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    ref material enzyme type substrate pH T km km err km 10n km unit vmax vmax err vmax 10n vmax unit kcat kcat err kcat 10n kcat unit kcat/km kcat/km 10n kcat/km unit comment
    5918 32 Au2Pt POD H2O2 5.045 mM 14.11 -8 M/s 32 32
    5917 32 Au2Pt POD TMB 0.05378 mM 18.405 -8 M/s 32 32
    5928 39 Rh CAT H2O2 62.3 mM 6.8 μM/min 33.9 1/min 39 39
    5929 39 Au@Rh CAT H2O2 480.3 mM 98.0 μM/min 490.2 1/min 39 39
    5930 39 Au@Pt CAT H2O2 509.9 mM 72.5 μM/min 362.3 1/min 39 39
    6040 158 AgPd@BSA/DOX 158 158
    6041 159 Au@Pt POD H2O2 4.076 -3 mM 6.013 -8 M/s 2.004 3 1/s 159 The apparent Km values for Au@Pt nanozyme were about 80e600 times smaller than that ofHRP, which indicated that the affinity between TMB/H2O2 and Au@Pt nanozyme was stronger than that between HRP and TMB/H2O2. Moreover, the Kcat values for Au@Pt nanozyme were about 80e340 times higher than that of HRP, which indicated that the catalytic efficiency of Au@Pt nanozyme was stronger than that of HRP
    6042 159 HRP POD H2O2 1.468 mM 22.88 -8 M/s 18.3 1/s 159
    6043 159 Au@Pt POD TMB 2.431 -3 mM 4.425 -8 M/s 1.475 3 1/s 159
    6044 159 HRP POD TMB 0.3296 mM 7.638 -8 M/s 5.894 1/s 159
    6069 178 Au1Pd5 NCs POD TMB 0.086 mM 6.48 -8 M/s 178
    6070 178 Au1Pd5 NCs POD H2O2 160 mM 8.72 -8 M/s 178
    6130 232 AuPtRu POD o-phenylenediamine 232 232
    6131 234 CdCo2O4 POD H2O2 0.325 mM 3.75 -8 M/s 234 234
    6132 234 CdCo2O4 POD TMB 0.317 mM 2.19 -8 M/s 234 234
    6193 312 PtRu NPs multi-functionalities TMB 312
    6268 385 Au@Pt nanoparticles POD 385
    6313 461 PdCuAu NPs POD TMB 0.54 mM 1.7 -7 M/s 3.09 4 1/s 461
    6314 461 PdCuAu NPs POD H2O2 0.16 mM 1.2 -7 M/s 2.18 4 1/s 461 461
    6404 536 Cu/Au/Pt TNs POD H2O2 and TMB 5 536 536
    6429 554 Pd@Au nanostructures POD H2O2 0.022 mM 0.847 -8 M/s 554 554
    6430 554 Pd@Au nanostructures POD TMB 0.152 mM 9.64 -8 M/s 554 554
    6437 560 Mesoporous Pd@Pt POD TMB+H2O2 560 560
    6442 565 Au–Ag@HA NPs POD 565 565
    6506 621 Au@Pt POD 621 621
    6515 629 DNA-Au/Pt NCs POD TMB 1.56 mM 4 -8 M/s 629 629
    6521 637 Magnetite@cellulose NCs POD ABTS 637 637
    6654 744 GNRs POD H2O2 3.98 mM 4.96 -9 M/s 2.15 2 1/s 744 light off
    6652 744 Pt-GNRs POD H2O2 6.73 mM 7.73 -9 M/s 3.34 2 1/s 744 light off
    6653 744 Pt-GNRs POD H2O2 14.43 mM 1.89 -8 M/s 8.21 2 1/s 744 light on
    6655 744 GNRs POD H2O2 9.28 mM 8.59 -9 M/s 3.73 2 1/s 744 light on
    6662 752 Au@Pt POD H2O2 5.75 mM 1.28 -6 M/s 752
    6669 758 Ag1Pd1 POD H2O2 25 0.147 M 3.35 μM/min 758
    6670 758 Ag1Pd1 POD TMB 25 0.32 mM 7.16 μM/min 758
    6699 798 PtPdCu TNAs POD H2O2 1 mM 13.91 μM/min 98.484 1/min 798
    6700 798 PtPdCu TNAs POD OPD 0.091 mM 4.518 μM/min 31.99 1/min 798
    6701 798 PtPdCu TNAs CAT H2O2 50.172 mM 57723 μM/min 408683 1/min 798
    6723 830 CA@PtNi hNS POD H2O2 4.0 RT 2.5 mM 38.68 -8 M/s 830
    6724 830 CA@PtNi hNS POD TMB 4.0 RT 0.18 mM 21.89 -8 M/s 830
    6842 938 PtPd NPs POD TMB+HRP 938
    6849 944 Au@PtRu nanorods POD TMB 0.7 mM 1.3 -6 M/s 3.4 5 1/s 944 5 mM-1 s-1
    6898 990 Pd1Cu1.7 NAFs POD TMB 0.377 mM 53.24 -8 M/s 990
    6897 991 PtRu ANPs POD H2O2 0.24 mM 5.01 -7 M/s 991
    6902 991 PtRu ANPs POD TMB 4 0.016 mM 4.43 -8 M/s 991
    6920 998 CS-nFs POD OPD 143.29 0.01 μM 1.0193 -6 M/s 84.95 0.02 1/s 998
    7103 1135 Ni–Pt NPs POD TMB 3.5 -2 M 2.6 -5 M/s 4.5 7 1/s 1135
    7116 1155 Au25 GPx 0.47 mM/min 1155
    7117 1155 Au24Cu1 GPx 0.34 mM/min 1155
    7118 1155 Au24Cd1 GPx 0.10 mM/min 1155
    7119 1155 Au25 CAT 0.074 mM/min 1155
    7120 1155 Au24Cu1 CAT 0.35 mM/min 1155
    7128 1166 Pt–Ir NCs POD H2O2 4.13 mM 2.6 -8 M/s 1166
    7129 1166 Pt–Ir NCs POD TMB 0.38 mM 3.4 -8 M/s 1166
    7154 1210 Cr/CeO2 POD TMB 0.08 0.009 mM 0.138 0.027 -6 M/s 1210
    7155 1210 Cr/CeO2 POD H2O2 0.867 0.073 mM 0.159 0.024 -6 M/s 1210
    7216 1303 Au@Pt NRs POD TMB 1303 1303
    7339 1424 MoS2-Au@Pt POD 1424
    7345 1430 Pd-Pt POD TMB 0.48 mM 0.71 -6 M/s 10*6 1/s 1430
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