Cobalt tuned copper sulfide on montmorillonite: Peroxidase-like activity, catalytic mechanism and colorimetric sensing of hydrogen peroxide

References

ref title DOI material type comment
3551 358 Cobalt tuned copper sulfide on montmorillonite: Peroxidase-like activity, catalytic mechanism and colorimetric sensing of hydrogen peroxide https://doi.org/10.1016/j.colsurfa.2020.125063 Composite Co-doped CuS-Montmorillonite (Co/CuS-MMT)

Materials

ref material size size err size unit size type size comment BET b nanozyme b 10n b unit specific act sa 10n sa unit comment
7596 358 50Co/CuS-MMT 100 nm It can be found that the porous hollow spheres of 50Co/CuS-MMT with ca. 100 nm are composed of even smaller nanoparticles with the size of ca. 2 nm.

Kinetics

ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment
6239 358 50Co/CuS-MMT POD H2O2 3.422 mM 7.054 -8 M/s 358 358
6238 358 50Co/CuS-MMT POD TMB 0.077 mM 10.373 -8 M/s 358

Applications

ref material application target method linear range linear ran unit LOD lod unit recovery comment
5262 358 50Co/CuS-MMT detection of H2O2 residue in contact lens solution H2O2 Color 10-100 μM 2.2 μM Fig. 6B displays that the absorbance at 652 nm was linearly correlated with H2O2 concentration from 10 to 100 μM and the limit of detection (LOD) was calculated to be 2.2 μM (LOD = 3 s/k, where s, k are the relative standard deviation of eight parallel controlled measurements and the slope of the linear calibration plots, respectively. In this formula, s = 0.000157, k = 2.14 × 10−4, and therefore, LOD =2.2 μM).
5261 358 50Co/CuS-MMT detection of H2O2 residue in contact lens solution H2O2 Color 10-100 μM 2.2 μM