Portable Hg2+ Nanosensor with ppt Level Sensitivity Using Nanozyme as the Recognition Unit, Enrichment Carrier, and Signal Amplifier

References

ref title DOI material type comment
3579 391 Portable Hg2+ Nanosensor with ppt Level Sensitivity Using Nanozyme as the Recognition Unit, Enrichment Carrier, and Signal Amplifier https://doi.org/10.1021/acsami.0c00210 Sulfide CuS hollow nanospheres (HNSs)

Materials

ref material size size err size unit size type size comment BET b nanozyme b 10n b unit specific act sa 10n sa unit comment
7628 391 CuS HNSs. 200 nm TEM

Kinetics

ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment

Applications

ref material application target method linear range linear ran unit LOD lod unit recovery comment
5301 391 CuS HNSs. a portable and cost-effective Hg2+ nanosensor has been developed based on a desorption-free enrichmentdetection integration strategy. The core of the nanosensor is the employment of CuS HNSs, which play three roles including recognition unit for Hg2+ sensing, enrichment carrier for Hg2+ preconcentration, and mimetic peroxidase for signal amplification and readout. The customizable enrichmentdetection integration strategy gives the nanosensor a high selectivity, a wide detection range (50 ppt to 400 ppb), and a high sensitivity with a minimum detectable Hg2+ concentration of 50 ppt. In addition, the as-developed nanosensor is feasible for analysis of Hg2+ in real-world environmental and food samples with moderate accuracy (deviation <10%) and reproducibility (recovery ∼82%). Hg2+ Color 0.05 ppb 82