Protection and Isolation of Bioorthogonal Metal Catalysts by Using Monolayer‐Coated Nanozymes

References

ref title DOI material type comment
3621 433 Protection and Isolation of Bioorthogonal Metal Catalysts by Using Monolayer‐Coated Nanozymes https://doi.org/10.1002/cbic.202000207 Composite biorthogonal transition metal catalysts (TMCs) in biological environments by using self-assembled monolayers on gold nanoparticles (AuNPs)

Materials

ref material size size err size unit size type size comment BET b nanozyme b 10n b unit specific act sa 10n sa unit comment
7664 433 AuNP−TTMA 2 nm TEM
7663 433 AuNP−TTMA nm The diameter of the overall particle is ∼7 nm in water with 2 nm core which is verified by DLS and TEM measurements respectively and is not affected by the encapsulation of the TMCs (Figure 2, experimental details in the Supporting Information).

Kinetics

ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment

Applications

ref material application target method linear range linear ran unit LOD lod unit recovery comment
5343 433 AuNP−TTMA protection of biorthogonal transition metal catalysts
5342 433 AuNP−TTMA protection of biorthogonal transition metal catalysts We demonstrate here the protection of biorthogonal transition metal catalysts (TMCs) in biological environments by using self-assembled monolayers on gold nanoparticles (AuNPs).