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Materials
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    • Enzyme-like Activity
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    • Oxidase
    ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment
    5905 21 Fe-N/C OXD TMB, ABTS and OPD 3.5 37 0.94 mM 5.98 -7 M/s 21 21
    5932 40 g-C3N4 OXD TMB 0.31 mM 14.49 -8 M/s 40 40
    5961 63 C-CoNi-HNC OXD TMB 0.428 mM 0.621 -8 M/s 63 63
    5963 63 C-Co-HNC OXD TMB 0.35 mM 0.483 -8 M/s 63 63
    5962 63 C-CoZn-HNC OXD TMB 0.891 mM 0.537 -8 M/s 63 63
    5960 63 C-CoMn-HNC OXD TMB 0.205 mM 0.69 -8 M/s 63 63
    5969 73 vanadium oxide nanodots (VOxNDs) OXD TMB 3.5 35 0.3022 mM 0.0562 -7 M/s 73 73
    5981 84 Co-V MMO nanowires OXD TMB 0.444 mM 9.5 -8 M/s 84 84
    5991 103 CeO2NRs-MOF OXD TMB 107.6 μM 5.862 -1 μM/min 103 103
    6001 119 ZIF-67 OXD TMB 22 μM 412 nM/s 119
    6002 119 ZIF-67 OXD AR (Amplex red) 5.28 μM 28.2 nM/s 119
    6009 134 CTF–1 OXD luminol 10 8.25 -5 M 6.06 4 ICL·s−1 134
    6022 147 laccase OXD OPD 0.17 0.001 mM 0.028 0.0015 μM/min 147
    6023 147 Fe3O4@Cu/GMP OXD OPD 3.02 0.02 mM 0.12 0.003 μM/min 147 147
    6025 149 NiO OXD 149 149
    6045 160 Fe-N-C-400 OXD TMB RT 0.269 mM 0.338 μM/s 160 160
    6046 160 Fe-N-C-850 OXD TMB RT 0.23 mM 0.133 μM/s 160 160
    6060 171 HS-PtNPs OXD TMB 0.01012 mM 171 171
    6062 173 MoO3 NPs OXD ABTS 1.6769 mM 173
    6093 196 Pt NPs OXD 3,5-DTBC 8.0 1811 μM 4.71 μM/s 0.0184 1/s 196 M-1 s-1 catechol oxidase
    6090 196 CeO2 OXD 3,5-DTBC 8.0 1262 μM 0.182 μM/s 6.28 -4 1/s 196 M-1 s-1 196
    6091 196 MOF-818 OXD 3,5-DTBC 8.0 810 μM 3.17 μM/s 0.383 1/s 196 M-1 s-1 catechol oxidase
    6092 196 MOF-818 OXD L-dopa 8.0 480 μM 0.080 μM/s 0.0096 1/s 196 M-1 s-1 catechol oxidase
    6100 203 Au@CD NPs OXD DAB 42 mM 203 the GOx-like activity of Au@CD was first investigated by using DAB as the chromogenic substrates and an absorbance at 460 nm as the quantitative referenced wavelength. As shown in Figure S5, the Michaelis–Menten constant (Km) for the Au@CD NPs was 42 mM, which was distinctly higher than that of glucose oxidase (about 4.87 mM).
    6104 208 AgNPs OXD ABTS 7.2 μM 2.89 μM/min 208 208
    6107 211 Cu2O-CDs-Cu (Dark) OXD OPD 11.95 mM 4.72 μM/min 211
    6108 211 Cu2O (Light) OXD OPD 1.69 mM 2.07 μM/min 211 211
    6109 211 Cu2O-CDs-Cu (Light) OXD OPD 3.94 mM 9.47 μM/min 211 211
    6120 222 Hg2+/heparin–OsNPs OXD TMB 0.176 mM 1.52 -7 M/s 222 222
    6121 222 Hg2+/heparin–OsNPs OXD TMB 0.8 mM 8.45 -8 M/s 222 Hg2+ 0μM
    6122 222 Hg2+/heparin–OsNPs OXD TMB 0.051 mM 3.28 -7 M/s 222 Hg2+ 40μM
    6124 224 oxidized UiO-66(Ce/Zr) OXD TMB 4.0 RT 224
    6134 257 TiO2/C-QDs OXD TMB 5 25 0.158 mM 2.5 -8 M/s 6.04 1/s 257 257
    6135 260 PtNPs OXD TMB 0.062 mM 11.44 -8 M/s 260 260
    6141 269 CMS NPs OXD Ascorbic acid 12.06 μM 0.11 μM/s 269
    6151 271 Co3O4 nanoflowers OXD TMB 0.0469 mM 0.0459 μM/s 271 271
    6165 283 Cit-IrNPs OXD TMB 3.86 RT 0.287 mM 0.587 -6 M/s 283
    6170 288 MGCN-chitin-AcOH OXD glucose 4.54 mM 4.67 -6 M/s 288
    6173 291 CuCo2O4 nanorods OXD TMB 0.032 mM 0.217 μM/s 291 291
    6176 293 FeNZ OXD 293 293
    6188 305 Cu-NC OXD TMB 0.223 mM 0.0302 μM/s 305 305
    6196 314 Fe-MOF OXD TMB 314
    6215 325 CoOOH NFs OXD 325
    6257 377 A-PCM OXD 377
    6262 379 EPC-900 OXD TMB 0.106 mM 5.1 -8 mM/s 379 379
    6266 382 MnO2-Silk film OXD TMB 1.62 0.664 mM 160 0.031 μM/min 382
    6271 388 COF-300-AR OXD TMB 0.088 mM 3.38 -8 M/s 388
    6276 395 Gold-Mesoporous Silica Heteronanostructures OXD Glucose 7.4 37 55.2 mM 0.018 mM/s 395 395
    6281 405 Ag3PO4 NPs OXD TMB 0.15 mM 405
    6283 413 MoS2-QDs-AgNPs OXD TMB 390 μM 7 -6 M/s 413
    6293 419 core–shell Mn/Fe PBA@Mn/Fe PBA OXD TMB 0.04 mM 419
    6308 456 Nanocages OXD Dopamine 9.82 μM 3.67 -8 M/s 456
    6316 462 CuO NPs OXD AA 0.1302 mM 9.9 -4 mM/s 26.98 1/s 462 ascorbate oxidase (AAO) mimic
    6315 462 AAO OXD AA 0.084 mM 6.5 -4 mM/s 363.13 1/s 462
    6323 465 Pt NC/3D GF nanohybrid OXD TMB 0.089 mM 2.74 -7 M/s 465
    6328 469 V2O5 nanobelts OXD glucose 7.0 37 3.02 mM 18.114 -8 M/s 469 469
    6354 498 SPDA OXD TMB 6.35 mM 498 498
    6361 501 Cu-HCF SSNEs OXD H2O2 71.9 8.2 mM 17.2 0.5 -3 mM/s 501 SSNEs pretreated with GSH (denoted as SSNEs-G)
    6362 501 Cu-HCF SSNEs OXD GSH 0.09 0.05 mM 25.7 0.8 -3 mM/s 501 501
    6372 506 Fe–N4 pero-nanozysome OXD TMB 4.5 37 0.55 mM 45.27 nM/s 506 In addition, pero-nanozysome also possessed higher catalytic efficiency than that of N-nanozyme (Figure 3e and Table S6, Supporting Information).
    6376 510 Mn3O4 nanoparticles (NPs) c OXD TMB 3.0 30 0.08 mM 48.17 -8 M/s 4.41 1/s 510 510
    6378 512 NiCo2O4-Au composite OXD TMB 4.0 37 7.528 0.286 -5 mM 34.537 2.545 M/s 512 The oxidase-like catalytic activities of NiCo2O4-Au composite and NiCo2O4 were also studied by similar enzyme kinetics models and methods, and the results are shown in Fig. S9, S10, and Table S1.
    6384 521 Fe3O4 OXD Ce6+ 4.0 RT 0.114 mM 521 521
    6386 523 CeO2 NPs OXD TMB 523 523
    6395 530 HCS@Pt NPs OXD TMB 4.5 15 0.352 mM 0.8243 -8 M/s 530 530
    6401 534 Ag@Ag2WO4 NRs OXD TMB 4.0 25 0.026 mM 6.83 -6 M/s 534 534
    6407 538 iron alkoxide OXD TMB 0.12 mM 2.11 -8 M/s 538 538
    6447 569 Au NPs OXD 569 569
    6455 575 BP QDs OXD TMB 575 575
    6461 579 MnO2 OXD TMB 3.45 μM 16.80 -6 M/s 579 579
    6479 596 GOx@Pd@ZIF-8 OXD 596 596
    6481 598 CeO2 NPs OXD glucose 5.93 mM 0.59 -6 M/s 10.09 1/s 598 598
    6502 617 LM OXD 2,4-DP 0.15 mM 8.26 -3 mM/min 3.06 4 1/min 617 M-1 min-1 617
    6508 623 thiamine-MnO2 OXD ATCh 623 623
    6509 624 AMP-Cu OXD 2,4-dichlorophenol 0.09 mM 1.30 μM/min 624 624
    6520 636 MWCNT@MoS2 NS's OXD 5-Nitroguaiacol 10.59 μM 636 636
    6524 640 Pd12 nanocage OXD TMB 0.24 mM 7.084 -8 M/s 640 640
    6527 645 styrene, 4-styryldi( pentafluorophenyl)borane and 4-styryl-dimesitylphosphine OXD Acetophenones 645 645
    6528 646 Co(OH)2 OXD TMB 0.362 mM 6.06 M/s 646 646
    6531 648 Au/OMCS OXD Xanthine 20.65 μM 6.84 μM/s 648 648
    6540 659 Mn/Ni(OH)x LDHs OXD TMB 3.6 RT 0.19 mM 63.77 -8 M/s 659
    6574 679 R-MnCo2O4 OXD TMB 0.14 mM 14 -8 M/s 679
    6585 695 Pt OXD TMB 0.102 mM 330 nM/s 695
    6588 701 Hep-Pd NPs OXD TMB 0.178 mM 701
    6628 722 PtNPs@MWCNTs OXD BNAH 0.452 mM 0.066 1/s 722
    6627 722 PtNPs@MWCNTs OXD NADH 0.14 mM 0.021 1/s 722
    6635 732 Mn0.98Co0.02O2 OXD UA 22.34 μM 0.00892 μM/min 732
    6651 742 PFO Pdots OXD TMB 0.106 mM 1.497 -5 mM/s 6.84485 6 1/s 742 10 M-1 s-1
    6658 747 2D Co3O4@Rh NC OXD TMB 0.018 mM 6.45 -8 M/s 747
    6659 749 OV-Mn3O4 NFs OXD TMB 1.66 mM 3.97 -8 M/s 749 -8 μM-1 s-1
    6660 749 Mn3O4 NFs OXD TMB 13.2 mM 1.35 -8 M/s 749 -8 μM-1 s-1
    6661 750 Ag2S@GO OXD TMB 0.1 mM 3.94 -8 M/s 750
    6667 754 CMP-Pt/EG OXD epinephrine. 0.042 mM 18.97 μM/min 754
    6668 757 BSA-Cu complex OXD guaiacol 0.159 mM 0.004 mM/min 2.66 1/min 757
    6686 784 AuPt@SF (APS) OXD glucose 45.795 µg/mL 0.125 μM/s 784
    6693 793 g-C3N4/hemin/Au OXD H2O2 0.76 mM 793
    6694 795 Fe–N/C OXD TMB 0.205 mM 5.411 -7 M/s 5.411 -4 1/s 795
    6695 795 Fe–N/C OXD OPD 0.676 mM 1.06 -6 M/s 3.533 -4 1/s 795
    6696 795 Fe–N/C OXD ABTS 0.118 mM 3.44 -7 M/s 3.822 -4 1/s 795
    6712 807 AuNPs OXD Glucose 24.6 mM 57.4 -8 M/s 807
    6749 858 ZnCd QDs OXD 37 858
    6772 873 H-GNs OXD TMB 873
    6767 873 H-GNs OXD H2O2 1.25 mM 16.7 -8 M/s 873
    6774 875 DMSN-Au NP OXD 6.8 0.13 mM 3.97 μM/min 22.4 3 1/s 875
    6775 876 Co4S3/Co(OH)2 HNTs OXD TMB 4.0 1.33 mM 4.66 -7 M/s 0.01991 1/s 876
    6776 877 ZIF-67/Cu0.76Co2.24O4 NSs OXD GSH 0.484 mM 877
    6781 881 FePOs OXD TMB 0.72 0.25 mM 0.85 0.19 mM/min 881
    6770 882 o-CDs OXD TMB 882
    6777 884 NL-MnCaO2 OXD H2O2 0.549 mM 884
    6782 884 NL-MnCaO2 OXD OPD 50.99 38.3 mM 0.49 0.31 mM/min 884
    6792 884 NL-MnCaO2 OXD TMB 0.087 mM 97.83 -8 M/s 884
    6799 890 ML-MoOx OXD K3[Fe (CN)6] 32.5 0.2 mM 58.61 μM/min 890
    6806 901 DHPC@CS-AgNPs OXD TMB 0.0165 mM 4.6512 -8 M/s 901
    6827 925 AuNPs OXD TMB 925
    6839 935 CeO2 NPs OXD 935
    6840 936 Co3O4/NF OXD 400 936
    6843 939 MNPs OXD 939
    6863 961 Au NC's Oxidase Thiamine 7.4 RT 961
    6872 970 phosphorene@Ti3C2-MXene Oxidase NAA 4.0 0.11 μM 20.79 μ A (Imax) 970
    6874 972 BSA@Au NPs OXD Glucose 972
    6879 976 FeN5 SAs OXD Na2S2O4 4.2 -5 M 976
    6882 978 Au NPs OXD Glucose 978
    6891 985 CDs@γ-/α-Fe2O3 OXD TMB 0.488 mM 3.39 μM/s 985
    6925 1003 V4O7 OXD catechol 4.2 25 6.03 mM 1.89 μM/min 5.80 -3 1/s 1003
    6922 1006 V4O7 OXD TMB 0.39 mM 1.11 -7 M/s 1006
    6927 1006 V4O7 OXD quercetin 4.2 25 0.08 mM 232.6 μM/min 1.95 -1 1/s 1006
    6947 1013 GNF OXD catechol 6.8 RT 1.84 0.37 mM 5.40 0.39 μM/min 7.06 10 1/min 1013
    6948 1014 CTNs OXD 2,4-DP and 4-AP 6.5 25 1.2 mM 1014
    6953 1020 CeO2/Tb2+ OXD H2O2 5.3 mM 13.2 nM/s 7.7 1/min 1020
    6952 1020 CeO2-x OXD H2O2 6.5 mM 16.2 nM/s 9.5 1/min 1020
    6956 1023 MnOOH nanotubes OXD TMB 1 mM 20 μM/min 1023
    6960 1030 Se@PDA@Bor OXD TMB 2.914 μM 1.894 -8 M/s 1030
    6965 1030 Se@PDA@Bor OXD salicylic acid + FeSO4 + H2O2 37 1030
    6970 1041 OH-Co3O4 OXD GSH 0.66 mM 0.98 μM/min 8.34 4 1/s 1041 8 M-1 s-1
    6984 1041 Mn3O4 NPs OXD Polyphenol 1.14 mM 1041
    6989 1046 Au/Ni-Fe LDH/rGO OXD TMB 1046
    6980 1046 NC OXD H2O2 281 mM 5.27 -7 M/s 7.46 4 1/s 1046
    6985 1046 NC OXD Polyphenol 0.84 mM 1046
    6992 1048 CuCo(O)@PCNs OXD H2O2 1048
    7012 1060 LSG OXD XT 81.35 μM 1060 原文数据即有两个小数点，存疑
    7009 1060 LSG OXD HX 58.52 μM 1060 1060
    7010 1060 LSG OXD XT 72.49 μM 1060 1060
    7011 1060 LSG OXD HX 66.84 μM 1060 1060
    7067 1098 Au NCs（300） OXD nitrobenzene 4.1 0.5 mM 0.3 0.02 mM/min 1 0.1 1/min 1098 0.05 1098
    7065 1098 Au NCs（90） OXD nitrobenzene 6 1.2 mM 0.15 0.02 mM/min 0.52 0.07 1/min 1098 0.029 1098
    7066 1098 Au NCs（965） OXD nitrobenzene 3.4 0.6 mM 0.69 0.09 mM/min 2.4 0.3 1/min 1098 0.21 1098
    7072 1107 Mn/PSAE OXD TMB 6 25 0.11 mM 7 -8 M/s 1107 1107
    7077 1108 CeO2-nanorods OXD ABTS 1 RT 0.17 mM 11.24μM/s 1108 1108
    7074 1108 CeO2-nanorods OXD ABTS 4 RT 0.29 mM 0.48μM/s 1108 1108
    7075 1108 CeO2-nanoparticles OXD ABTS 1 RT 0.87 mM 1.03μM/s 1108 1108
    7076 1108 CeO2-nanoparticles OXD ABTS 4 RT 1.61 mM 0.20μM/s 1108 1108
    7078 1109 Fe/NPC OXD TMB 3.5 45 0.59 mM 1.274 -7 M/s 1109 1109
    7134 1180 Heme-AuNPs OXD TMB 0.168 mM 1.68 -8 M/s 1180
    7145 1197 CoOOH NSs OXD TMB 64.37 μM 0.005 μM/min 1197
    7160 1219 MnO2 NSs–TMB OXD TMB 4.0 37 1219
    7165 1227 CeO2 OXD TMB 1227
    7170 1229 MIL-53(Fe)-F OXD TMB 0.69 mM 27.7 -8 M/s 1229
    7166 1229 MIL-53(Fe)-NH2 OXD TMB 0.02 mM 1.8 -8 M/s 1229
    7167 1229 MIL-53(Fe)-CH3 OXD TMB 1.3 mM 4.0 -8 M/s 1229
    7168 1229 MIL-53(Fe)-H OXD TMB 0.5 mM 3.1 -8 M/s 1229
    7169 1229 MIL-53(Fe)-OH OXD TMB 0.48 mM 9.3 -8 M/s 1229
    7171 1229 MIL-53(Fe)-Cl OXD TMB 1.4 mM 35.7 -8 M/s 1229
    7172 1229 MIL-53(Fe)-Br OXD TMB 2 mM 33.3 -8 M/s 1229
    7173 1229 MIL-53(Fe)-NO2 OXD TMB 0.56 mM 42.3 -8 M/s 1229
    7177 1241 Au@NH2-MIL-125(Ti) OXD TMB 0.03 mM 13.56 -8 M/s 1241
    7196 1274 IrO2/MnO2 OXD TMB 8.98 -3 mM 1274 1274
    7206 1287 GNE-based Au NPs OXD Glucose 0.089 mM 0.133 μM/s 1287 1287
    7210 1295 RSPCO OXD OPD 0.064 mM 49.3 -8 M/s 1295 1295
    7213 1295 RSPCO OXD H2O2 22 mM 46.9 -8 M/s 1295 1295
    7221 1309 Au NPs@G QDs OXD Quercetin 1309 1309
    7250 1332 CSF-900 OXD TMB 7.13 -1 mM 9.54 -9 M/s 1332 1332
    7264 1353 CoSe2 hollow microspheres OXD TMB 0.47 mM 17 -8 M/s 1353 1353
    7266 1355 Au−PtNCs-GMP OXD ABTS 0.1321 mM 17.98 -8 M/s 1355 1355
    7265 1355 Au–PtNCs-GMP OXD TMB 6.805 mM 253.8 -8 M/s 1355 1355
    7269 1357 SA-PtNPs OXD TMB 0.012 mM 9.145 -8 M/s 1357 1357
    7280 1368 Ag3PO4 OXD TMB 0.136 mM 8.93 -7 M/s 1368 1368
    7281 1368 Ag3PO4 with Hg2+ OXD TMB 0.075 mM 3.27 -6 M/s 1368 1368
    7285 1371 RF Resin OXD glucose 4.35 mM 1371 1371
    7304 1392 MnxCo1-xO OXD TMB 0.0187 mM 7.62 -8 M/s 1392 1392
    7310 1401 PEI/ZIF-FMN OXD NADH 27.6 μM 2.9 1/min 1401
    7330 1412 BP QDs OXD TMB 1412
    7332 1416 AuNPs@PMo12 OXD TMB 1.57 mM 2.2 -3 mM/s 1416
    7344 1429 MnO2 OXD TMB 0.781 mM 0.668 -6 M/s 1429
    7364 1449 PBA NCs OXD 1449
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