peak current increased linearly with MP concentration in the ranges of 0.1–10 μmol/L and 10–100 μmol/L, with correlation coefficients (R2) higher than 0.99 for both two analytical curves (n=3, Fig. 6B).
5703 777 CeO2 catalytic degradation of p-nitrophenol p-nitrophenol Color HMS showed a maximum p-NP degradation rate of 76.5% at a CeO2 dosage of 40 mg, 2 h reactive time, at 30°C and pH of 4.8 when the concentration of p-NP was 20 mg L−1.
5900 993 CeO2 Measurement of HX HX Color 50-800 μM 15 μM
6015 1108 CeO2 Boosted Oxidative Catalytic Activity
6022 1115 CeO2 Melamine Detection Melamine Color 0.004-1.56 nM 4 pM
6105 1227 CeO2 Immunoassay for fenitrothion Fenitrothion Color 7.1-177.4 ng/mL 2.1 ng/mL
6117 1245 CeO2 Antitumor
6224 1370 CeO2 protein carriers
6259 1409 CeO2 Anticancer therapy

References

ref title DOI material type comment
3735 548 Polymer-Coated Cerium Oxide Nanoparticles as Oxidoreductase-like Catalysts https://doi.org/10.1021/acsami.0c08778 Metal oxide CeO2
4295 1108 CeO2 Nanoparticle Transformation to Nanorods and Nanoflowers in Acids with Boosted Oxidative Catalytic Activity https://doi.org/10.1021/acsanm.0c03387 Metal oxide CeO2 Nanoparticle
4566 1409 Dual-path modulation of hydrogen peroxide to ameliorate hypoxia for enhancing photodynamic/starvation synergistic therapy https://doi.org/10.1039/d0tb01556c Metal oxide Cerium oxide nanoparticles
4412 1227 Effect of proteins on the oxidase-like activity of CeO2 nanozymes for immunoassays https://doi.org/10.1039/d0an01755h Metal oxide CeO2
4429 1245 In Vivo Regenerable Cerium Oxide Nanozyme-Loaded pH/H2O2-Responsive Nanovesicle for Tumor-Targeted Photothermal and Photodynamic Therapies https://doi.org/10.1021/acsami.0c19074 Metal oxide CeO2
4299 1112 Porous CeO2 nanorods loaded with indocyanine green for enhanced tumor-specific therapy https://doi.org/10.1016/j.micromeso.2021.110905 Metal oxide porous CeO2 nanorods loaded with indocyanine green (ICG)
4277 1090 Mechanism and Dynamics of Fast Redox Cycling in Cerium Oxide Nanoparticles at High Oxidant Concentration https://doi.org/10.1021/acs.jpcc.1c00382 Metal oxide Ceria nanocrystals (nanoceria)
3842 656 Electrochemical detection of methyl-paraoxon based on bifunctional nanozyme with catalytic activity and signal amplification effect https://doi.org/10.1016/j.jpha.2020.09.002 Metal oxide A new electrochemical sensor for organophosphate pesticide (methyl-paraoxon) detection based on bifunctional cerium oxide (CeO2) nanozyme is here reported for the first time. Methyl-paraoxon was degraded into p-nitrophenol by using CeO2 with phosphatase mimicking activity.
3780 593 Synergistic effects between polyvinylpyrrolidone and oxygen vacancies on improving the oxidase-mimetic activity of flower-like CeO 2 nanozymes https://doi.org/10.1039/d0nr04177g Metal oxide polyvinylpyrrolidone (PVP)-capped CeO2 nanoflowers
3963 777 Synthesis of CeO2 hollow microspheres with oxidase-like activity and their application in the catalytic degradation of p-nitrophenol https://doi.org/10.1080/09593330.2019.1624835 Metal oxide CeO2
4532 1370 Catalytic performance of ceria fibers with phosphatase-like activity and their application as protein carriers https://doi.org/10.1016/j.apt.2020.05.016 Metal oxide ceria fibers
3964 778 A versatile nanocomposite based on nanoceria for antibacterial enhancement and protection from aPDT-aggravated inflammation via modulation of macrophage polarization https://doi.org/10.1016/j.biomaterials.2020.120614 Metal oxide coating red light-excited photosensitizer chlorin e6 (Ce6) onto nanoceria