Electrochemical detection of methyl-paraoxon based on bifunctional nanozyme with catalytic activity and signal amplification effect

References

ref title DOI material type comment
3842 656 Electrochemical detection of methyl-paraoxon based on bifunctional nanozyme with catalytic activity and signal amplification effect https://doi.org/10.1016/j.jpha.2020.09.002 Metal oxide A new electrochemical sensor for organophosphate pesticide (methyl-paraoxon) detection based on bifunctional cerium oxide (CeO2) nanozyme is here reported for the first time. Methyl-paraoxon was degraded into p-nitrophenol by using CeO2 with phosphatase mimicking activity.

Materials

ref material size size err size unit size type size comment BET b nanozyme b 10n b unit specific act sa 10n sa unit comment
7872 656 CeO2 3~4 nm XRD The synthesized CeO2 were uniform in size and the estimated average diameter was between 3 and 4 nm. The small and uniform particle size provides a larger specific surface area and more active sites, leading to superior enhanced performance in electrochemical detection.

Kinetics

ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment
6537 656 CeO2 hydrolase 656

Applications

ref material application target method linear range linear ran unit LOD lod unit recovery comment
5584 656 CeO2 pesticide detection. Methyl-paraoxon E-chem 0.1-100 and 0.1-10 μM/L 0.06 μM/L What's more, the oxidation peak current increased linearly with MP concentration in the ranges of 0.1–10 μmol/L and 10–100 μmol/L, with correlation coefficients (R2) higher than 0.99 for both two analytical curves (n=3, Fig. 6B).