Rational Construction of an Artificial Binuclear Copper Monooxygenase in a Metal–Organic Framework

References

ref title DOI material type comment
3962 776 Rational Construction of an Artificial Binuclear Copper Monooxygenase in a Metal–Organic Framework https://doi.org/10.1021/jacs.0c11920 MOF MOF-based artificial binuclear monooxygenase Ti8-Cu2

Materials

ref material size size err size unit size type size comment BET b nanozyme b 10n b unit specific act sa 10n sa unit comment
7982 776 Ti8-Cu2 μm SEM Transmission electron microscopy (TEM) and scanning electron microscope (SEM) indicated that Ti8-Cu2 maintained the disk-like morphology of Ti8-OH of ∼1 μm in diameter and ∼0.4 μm in thickness 1245

Kinetics

ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment

Applications

ref material application target method linear range linear ran unit LOD lod unit recovery comment
5702 776 Ti8-Cu2 This work highlights the potential of MOFs in the construction of robust artificial enzymes with uniform and precise active sites and high catalytic activities.