Hammett Relationship in Oxidase‐Mimicking Metal–Organic Frameworks Revealed through a Protein‐Engineering‐Inspired Strategy

References

ref title DOI material type comment
4414 1229 Hammett Relationship in Oxidase‐Mimicking Metal–Organic Frameworks Revealed through a Protein‐Engineering‐Inspired Strategy https://doi.org/10.1002/adma.202005024 MOF MIL-53(Fe)

Materials

ref material size size err size unit size type size comment BET b nanozyme b 10n b unit specific act sa 10n sa unit comment
8253 1229 MIL-53(Fe)

Kinetics

ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment
7173 1229 MIL-53(Fe)-NO2 OXD TMB 0.56 mM 42.3 -8 M/s 1229
7172 1229 MIL-53(Fe)-Br OXD TMB 2 mM 33.3 -8 M/s 1229
7171 1229 MIL-53(Fe)-Cl OXD TMB 1.4 mM 35.7 -8 M/s 1229
7170 1229 MIL-53(Fe)-F OXD TMB 0.69 mM 27.7 -8 M/s 1229
7169 1229 MIL-53(Fe)-OH OXD TMB 0.48 mM 9.3 -8 M/s 1229
7168 1229 MIL-53(Fe)-H OXD TMB 0.5 mM 3.1 -8 M/s 1229
7167 1229 MIL-53(Fe)-CH3 OXD TMB 1.3 mM 4.0 -8 M/s 1229
7166 1229 MIL-53(Fe)-NH2 OXD TMB 0.02 mM 1.8 -8 M/s 1229

Applications

ref material application target method linear range linear ran unit LOD lod unit recovery comment