Intrinsic peroxidase-like activity of graphene nanoribbons for label-free colorimetric detection of dopamine

References

ref title DOI material type comment
3855 669 Intrinsic peroxidase-like activity of graphene nanoribbons for label-free colorimetric detection of dopamine https://doi.org/10.1016/j.msec.2020.111034 Carbon Graphene nanoribbons (GNR) with intrinsic peroxidase mimic activity were introduced as a nanozyme with catalytic activity in oxidation of a typical chromogenic peroxidase substrate, 3,3′,5,5′-tetramethylbenzidine (TMB), in the presence of H2O2.

Materials

ref material size size err size unit size type size comment BET b nanozyme b 10n b unit specific act sa 10n sa unit comment
7886 669 GNR 32 nm TEM Also, Fig. S1 shows another TEM image of GNR which can also demonstrate the yield of MWCNT unzipping and GNR production. The FESEM images of MWCNT and GNR are shown in Fig. 2c and d, respectively. According to Fig. 2c, the average size of the synthesized GNR was found to be about 32 nm. 410

Kinetics

ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment
6556 669 GNR POD H2O2 4.0 35 3.52 mM 3.09 -8 M/s 669
6555 669 GNR POD TMB 4.0 35 0.42 mM 1.58 -8 M/s 669

Applications

ref material application target method linear range linear ran unit LOD lod unit recovery comment
5599 669 GNR detection of dopamine DA Color 0.1–1, 2.5–50 μM 0.035 μM 90-110%