7342 |
11 |
Fe–N-rGO |
|
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7343 |
12 |
CeO2@ZIF-8 NPs |
275 |
|
nm |
TEM |
the average |
651.2260 |
|
|
|
|
|
|
|
7344 |
14 |
CeONPs |
10 |
|
nm |
TEM |
|
88.6 |
|
|
|
|
|
|
|
7347 |
20 |
HMON-Au@Cu-TA |
64 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7349 |
23 |
Co3O4@Co-Fe oxide double-shelled nanocages (DSNCs) |
1250 |
|
nm |
SEM |
|
12.16 |
|
|
|
|
|
|
|
7350 |
24 |
core–shell–shell UCNPs |
29.8 |
2.2 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
7351 |
24 |
core–shell UMOFs@Au NPs |
81.6 |
|
nm |
TEM |
|
284.52 |
|
|
|
|
|
|
|
7353 |
29 |
PDA‐Pt‐CD@RuFc NPs |
290 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7358 |
38 |
Pt@PCN222-Mn |
200 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7360 |
40 |
MoS2/g-C3N4 HNs |
|
|
|
TEM and HRTEM |
the fringes are widely separated with the spacing of 0.323 nm are in agreement with the (002) plane of the g-C3N4 and the lattice spacing of 0.628 nm |
|
|
|
|
|
|
|
|
7361 |
42 |
Atv/PTP-TCeria NPs |
8.16 |
1.98 |
nm |
TEM |
the average sizes 8.16±1.98 nm |
|
|
|
|
|
|
U/mg |
|
7362 |
44 |
Sm-TCPP-Pt |
|
|
nm |
TEM |
nanoplate morphology (∼100 nm in diameter) and ultrathin thickness (<10 nm) |
|
|
|
|
|
|
|
|
7363 |
45 |
Au40/γ-CD-MOF |
∼264 |
|
nm |
Others |
γ-CD-MOF at ∼264 nm |
|
|
|
|
|
|
|
|
7364 |
47 |
CuTA |
|
|
nm |
TEM |
an average length and width of 140.5 and 36.9 nm |
|
|
|
|
|
|
|
|
7366 |
49 |
Lipo-OGzyme-AIE |
122.5 |
|
nm |
TEM |
the mean diameter increased from 96.8 nm of Lipo-AIE to 122.5 nm of the Lipo-OGzyme-AIE |
|
|
|
|
|
|
|
|
7367 |
52 |
EPL-coated MnO2 nanosheets (EM) |
~330.86 |
|
nm |
TEM |
the size of the MnO2 nanosheet was measured to be around 330.86 nm |
|
|
|
|
|
|
|
|
7369 |
56 |
MOF-546(Fe) |
|
|
|
SEM |
a length of about 1–2 μm and a diameter of about 0.5–1 μm |
|
|
|
μmol/min |
6 |
-2 |
μmol glucose/(mg GOx·min) |
|
7370 |
60 |
Cu2MoS4 (CMS)/Au |
106.57 |
|
nm |
DLS |
and the polymer dispersity index is 0.228 |
|
|
|
|
|
|
|
|
7371 |
61 |
Fe3O4-TiO2/rGO (FTG) |
9 |
0.2 |
nm |
TEM |
Fe3O4 and TiO2 |
|
|
|
|
|
|
|
|
7372 |
63 |
Co-based homobimetallic hollow nanocages |
700-1000 |
|
nm |
TEM |
Co based ZIFs |
|
|
|
|
|
|
|
|
7373 |
64 |
NCNTs@MoS2 |
40 |
|
nm |
TEM |
nanotubes are uniform with a shell thickness of about 40nm |
22.605 |
|
|
|
|
|
|
|
7374 |
65 |
CuO NFs@MP |
20-40 |
|
nm |
TEM |
the CuO NFs@MP clearly indicated the deposition of CuO NFs with an average size of 20–40 nm |
20.88 |
|
|
|
|
|
|
|
7376 |
68 |
Fe3O4@SiO2-NH2-Au@PdNPs |
<10 |
|
nm |
XRD |
The absorption spectrum of the AuNPs in Figure 1a-ii showed surface plasmon resonance (SPR) at 514 nm, and this is characteristic of small spherical nanoparticles with size less than 10 nm |
|
|
|
|
|
|
|
|
7377 |
71 |
Au/Co@HNCF |
|
|
|
|
|
|
|
|
|
|
|
|
|
7380 |
75 |
BDD|PB nanozymes |
|
|
|
SEM |
The average apparent doped-diamond grain size is between 50 and 500 nm |
|
|
|
|
|
|
|
|
7381 |
76 |
DNA-Ag/Pt NCs |
4 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7382 |
77 |
TPP-MoS2 QDs |
1.69 |
0.15 |
nm |
TEM |
the thicknesses |
|
|
|
|
|
|
|
|
7383 |
77 |
TPP-MoS2 QDs |
50 |
|
nm |
TEM |
the lateral diameters |
|
|
|
|
|
|
|
|
7387 |
84 |
Co-V MMO nanowires |
|
|
|
|
|
33.63 |
|
|
|
|
|
|
|
7388 |
85 |
Pt@P-MOF(Fe) |
500 |
|
nm |
SEM |
the ellipsoidal morphology with a uniform size of 500 nm |
|
|
|
|
|
|
|
|
7389 |
87 |
CeM |
|
|
|
|
|
|
|
|
|
7 |
2 |
U/mg |
|
7390 |
87 |
CeM |
|
|
|
|
|
|
|
|
|
7 |
4 |
U/mg |
|
7401 |
98 |
Tb-OBBA-Hemin |
200-1500 |
|
nm |
SEM |
As shown in Figure 1a, the as-prepared Tb-OBBA-Hemin has spherical particles with a size of 200 nm to 1.5 μm |
21.38 |
|
|
|
|
|
|
|
7403 |
103 |
CeO2NRs-MOF |
120 |
|
nm |
TEM |
the length of the prepared CeO2NRs is about 120 nm |
|
|
|
|
|
|
|
|
7404 |
105 |
AU-1 |
|
|
|
|
|
|
|
|
|
|
|
|
|
7405 |
106 |
IMSN-PEG-TI |
100 |
|
nm |
TEM |
The typical transmission electron microscopy (TEM) and scanning electron microscopy (SEM) images indicated the as-prepared IMSN exhibited a uniform spherical morphology with an average diameter of about100 nm, and the surface of IMSN became rough (Figure 1b,c). |
|
|
|
|
|
|
|
|
7406 |
108 |
HP-MIL-88B-BA |
|
|
|
|
|
|
|
|
|
|
|
|
|
7408 |
110 |
SnSe |
|
|
|
|
|
|
|
|
|
|
|
|
|
7409 |
111 |
F-BS NCs |
|
|
nm |
TEM |
BSA-capped Fe3O4@Bi2S3nanocatalysts (F-BSP NCs) dispersed well and stably in the DMEM medium (Figure S6) with an average hydrodynamic size of around 342 nm but with 396 nm in both water and PBS (Figure S7B). |
|
|
|
|
|
|
|
|
7411 |
113 |
PB |
|
|
|
|
|
|
|
|
|
|
|
|
|
7412 |
114 |
Pt-carbon nanozyme |
122 |
|
nm |
DLS |
The DLS analysis showed that the particle size of Pt-carbon nanozymes was approximately 122 nm. |
|
|
|
|
|
|
|
|
7413 |
115 |
CuO-C-dots |
|
|
|
TEM |
well-dispersed C-dots were of uniform (small spherical) shape with an average diameter of 2 nm |
|
|
|
|
|
|
|
|
7414 |
117 |
Au/Fe-MOF |
300 |
2.6 |
nm |
TEM |
average size of Fe-MOF is about 300 ± 2.6 nm. there are many uniformLy distributed small particles which are approximately 7 nm in diameter on the Fe-MOF surface after the reduction of HAuCl4. |
|
|
|
|
|
|
|
|
7415 |
118 |
Au@Au-aptamer |
12 |
|
nm |
DLS |
|
|
|
|
|
|
|
|
|
7416 |
119 |
ZIF-67 |
400 |
|
nm |
SEM |
|
1833.26 m2/g |
|
|
|
|
|
|
|
7417 |
120 |
Fe3O4-Au@Ag |
400 |
|
nm |
TEM |
The diameter of the AuNPs was about 2.7 nm. The particle size of Au@Ag NPs increased to about 8 nm.The Fe3O4 MNPs exhibited a spherical morphology with approximately 400 nm in diameter. |
|
|
|
|
|
|
|
|
7418 |
121 |
CeO2/C nanowires |
3-6 |
|
μm |
SEM |
the CeO2 NPs with mean size of about 6.83 nm are dispersed in the CeO2/C nanowire frameworks |
|
|
|
|
|
|
|
|
7421 |
124 |
PPy@MnO2-BSA |
15 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7422 |
125 |
Ag@Au core/shell TNPs |
|
|
|
|
gold shells of different thickness were deposited on the Ag TNPs by controlling the amount of HAuCl4 |
|
|
|
|
|
|
|
|
7423 |
126 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
7424 |
127 |
GOx-MnO2/HMME |
200 |
|
nm |
SEM |
the average pore diameter was about 3.85 nm |
50.34 m2/g |
|
|
|
|
|
|
|
7426 |
129 |
CoFe-LDH/CeO2 |
|
|
|
|
CeO2 NTs were composed of numerous nanoparticles with grain size of 10-30 nm. |
35.7 m2/g |
|
|
|
|
|
|
|
7427 |
130 |
Ru4PCVs |
25 |
15 |
μm |
DLS |
|
|
|
|
|
|
|
|
|
7429 |
137 |
Zr-MOF |
60 |
|
nm |
SEM |
As demonstrated by Fig. 1C, the synthesized Zr-MOF presents a uniform spherical morphology, and the diameter is ∼60 nm. |
217.5 |
|
|
|
|
|
|
|
7430 |
138 |
Ru@CeO2 YSNs |
78 |
|
nm |
DLS |
The hydrated particle size distribution indicates that the size of Ru@CeO2 YSNs were approximately 78 nm, |
81.3 |
|
|
|
|
|
|
|
7431 |
139 |
AuNFs/Fe3O4@ZIF-8-MoS2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
7432 |
140 |
Fe3+/AMP CPs |
100 |
|
nm |
TEM |
Under TEM an extended network structure composed of aggregated nanoparticles was observed (Fig. 1b), which should give a large surface area for reaction. The average feature size is about 100 nm (Fig. S1, Supporting Information). |
|
|
|
|
|
|
|
|
7433 |
141 |
CDAu |
|
|
|
|
|
|
|
|
|
|
|
|
|
7436 |
145 |
Ag/ZnMOF |
|
|
|
|
|
|
|
|
|
|
|
|
|
7437 |
147 |
Fe3O4@Cu/GMP |
>1 |
|
μm |
DLS |
Dynamic light scattering (DLS) (Helos-Sucell, Sympatec GmbH, Germany) showed that the average size of Cu/GMP and Fe3O4@Cu/GMP particles were over 1 μm, indicating agglomeration of Cu/GMP and Fe3O4@Cu/GMP, consistent with the above TEM data. |
|
|
|
|
|
|
|
|
7438 |
148 |
AgNP@CD |
30 |
|
nm |
AFM |
|
|
|
|
|
|
|
|
|
7441 |
151 |
Hf-DBP-Fe |
82.1 |
2.1 |
nm |
DLS |
Dynamic light scattering (DLS) showed similar number-averaged sizes of 82.1 ± 2.1 for Hf-DBP-Fe and 81.6 ± 3.6 nm for Hf-DBP (Fig. 2d). |
|
|
|
|
|
|
|
|
7442 |
154 |
GOD/hPB@gellan |
|
|
|
|
|
|
|
|
|
|
|
|
|
7445 |
156 |
Au@NH2-MIL-125(Ti) |
300 |
|
nm |
SEM |
thickness |
|
|
|
|
|
|
|
|
7446 |
156 |
Au@NH2-MIL-125(Ti) |
500 |
|
nm |
SEM |
diameter |
|
|
|
|
|
|
|
|
7444 |
156 |
Au@NH2-MIL-125(Ti) |
<5 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7448 |
157 |
Bi2S3@DMSN |
110.6 |
18.6 |
nm |
TEM |
length |
|
|
|
|
|
|
|
|
7447 |
157 |
PEG/Ce-Bi@DMSN |
3-4 |
|
nm |
TEM |
The TEM image of the CeO2 nanozymes presented in Figure 1d, shows that the CeO2 nanozymes were 3–4 nm in diameter and were suitable for loading into the large-pore channels of Bi2S3@ DMSN nanoparticles |
|
|
|
|
|
|
|
|
7449 |
157 |
Bi2S3@DMSN |
65.6 |
9.2 |
nm |
TEM |
width |
201.32 |
|
|
|
|
|
|
|
7454 |
161 |
CeO2/Mn3O4 Nanocrystals |
4 |
|
nm |
TEM |
Heterostructured CeO2/Mn3O4 nanocrystals were prepared by a seed-mediated growth process.[14] The seeds, 4 nm sized truncated octahedral CeO2 nanocrystals, predominantly enclosed by {100} and {111} (Figure 1a), were reacted with MnCl2 to yield the |
|
|
|
|
|
|
|
|
7455 |
162 |
Ir@MnFe2O4 NPs |
11.24 |
1.11 |
nm |
TEM |
The average sizes of the MnFe2O4 NPs and Ir@MnFe2O4 NPs were determined by manually counting to be 10.47 ± 0.99 nm and 11.24 ± 1.11 nm respectively |
|
|
|
|
|
|
|
|
7456 |
164 |
PBNPs in TiNM |
|
|
|
SEM |
the TiNM was composed of parallel nanochannels, and these nanochannels have conical shape with an average diameter of a large base entrance of -200 nm and small tip entrance of -50 nm |
|
|
|
|
|
|
|
|
7459 |
167 |
UsAuNPs/MOFs |
150 |
|
nm |
TEM |
The UsAuNPs/MOFs present uniform dispersion with an average size of around 150 nm (Figure S11, Supporting Information). |
|
|
|
|
|
|
|
|
7460 |
168 |
MIL-101(Fe) |
500 |
|
nm |
SEM |
SEM images showed that MIL-101(Fe) had the well-defined octahedral morphology with an average diagonal length of approximately 500 nm |
2702.9 |
|
|
|
|
|
|
|
7461 |
169 |
FeTPP assemblies within AuTTMA monolayer |
~2 |
|
nm |
Others |
In our previous studies, we incorporated hydrophobic TMCs into the monolayer of 2-nm gold nanoparticles (NPs),6,29–31 to generate nanozymes that were functional in complex biological environments |
|
|
|
|
|
|
|
|
7463 |
172 |
Fe3O4@PDA@BSA-Bi2S3 |
120, 125, and 123 |
|
nm |
DLS |
The DLS size of Fe3O4@PDA@BSA-Bi2S3 NPs were indicated as 120, 125, and 123 nm, respectively, and showed no detectable fluctuation during the 5 days storage |
|
|
|
|
|
|
|
|
7465 |
174 |
IrRu-GOx@PEG NPs |
43 |
|
nm |
TEM |
Therefore, we synthesized IrRu NPs with different ratio of Ir and Ru elements to obtain better enzyme-like catalytic activity. the TEM image showed Ir2Ru1 NPs, Ir4Ru1 NPs, and Ir8Ru1 NPs are uniformly dispersed black particles with an average particle size of ~2 nm (Fig. 1A and B) and ~3 nm (Figs. S1A and B), ~4 nm.As shown in TEM images, the IrRuGOx@PEG NPs obtained by PEG-coated IrRu NPs were spherical and the average particle size was ~43 nm |
|
|
|
|
|
|
|
|
7466 |
175 |
Fe3O4/CoFe-LDH |
320-350 |
|
nm |
TEM |
As displayed in Fig. 2a and b, Fe3O4 were well-separated lycheelike spherical structure with mean grain size of about 300 nm. Fig. 2c-e clearly show the core-shell structure where Fe3O4 microspheres were encapsulated in CoFe-LDH nanosheets. Since there were no obvious boundaries between the core and shell, we approximately estimated that the particle sizes of Fe3O4/CoFe-LDH were in the range of 320-350 nm |
44.5 |
|
|
|
|
|
|
|
7467 |
176 |
N-doped MoS2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
7469 |
179 |
PMOF(Fe) |
300 |
|
nm |
SEM |
The low-magnification SEM images revealed that PMOF(Fe) was of uniform ellipsoidal shape with an average diameter of 300 nm (Figure 1A). TEM images in Figure 1B further show the morphology and size of PMOF(Fe), which was consistent with the result of SEM. After modifying the Pt NPs on the surface of PMOF(Fe), Pt@PMOF(Fe) kept the morphology of PMOF(Fe) (Figure 1C) and with a lot of Pt NPs. The size of Pt NPs is around 2 nm (Figure 1D, inset). These Pt NPs were modified on the surface of PMOF(Fe) uniformly. |
|
|
|
|
|
|
|
|
7470 |
181 |
hemin@CD |
2.3 |
|
nm |
TEM |
High-resolution TEM image shows the lattice fringe of 0.21 nm corresponding to the (100) facet (inset of Fig. 1a) [27]. After hemin was modified on CDs, the average size of hemin@CDs is 2.3 nm (Fig. 1b), which suggests there have been no significant change in the average size of CDs after hemin molecule decoration. |
|
|
|
|
|
|
|
|
7472 |
183 |
GCE/MWCNTs-Av/RunNPs |
|
|
|
|
|
|
|
|
|
|
|
|
|
7473 |
184 |
GO–PtNPs |
6 |
|
nm |
TEM |
average size |
|
|
|
|
|
|
|
|
7474 |
184 |
GO–PtNPs |
|
|
nm |
TEM |
the TEM and STEM images of the formed GO/DNA–PtNPs showed sparsely distributed PtNPs with smaller size (1–2 nm) |
|
|
|
|
|
|
|
|
7475 |
186 |
mGPB |
~182 |
|
nm |
TEM |
After loading, the hydrodynamic size of the nanoparticles (162.2 nm) increased to ∼182.0 nm |
|
|
|
|
|
|
|
|
7476 |
189 |
CC-PdNPs |
2.4-2.7 |
|
nm |
TEM |
To determine a reliable size distribution, we carried out a statistical analysis by Gaussian fitting of 50 random nanoparticles according to TEM results and found that the diameters of PdNPs are mainly distributed in the 2.4–2.7 nm range with an average size of 2.68 nm |
|
|
|
|
|
|
|
|
7477 |
190 |
MNET |
216 |
|
nm |
TEM |
Meanwhile, the hydrodynamic dimension of Mn3O4 NPs was 25.5 ± 3 nm by DLS (Figure 1C). After Mn3O4 encapsulated, the average size of MNET increased from 186 to 216 nm |
|
|
|
|
|
|
|
|
7478 |
193 |
Cu-hNFs |
19 |
|
μm |
SEM |
Also, with SEM images, the diameter of Cu-NFs composed of nano-sized petals was measured as 19 µm. |
|
|
|
|
|
|
|
|
7479 |
194 |
aptamer-AuNPs |
18 |
|
nm |
DLS |
DLS is an effective method to measure the overall particle size distribution of nanomaterials. As can be seen from Fig. 3, the particle size of aptamer-AuNPs is about 18 nm with a small distribution range. |
|
|
|
|
|
|
|
|
7480 |
195 |
CDs@Cu4O3 |
|
|
|
|
|
|
|
|
|
|
|
|
|
7482 |
199 |
MoS2 |
100-200 |
|
nm |
TEM |
a layered structure with approximately average size (the longest part) of 100–200 nm and uniform edges. |
|
|
|
|
|
|
|
|
7483 |
199 |
M/H-D |
213.2 |
15.8 |
nm |
DLS |
After the modification of dextran, dynamic light scattering (DLS) measurements showed the average hydrous dynamic diameter of 70% of the M/H-D was ∼213.2 ± 15.8 nm (Figure S2). |
|
|
|
|
|
|
|
|
7484 |
199 |
HfO2 NPs |
2~5 |
|
nm |
TEM |
The size of HfO2 NPs (2–5 nm) anchored on the surface of MoS2 was smaller than the HfO2 NPs alone (10 nm), which could be attributed to the two different nucleation centers of HfO2 in the presence or absence of MoS2 NSs in the solution. |
|
|
|
|
|
|
|
|
7485 |
199 |
HfO2 NPs |
10 |
|
nm |
TEM |
The size of HfO2 NPs (2–5 nm) anchored on the surface of MoS2 was smaller than the HfO2 NPs alone (10 nm), which could be attributed to the two different nucleation centers of HfO2 in the presence or absence of MoS2 NSs in the solution. |
|
|
|
|
|
|
|
|
7488 |
202 |
Pt/EMT |
|
|
|
|
The EMT zeolite synthesized under mild conditions comprises a great number of uniform nanocrystals with slightly different morphology and average particle size of 15–20 nm (Fig. 2A and S2), in agreement with the result calculated by Scherrer Equation. Moreover, some highly-dispersed Pt NPs in size of 5–8 nm are confined within the zeolite (Fig. 2D) |
457 |
|
|
|
|
|
|
|
7489 |
203 |
Au nanoparticles (NPs) modified by cyclodextrin (Au@CD) |
20 |
|
nm |
|
As shown in Figure 2A, the Au@CD NPs showed good dispersity with a diameter around 20 nm. |
|
|
|
|
|
|
|
|
7494 |
210 |
AuNPs |
10 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7495 |
210 |
iron-based MOFs (IM) |
|
|
|
|
an average diameter and length around 60 and 400 nm respectively |
|
|
|
|
|
|
|
|
7497 |
215 |
hydrogel |
50-70 |
|
nm |
|
As shown in Fig. 1(a), the hydrogel appeared to be a network nanofiber with diameters of 50–70 nm. |
2.318 |
|
|
|
|
|
|
|
7499 |
217 |
IrO2 |
1.7 |
0.3 |
nm |
DLS |
The average size of IrO2 nanoparticles was 1.7 ± 0.3 nm by counting more than 200 nanoparticles. The monodisperse IrO2 nanoparticles on GO indicated that GO had effectively inhibited the aggregation of IrO2 nanoparticles. There were no unsupported IrO2 nanoparticles observed, which indicated that the GO was an excellent support. |
|
|
|
|
|
|
|
|
7500 |
221 |
VB2-IONzymes |
<200 |
|
nm |
SEM |
The naked IONzymes showed a spherical shape with a diameter of about 200 nm. VB2-IONzymes became smaller and developed a rough surfaceupon modification with a high amount of VB2. |
|
|
|
|
|
|
|
|
7502 |
222 |
Hg2+/heparin–OsNPs |
|
|
|
|
|
|
|
|
|
80.97 |
|
U/g |
TEM image of heparin–OsNPs. Inset: HRTEM image and the size distribution of heparin–OsNPs determined from the TEM image (from size distribution analysis of 50 random nanoparticles by Gaussian fitting). |
7501 |
222 |
Hg2+/heparin–OsNPs |
|
|
|
|
|
|
|
|
|
81 |
|
U/g |
|
7503 |
223 |
laccase@MMOFs |
<100 |
|
nm |
SEM |
The laccase@MMOFs found spherical in nature with an average particle size below 100 nm |
343.27 |
|
|
|
|
|
|
|
7504 |
224 |
oxidized UiO-66(Ce/Zr) |
|
|
|
|
|
|
|
|
|
|
|
|
Correspondingly, the strong adsorption of Pi onto oxidized UiO-66(Ce/Zr) decreases the specific surface area and pore size of the latter |
7507 |
229 |
lipase immobilized on Fe3O4/SiO2/Gr NC |
|
|
|
SEM |
The morphology and structure of the Fe3O4/SiO2/Gr NC were revealed through the SEM microphotographs. It reveals the SEM visual of the as-synthesized Fe3O4/SiO2 having a blockish like structure over Gr nanostructured sheet (Fig. 2). |
|
|
|
|
|
|
|
|
7508 |
230 |
HP-HIONs@PDA-PEG |
526.24 |
48.89 |
nm |
TEM |
The diameter of the HP-HIONs@PDA-PEG was 526.24 ± 48.89 nm, as determined by TEM, corresponding to the results of DLS experiments (Fig. S1A, 588 ± 140.23 nm). |
|
|
|
|
|
|
|
|
7509 |
231 |
HKUST-1 |
85 |
|
nm |
TEM |
And the obtained HKUST-1 with blue color shows a regular sphere morphology with the average particle size of ∼85 nm in TEM imaging (Figure 1a) and a larger value of 140 nm in the DLS dispersed in water (Figure 1b). |
|
|
|
|
|
|
|
|
7512 |
235 |
GOx&PVI-Hemin@ZIF-8 |
270 |
|
nm |
TEM |
The TEM image in Figure 1d displays a typical GOx&PVI-hemin@ZIF-8 particle with a diameter of ca. 270 nm. |
|
|
|
|
|
|
|
Compared to pure ZIF-8, the GOx&PVI-hemin@ ZIF-8 composite shows an obvious decrement of the Brunauer−Emmett−Teller surface areas, attributed to the encapsulation of nonporous GOx&PVI-hemin. |
7513 |
257 |
TiO2/C-QDs |
5.23 |
0.3 |
nm |
TEM |
The mean size was 5.23 nm, as calculated from 100 particlesin the TEM image. |
|
|
|
|
|
|
|
|
7514 |
258 |
RBIR |
3.5 |
|
nm |
TEM |
RBIR appeared as well-dispersed nanodots with an average diameter of 3.5 nm, |
|
|
|
|
|
|
|
|
7519 |
261 |
Co–Fe@hemin |
~80 |
|
nm |
|
the Co–Fe@hemin nanozymes resemble spherical particles, characterized by an average diameter of approx. 80 nm |
|
|
|
|
70 |
0 |
U/mg |
|
7518 |
261 |
Co–Fe@hemin |
~80 |
|
nm |
|
the Co–Fe@hemin nanozymes resemble spherical particles, characterized by an average diameter of approx. 80 nm |
|
|
|
|
69.915 |
0 |
U/mg |
|
7526 |
268 |
Fe3O4@Au MBs |
116 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7530 |
272 |
Pt-MOFs (PtMs) |
92.5 |
|
nm |
DLS |
|
810.88 |
|
|
|
|
|
|
|
7532 |
277 |
HIONCs |
327 |
80 |
nm |
DLS |
|
|
|
|
|
|
|
|
|
7535 |
288 |
MGCN |
<10 |
|
nm |
SEM |
|
|
|
|
μmol/min |
|
|
U/mg |
|
7541 |
296 |
CeM |
|
|
|
XRD |
The crystallite size of CeM was found ~3.1 nm. The length of cotiledones shaped CeM was observed ~ 10 μm, average diameter was ~ 2.5 μm and the average thickness of particles was 350 nm. |
|
|
|
|
|
|
|
|
7543 |
298 |
Cu-ADP |
5 |
|
μm |
TEM |
|
|
|
|
|
|
|
U/mg |
|
7544 |
298 |
Cu‐ATP |
5 |
|
μm |
TEM |
|
|
|
|
|
|
|
|
|
7542 |
298 |
Cu-AMP |
5 |
|
μm |
TEM |
|
|
|
|
|
|
|
U/mg |
|
7545 |
300 |
ceria A-III and B-IV coatings |
10mm*1mm |
|
|
|
|
|
|
|
|
|
|
|
|
7546 |
301 |
His-GQD/hemin |
13-80 |
|
nm |
Others |
His-GQDs, synthesized according to our previously reported procedure [22], have an average lateral size of ~ 3 nm and a height of ~ 2 nm (Fig. 1(a) and Fig. S1 in the Electronic Supplementary Material (ESM)) |
|
|
|
|
|
|
|
|
7547 |
302 |
MoS2-MIL-101(Fe) |
|
|
|
SEM |
MoS2 exhibits a flower-like appearance with a uniform diameter of approximately 150 nm, and MIL-101(Fe) exhibits an octahedral struc |
340 m2 ·g−1 |
|
|
|
|
|
|
|
7548 |
303 |
Quercetin@ZIF-90 (QZ) |
105 |
±15 |
nm |
SEM |
SEM image shows that the average size of QC-5@ZIF-90 is 105±15 nm |
|
|
|
|
|
|
|
|
7549 |
303 |
Quercetin@ZIF-90 (QZ) |
105 |
|
nm |
SEM |
SEM image shows that the average size of QC-5@ZIF-90 is 105±15 nm |
|
|
|
|
|
|
|
|
7552 |
305 |
Cu-NC |
|
|
nm |
SEM |
The scanning electron micrographs (SEM) images revealed the two catalysts mainly exhibited the interconnected nanoparticles with a size of 50∼100nm |
627 m2 /g |
|
|
|
|
|
|
|
7551 |
305 |
Cu-OC |
|
|
|
|
|
669 m2 /g |
|
|
|
|
|
|
|
7553 |
310 |
AuBP@Pt |
100*50 |
|
nm |
TEM |
the size of Au BPs was about 80 nm length and 30 nm width. the AuBP@Pt exhibited a nano bipyramid morphology with about 100 nm length and 50 nm width. |
|
|
|
|
|
|
|
|
7554 |
311 |
organic nanozymes |
|
|
|
TEM |
As imaged with TEM, the freshly prepared nanozymes show uniform and small diameters of about 3 nm (Figure 2a), and upon exposure to the radicals, for example, H2O2 or •OH (Figure S6a), they aggregated gradually to about 300 nm because of multiple disulphide bridging between particles. Likewise, the AFM image demonstrates a uniform height of about 3 nm for the nanozyme (Figure 2b). Under H2O2 or •OH treatments (Figure S6b), the nanozyme sizes increase significantly in width with similar morphologies to those in TEM images, but their heights reached only about 10 nm, likely resulting from a collapse of soft-structured nanozyme aggregation. |
|
|
|
|
|
|
|
|
7556 |
313 |
Fe-Loaded MOF-545(Fe) |
3.7 |
|
nm |
SEM |
The SEM results showed that the crystal (Fe-loaded MOF-545(Fe)) exhibited a rod-like morphology in size (3.7 nm) with hexagonal edge, which was the same as the published results |
2368 |
|
|
|
|
|
|
|
7557 |
314 |
Fe-MOF |
500-700 |
|
nm |
SEM |
FE-SEM images in Fig. S1A&B show that Fe-MOFs (Fig. S1A) and Zr-MOFs (Fig. S1B) are in octahedral crystal shape with around 500–700 nm and 100–300 nm diameter, respectively, while Cu-MOFs (Fig. S1C) is in spherical shape with a size of 400–700 nm diameter. |
|
|
|
|
|
|
|
|
7558 |
316 |
Fe-MIL-88B |
270 |
|
nm |
TEM |
MIL-88 with an average diameter of 270 nm was synthesized by the hydrothermal method |
13.40 m2 ·g−1. |
|
|
|
|
|
|
|
7560 |
318 |
Fe3O4@TAn nanoflowers (NFs) |
390 |
|
nm |
SEM |
The Fe3O4@TA1.0 NFs exhibit petal-like nanoflowers morphology with an average particle size of 390 nm and the size distribution is consistent with normal distribution |
|
|
|
|
|
|
|
|
7562 |
320 |
Au-BNNs |
4 |
|
nm |
SEM |
The size of AuNPs and AgNPs dispersed on BNNs was approximately 4 nm and 7 nm. |
|
|
|
|
|
|
|
|
7561 |
320 |
Ag-BNNs |
7 |
|
nm |
SEM |
|
|
|
|
|
|
|
|
|
7563 |
321 |
PdNPs/GDY |
3.1 |
|
nm |
TEM |
In contrast, many Pd nanoparticles, with an average size of 3.1 nm, were observed and uniformly distributed on the GDY sheet after reduction with NaBH4 (Fig. 1c and d, Fig. S2), demonstrating the successful preparation of the PdNPs/GDY composite. |
|
|
|
|
|
|
|
|
7564 |
322 |
PDI-CeCoO3 |
35 |
|
nm |
TEM |
As can be seen from Fig. 2A, the size of irregular nanoparticles is from around 11 to 62 nm with average diameter of 35 nm |
|
|
|
|
|
|
|
|
7566 |
325 |
CoOOH NFs |
105 |
|
nm |
SEM |
SEMnimage showed that the CoOOH NFs have a hexagonal sheet morphology with an average diameter of around 105 nm. |
|
|
|
|
|
|
|
|
7567 |
326 |
SiO2@MPGs |
10 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7568 |
327 |
Co4S3/Co3O4 nanotubes |
~166.7 |
|
nm |
TEM |
Diameter |
|
|
|
|
|
|
|
|
7569 |
328 |
Pc(OH)8/CoSn(OH)6 |
150-210 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7571 |
331 |
Fe-MOFs |
100 |
|
nm |
TEM |
Diameter |
|
|
|
|
|
|
|
|
7572 |
331 |
Fe-MOFs |
185 |
|
nm |
TEM |
length |
|
|
|
|
|
|
|
|
7573 |
334 |
Au/MOFs(Fe, Mn)/CNTs |
|
|
|
|
|
145.22 |
|
|
|
|
|
|
|
7583 |
342 |
HMPWCs |
~120 |
|
nm |
SEM |
|
|
|
|
|
|
|
|
|
7585 |
345 |
MIL-53 (Fe) |
less than 250 nm |
|
nm |
SEM |
|
|
|
|
|
|
|
|
|
7586 |
346 |
MoS2/rGO |
5 |
|
μm |
SEM |
thickness |
|
|
|
|
|
|
|
|
7587 |
348 |
CMC |
112.6 |
4.2 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
7592 |
350 |
AuNP@Fe-TCPP-MOF |
1.1 |
|
μm |
SEM |
|
|
|
|
|
|
|
|
|
7594 |
356 |
MoS2/rGO VHS |
100 |
|
nm |
SEM |
MoS2 nanosheets with an average diameter of 100 nm are vertically decorated on rGO sheets.the thickness of the nanosheet is about 10 nm |
|
|
|
|
|
|
|
|
7596 |
358 |
50Co/CuS-MMT |
100 |
|
nm |
|
It can be found that the porous hollow spheres of 50Co/CuS-MMT with ca. 100 nm are composed of even smaller nanoparticles with the size of ca. 2 nm. |
|
|
|
|
|
|
|
|
7600 |
361 |
CoO@AuPt |
~36 |
|
nm |
TEM |
The SEM and TEM images clearly indicated the spherical hollow structure of the as-synthesized CoO@AuPt NPs with a uniform size distribution (Fig. 2a and b). The average diameter of the CoO@AuPt NPs was calculated to be ~36 nm with a nanoshell thickness of ~4 nm. |
|
|
|
|
|
|
|
|
7607 |
370 |
Cu3V2O7(OH)2·2H2O |
50 to 120 |
|
nm |
SEM |
While the width of these ribbons ranged from 50 to 120 nm, they were tens of micrometers in length. |
|
|
|
|
|
|
|
|
7608 |
371 |
Mn3O4@Au-dsDNA/DOX |
354 |
8 |
nm |
DLS |
The average hydrodynamic sizes of AN, Mf, MfAN, and MfAND were about 42 ± 2, 214 ± 7, 361 ± 18, and 354 ± 8 nm, respectively |
|
|
|
|
|
|
|
|
7609 |
372 |
Cu2(OH)3NO3 nanosheets |
1 |
|
μm |
SEM |
The structure and morphology of the as-prepared Rouaite were characterized by SEM and TEM (Fig. 2). The acquired SEM image shows the sheet-like structure of the average diameter of 1 μm (Fig. 2a). |
104.3 m2/g |
|
|
|
|
|
|
|
7610 |
374 |
AL-PB |
42 |
|
nm |
DLS |
The average hydrodynamic radius was found to be 42 nm at pH 4 and did not show any unambiguous trends by changing the pH. |
|
|
|
|
|
|
|
|
7614 |
378 |
Ce2(MoO4)3/rGO |
~500 |
|
nm |
HR-TEM |
Fig. 5d shows the HR-TEM images of rGO/CM (48 h) nanocomposites where large size (∼500 nm) polyhedrons are attached with rGO sheet. |
|
|
|
|
|
|
|
|
7615 |
381 |
PdCu TPs/PG |
25 |
|
nm |
TEM |
As shown in Fig. 2A, the PdCu TPs are tripod-shaped with an arm length of approximately 25 nm. |
|
|
|
|
|
|
|
|
7619 |
384 |
TPP-Se-CDs |
~18.4 |
0.5 |
nm |
DLS |
The obtained hydrodynamic diameters in those two media stayed nearly unchanged during this period, ~18.4 ± 0.5 and ~19.3 ± 0.6 nm in PBS and DMEM, respectively |
|
|
|
|
|
|
|
|
7618 |
384 |
TPP-Se-CDs |
~19.3 |
0.6 |
nm |
DLS |
The obtained hydrodynamic diameters in those two media stayed nearly unchanged during this period, ~18.4 ± 0.5 and ~19.3 ± 0.6 nm in PBS and DMEM, respectively |
|
|
|
|
|
|
|
|
7625 |
387 |
Ag@Ag2WO4 NRs |
|
|
nm |
SEM |
The Ag@Ag2WO4 revealed rod-shaped particles with cubic and hexagonal silver nanoparticle distribution |
|
|
|
|
|
|
|
|
7629 |
392 |
2D TCPP(Fe)-BDMAEE |
1.85 |
|
nm |
AFM |
a thickness of ~ 1.8–1.9 nm |
|
|
|
|
|
|
|
|
7630 |
393 |
C‑dots/Mn3O4 nanocomposite |
|
2/10 |
nm |
TEM |
The diameters of nanoparticles are 2 and 10 nm, respectively. |
|
|
|
|
|
|
|
|
7631 |
393 |
C‑dots/Mn3O4 nanocomposite |
|
|
nm |
TEM |
The diameters of nanoparticles are 2 and 10 nm, respectively. |
|
|
|
|
|
|
|
|
7633 |
394 |
Fe3O4@Cu/C |
|
|
nm |
TEM |
However, calcination at a higher temperature and a long time caused serious collapse of the structure, leading to the disappearance of original morphology. It can be found that Fe3O4@CuO composites fail to inherit the original octahedral structure and present nearly spherical (Fig. 3a, c). From TEM image (Fig. 3e, f), the constructions of Fe3O4@HKUST-1 composites are shrunk in certain degree and the sizes are reduced, whether the composites were calcined in N2 or air atmosphere. |
112.1 |
|
|
|
|
|
|
|
7632 |
394 |
Fe3O4@CuO |
|
|
nm |
TEM |
However, calcination at a higher temperature and a long time caused serious collapse of the structure, leading to the disappearance of original morphology. It can be found that Fe3O4@CuO composites fail to inherit the original octahedral structure and present nearly spherical (Fig. 3a, c). From TEM image (Fig. 3e, f), the constructions of Fe3O4@HKUST-1 composites are shrunk in certain degree and the sizes are reduced, whether the composites were calcined in N2 or air atmosphere. |
45.8 |
|
|
|
|
|
|
|
7634 |
395 |
Gold-Mesoporous Silica Heteronanostructures |
<5 |
|
nm |
TEM |
Cs-corrected Scanning Transmission Electron Microscopy (STEM) images demonstrated the formation of crystalline Au NPs with average diameters below 5 nm |
|
|
|
|
|
|
|
|
7636 |
398 |
FePPOPBFPB |
150 |
|
nm |
SEM |
The SEM image (Figure 1C) shows that FePPOPBFPB contains relatively uniform globular particles with an average size of 150 nm. |
308 |
|
|
|
|
|
|
|
7637 |
399 |
GO−Fe(III) |
60-90 |
|
μm |
Others |
It can be seen in Figure 1b that the CSs prepared using GO nanosheets as stabilizers are in the range of 60−90 μm, which is in agreement with the results in Figure S1c. |
|
|
|
|
|
|
|
|
7638 |
400 |
MS@MnO2 hybrid |
~54 |
|
nm |
TEM |
The nanoparticle was ∼54 nm in size and showed good dispersibility. |
|
|
|
|
|
|
|
|
7640 |
405 |
Ag3PO4 NPs |
15–40 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7642 |
408 |
CuS@CeO2 |
200 |
|
nm |
TEM |
CuS 5-8 nm |
|
|
|
|
|
|
|
|
7643 |
409 |
Pd NPs/ CMC-COF-LZU1 |
4 |
|
nm |
TEM |
|
402.494 |
|
|
|
|
|
|
|
7644 |
410 |
Au@HMPB |
100 |
|
nm |
TEM |
hollow structure |
|
|
|
|
|
|
|
|
7645 |
411 |
dSCS-Au NPs |
250 |
|
nm |
TEM |
pore 10nm Carbon dots <10nm |
|
|
|
|
|
|
|
|
7647 |
413 |
MoS2-QDs-AgNPs |
5.9 |
1.1 |
nm |
TEM |
MoS2 QDs |
|
|
|
|
|
|
|
|
7648 |
414 |
PBA NCs |
60 |
|
nm |
TEM |
|
60.12 |
|
|
|
|
|
|
|
7649 |
415 |
BSA-PtAu@CNS |
100-200 |
|
nm |
TEM |
|
921.336 |
|
|
|
|
|
|
|
7650 |
417 |
Fe3O4@MoS2-Ag |
428.9 |
|
nm |
Others |
The Fe3O4@MoS2-Ag composites were observed with MoS2 covering Fe3O4 (diameter of ~428.9 nm) by SEM and TEM images |
17.446 |
|
|
|
|
|
|
The BET surface area was calculated to be 7.746, 13.464, 16.607 and 17.446 m2/g for MoS2, Fe3O4, Fe3O4@MoS2 and Fe3O4@MoS2-1%Ag, respectively, showing the superiority of MoS2 sheets vertically growing on Fe3O4. |
7651 |
419 |
Hollow MnFeO oxide |
|
|
|
|
|
241.291 |
|
|
|
|
|
|
|
7653 |
421 |
Por-NiCo2S4 |
570 |
|
nm |
SEM |
As seen from SEM images (Fig. 3a-3c), the morphologies of both NiCo2S4 and Por-NiCo2S4 are yolk-shell nanospheres with a uniform size of ca. 570 nm |
18.3031 |
|
|
|
|
|
|
|
7654 |
422 |
BSA-PtNP@MnCo2O4 |
|
|
|
|
|
71.922 |
|
|
|
|
|
|
|
7655 |
423 |
Lyz-AuNPs |
100/60 |
|
nm |
DLS |
When the ζ-potential values approach zero, the hydrodynamic diameter distributions show the tendency to become broader and unstable. Correspondingly, aggregates reach the maximum values of the hydrodynamic diameter of 640 ± 30 nm for 100 nm AuNPs and 760 ± 60 nm for 60 nm AuNPs. |
|
|
|
|
|
|
|
|
7656 |
424 |
m-SAP/cDNA |
220.82 |
|
nm |
TEM |
As exhibited in Fig. 3C, the hydrodynamic diameters of m-SiO2 NP, MNP-aptamer and m-SAP/c-DNA are 201.09, 117.95, 220.82 nm, respectively. When MNP-aptamer and m-SAP/cDNA incubated and reacted, the m-SAP/MNP complex generated and showed a large size increase to 457.43 nm, implying the successful hybridization of aptamer and cDNA. |
|
|
|
|
|
|
|
|
7658 |
427 |
MnO2 |
|
|
nm |
TEM |
The size of MnO2 nanosheets was found to be around 280 nm while the heights were about 5.6 nm |
|
|
|
|
|
|
|
|
7659 |
428 |
AuNP |
13 |
|
nm |
TEM |
The AuNPs have a particle size of about 13 nm. |
|
|
|
|
|
|
|
|
7660 |
429 |
ZIF@GOx/GQDs |
150 |
|
nm |
TEM |
TEM and scanning electron microscopy (SEM) images presented that the obtained ZIF@GOx/GQDs possessed relatively homogeneous size of around 150 nm |
|
|
|
|
|
|
|
|
7661 |
430 |
MnO2 NFs |
100 |
|
nm |
TEM |
Fig. 2(d–e) shows that the MnO2 NFs have the diameter of ∼100 nm. |
155.06 |
|
|
|
|
|
|
|
7663 |
433 |
AuNP−TTMA |
|
|
nm |
|
The diameter of the overall particle is ∼7 nm in water with 2 nm core which is verified by DLS and TEM measurements respectively and is not affected by the encapsulation of the TMCs (Figure 2, experimental details in the Supporting Information). |
|
|
|
|
|
|
|
|
7664 |
433 |
AuNP−TTMA |
2 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7665 |
434 |
AuNP-TTMA |
|
|
nm |
|
The diameter of the overall particle is ∼7 nm in water with 2 nm core which is verified by DLS and TEM measurements respectively and is not affected by the encapsulation of the TMCs (Figure 2, experimental details in the Supporting Information). |
|
|
|
|
|
|
|
The diameter of the overall particle is ∼7 nm in water with 2 nm core which is verified by DLS and TEM measurements respectively and is not affected by the encapsulation of the TMCs (Figure 2, experimental details in the Supporting Information). |
7666 |
435 |
MnNS:CDs |
3.8 |
0.1 |
nm |
TEM |
an average particle size of 3.8 ± 0.1 nm |
|
|
|
|
|
|
|
|
7670 |
440 |
PEG-Au/FeMOF@CPT NPs |
50 |
|
nm |
TEM |
Monodispersed nanoparticles with the diameter around 50 nm were observed in transmission electron microscopy (TEM) image (Figure 1a and Figure S1, Supporting Information). Au/FeMOF NPs were further fabricated using FeMOF NPs as platforms by directly reducing HAuCl4 in water using sodium borohydride as a reductant. As shown in Figure 1b,d, dark spots corresponding to the Au NPs ≈5 nm in diameter were observed on the exterior surface of Au/FeMOF NPs. |
1451 |
|
|
|
|
|
|
|
7671 |
444 |
Fe3O4@SiO2 |
6.25 |
|
μm |
SEM |
|
|
|
|
|
|
|
|
|
7672 |
444 |
HA@Fe3O4@SiO2 |
6.24 |
|
μm |
SEM |
|
|
|
|
|
|
|
|
|
7679 |
446 |
FeSO4+ CoCl2 |
|
|
|
|
|
|
|
|
|
30 |
|
U/mg |
|
7674 |
446 |
Au@Co-Fe NPs |
53.4 |
1.8 |
nm |
DLS |
Mean diameter |
|
|
|
|
87 |
|
U/mg |
|
7675 |
446 |
HRP natural |
|
|
|
|
|
|
|
|
|
517 |
|
U/mg |
|
7676 |
446 |
HRP natural |
|
|
|
|
|
|
|
|
|
153 |
|
U/mg |
|
7677 |
446 |
Au@Fe NPs |
|
|
|
|
|
|
|
|
|
72 |
|
U/mg |
|
7678 |
446 |
Au@Co NPs |
|
|
|
|
|
|
|
|
|
36 |
|
U/mg |
|
7680 |
446 |
FeSO4 |
|
|
|
|
|
|
|
|
|
26 |
|
U/mg |
|
7681 |
446 |
CoCl2 |
|
|
|
|
|
|
|
|
|
18 |
|
U/mg |
|
7682 |
446 |
Au |
22.4 |
0.8 |
nm |
DLS |
|
|
|
|
|
31 |
|
U/mg |
|
7683 |
446 |
Au@Co-Fe NPs |
25 |
|
nm |
TEM |
The TEM image also confirmed that Au@Co-Fe NPs are spherical and about 25 nm. |
|
|
|
|
253 |
|
U/mg |
The Au@Co-Fe NPs activity (units) calculated based on the Eq. 4:(4)bnanozyme=Vε×l×(ΔAΔt) In the Eq. 4, b nanozyme is the catalytic activity of Au@Co-Fe NPs defined in units. V is the total volume of reaction solution (μl), ε is the molar extinction coefficient (39,000 M−1 cm−1) of the oxidized TMB, at 652 nm, l is the path length of light traveling in the cuvette (cm), A is the absorbance after subtraction of the blank value and ΔA/Δt is the initial rate of change in absorbance at 652 nm min−1. |
7688 |
452 |
GO/AuNPs |
31 |
|
nm |
TEM |
TEM results (see the Supporting Information, Fig. S1) showed that spherical nanoparticles were uniformly dispersed and embedded on the surface of GO and the particle size of nanoparticles was about 31 nm. |
|
|
|
|
|
|
|
|
7690 |
456 |
PBAs |
60 |
|
nm |
TEM |
The size of the PBAs was accurately controlled to be ∼60 nm with smooth surfaces through a 40 °C water-bath-assisted synthesis (Figure S1A,B, Supporting Information). The elements Ni and Fe existed in the PBA in the energy-dispersive X-ray spectroscopy (EDS) spectrum (Figure S1C) and in the elemental mapping images (Figure S1D), which indicated that the bimetal nanocubes were well synthesized. From the TEM images of the Nanocages (Figure 1A), a cubic morphology with an average size of 60 nm was retained, but the cube became hollow and the surfaces became much rougher. |
60.11 |
|
|
|
|
|
|
|
7691 |
457 |
CuS-BSA-Cu3(PO4)2 |
121.8 |
34.5 |
nm |
DLS |
the average diameters of CuS-BSA and CuS-BSA-Cu3(PO4)2 are 134.5 ± 29.4 nm and 121.8 ± 34.5 nm |
|
|
|
|
|
|
|
|
7692 |
457 |
CuS-BSA-Cu3(PO4)2 |
10 |
0.21 |
nm |
DLS |
TEM investigation of both CuS-BSA-Cu3(PO4)2 (Fig. 2) and CuS-BSA (Fig. S8) nanoparticles revealed that the nanomaterials consist of nanoparticles with an average diameter of 10 ± 0.21 nm and 9.68 ± 0.602 nm, respectively (the size was determined from 100 NPs using Image J software). |
|
|
|
|
|
|
|
|
7693 |
459 |
Ag-MA |
2.5 |
|
μm |
TEM |
One can note from Fig. 1A that the original products of Ag-MA nanocomposites could exhibit uniform rod-like profile with the side width of about 2.5 μm, with the mesoporous structure as revealed in the amplified view (insert), which could also be witnessed clearly from the TEM images (Fig. 1C). |
|
|
|
|
|
|
|
|
7697 |
463 |
ZV-Mn NPs |
<50 |
|
nm |
TEM |
High resolution transmission electron microscopy (HR-TEM) images indicated that the particle size of ZV-Mn NPs was less than 50 nm |
6.0568 |
|
|
|
|
|
|
|
7698 |
464 |
FePorMOFs |
150 |
|
nm |
SEM |
The SEM image showed the as prepared FePorMOFs were uniform in a rod-like structure with a 600 nm length and 150 nm width (Figure 3B). |
|
|
|
|
|
|
|
|
7699 |
465 |
Pt NC/3D GF nanohybrid |
|
|
|
SEM |
As shown in Figure 1A, 3D GF displays a regular three-dimensional porous structure, in which the pore diameter is 100–200 μm. The color of the Pt NC/3D GF nanohybrid was deeper than that of pure 3D GF, demonstrating that Pt NC was evenly anchored on 3D GF (Figure 1A inset). The transmission electron microscopy (TEM) images (Figure 1C,D) revealed that interconnected 3 nm Pt nanocrystals formed Pt nanoclusters on the 3D GF. |
In addition to the high surface area provided by the special 3D macroporous structure of 3D GF (∼850 m2/g bare 3D GF estimated by the Brunauer–Emmett–Teller method(50)) |
|
|
|
|
|
|
|
7703 |
470 |
Tα-MOF |
65 |
|
nm |
TEM |
These results are consistent with the data obtained from TEM image. Homogeneous size distribution and an average size of 65 nm observed in Fig. 2b. |
|
|
|
|
|
|
|
|
7707 |
477 |
NC@GOx NPs |
178 |
12 |
nm |
DLS |
The hydrodynamic sizes became larger (178 ± 12 nm) than NC NPs (155 ± 15 nm), further confirming the successful modification of GOx on NC NPs. |
|
|
|
|
|
|
|
|
7708 |
478 |
DNA/MoS2 NSs |
75 |
|
nm |
TEM |
The transmission electron microscopy (TEM) image showed that the MoS2 possessed a two-dimensional nanosheet structure with an average diameter of about 75 nm |
|
|
|
|
|
|
|
|
7709 |
483 |
DMSN@AuPtCo |
80 |
|
nm |
TEM |
The average particle diameter and central-radial pore size of DMSNs were around 80 nm and 11.5 nm respectively, which were found from scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images, and nitrogen adsorption measurements.AuPtCo clusters having a diameter of around 2.2 nm were formed by in situ reduction and attached to the pore surfaces, as clearly shown by SEM , TEM , elemental mapping images , powder X-ray diffraction analysis and diameter distribution analysis. |
|
|
|
|
|
|
|
|
7710 |
484 |
Co3O4/MO3 |
19.1, 25.3 |
|
nm |
TEM |
The average pore sizes of Co3O4, Co3O4/MoO3 and Co3O4/WO3 were 12.7, 19.1 and 25.3 nm, respectively. |
|
|
|
|
|
|
|
|
7715 |
487 |
Cu-MOPN |
|
|
|
|
|
|
|
|
|
|
|
|
|
7716 |
488 |
HRP/MB/chitosan/MoS2/GF |
5-8 |
|
nm |
SEM |
The thickness of MoS2 is about 0.8 μm. Measuring from the curved edges of the nanosheets, the thickness of the MoS2 nanosheets is determined to be about 5–8 nm |
|
|
|
|
|
|
|
|
7717 |
489 |
Fe/Al-GNE |
40 |
|
nm |
DLS |
The successful synthesis of Fe/Al-GNE was further verified by transmission electron microscopy (TEM) imaging, where characteristic carbon layers could be observed (Fig. 1B). It was also revealed that the average size of Fe/Al-GNE was about 40 nm, in line with dynamic light scattering results |
|
|
|
|
|
|
|
|
7718 |
489 |
Fe/Al-GNE |
40 |
|
nm |
TEM |
The successful synthesis of Fe/Al-GNE was further verified by transmission electron microscopy (TEM) imaging, where characteristic carbon layers could be observed (Fig. 1B). It was also revealed that the average size of Fe/Al-GNE was about 40 nm, in line with dynamic light scattering results |
|
|
|
|
|
|
|
|
7719 |
492 |
CoPc |
114 |
|
nm |
DLS |
The hydrodynamic radius of cobalt(ii) phthalocyanine colloid was characterized by dynamic light scattering (DLS). (Fig. 3) showed a single peak in solution with an average diameter of 114 nm. |
|
|
|
|
|
|
|
|
7720 |
494 |
nanozyme |
20 |
|
nm |
TEM |
The synthesized AuNPs were investigated by TEM. It is apparent that the AuNPs are monodisperse, spherical in shape, and a narrow particle-size distribution with a mean size of about 20 nm. |
|
|
|
|
|
|
|
|
7721 |
495 |
β-CD@AuNPs–MWCNTs |
13+10~20 |
|
nm |
TEM |
As exhibited in Fig. 1A, we could see that spherical β-CD@AuNPs with an average diameter of 13 nm were attached on the surface of MWCNTs (diameter: 10–20 nm), indicating the successful synthesis of β-CD@AuNPs–MWCNTs nanomaterials. |
|
|
|
|
|
|
|
|
7722 |
496 |
CS-MNPs |
30 |
|
nm |
SEM |
The morphology and size of the resulting MNPs and CS-MNPs were then analyzed by SEM images (Figure 1b,c). Both MNPs and CS-MNPs presented spherical shapes with a nearly-uniform diameter of around 30 nm. |
|
|
|
|
|
|
|
|
7724 |
498 |
SPDA |
1.8 |
0.3 |
nm |
TEM |
Transmission electron microscopy was used to explore the morphology, particle size and dispersity of SPDA. Fig. 1 shows the TEM images of SPDA. SPDA were substantially spherical or spheroidal with the diameter ranging from 1.5 to 2.1 nm. |
|
|
|
|
|
|
|
|
7725 |
499 |
Fe@Fe3O4@heparin |
13.9 |
1.7 |
nm |
TEM |
water-soluble Fe@Fe3O4 NPs were modified with heparin through the ligand exchange method to form Fe@Fe3O4@heparin NPs (MNPs). |
|
|
|
|
0.456 |
|
U/mg |
|
7726 |
499 |
Fe3O4@heparin |
|
|
|
|
|
|
|
|
|
0 |
|
U/mg |
|
7727 |
499 |
Fe@Fe3O4@heparin |
13.9 |
1.7 |
nm |
TEM |
water-soluble Fe@Fe3O4 NPs were modified with heparin through the ligand exchange method to form Fe@Fe3O4@heparin NPs (MNPs). |
|
|
|
|
0 |
|
U/mg |
|
7728 |
499 |
Fe3O4@heparin |
|
|
|
|
|
|
|
|
|
0.044 |
|
U/mg |
|
7729 |
500 |
CNF/FeCDs |
4 |
0.9 |
nm |
DLS |
The corresponding size-distribution analysis (Fig. 1b) unveiled their narrow size distribution in the range of 2–7 nm with a mean diameter of 4.0 ± 0.9 nm, which confirmed that it was a good candidate for doping additive. |
|
|
|
|
|
|
|
|
7730 |
501 |
Cu-HCF SSNEs |
102.5 |
21.8 |
nm |
TEM |
Monodispersed SSNEs were obtained with a statistical size of 102.5±21.8 nm |
|
|
|
|
|
|
|
|
7731 |
501 |
Cu-HCF SSNEs |
128.3 |
4.2 |
nm |
DLS |
The hydrodynamic size of SSNEs was measured to be 128.3±4.2 nm by dynamic light scattering (DLS) analysis, which is larger than the TEM results due to the existence of PEG layer. |
|
|
|
|
|
|
|
|
7732 |
502 |
M/CeO2 |
261 |
0.2 |
nm |
TEM |
The nanorods in dispersions show an average length of 261.0 ± 0.2 nm and average diameter of 14.2 ± 0.5 nm |
|
|
|
|
|
|
|
|
7743 |
512 |
NiCo2O4-Au composite |
|
|
|
TEM |
As depicted in Fig. 1A and B, NiCo2O4-Au composite had a rough surface with a wide size distribution, similar to single NiCo2O4 (Sup-porting Information, Fig. S1) |
|
|
|
|
|
|
|
|
7746 |
516 |
Zn-MnO2 and Cu-MnO2 |
10-60 |
|
nm |
SEM |
The Cu-MnO2 coating surface, on the other hand, con-sisted of nanoparticles aggregation (10–60 nm in diameter). The surface of Zn-MnO2 nanocoating was composed of stripe-like nanostructures with coarse surface. |
|
|
|
|
|
|
|
|
7747 |
517 |
GOx@h-CNT/Fe3O4/ZrO2 |
5-20 |
|
nm |
TEM |
The TEM image of the synthesized h-CNT/Fe3O4 composites in Fig. 2c told us Fe3O4 nanoparticles were quasi-spherical and the majority of the particles were in the range of 5–20 nm, thus exhibiting superparamagnetism. |
324.9m2 g−1 |
|
|
|
|
|
|
|
7752 |
522 |
MIL-88@Pt@MIL-88@sDNA |
40-60 |
|
nm |
SEM |
The size distribution of CeO2 NPs ranged from 40 to 60 nm, which corresponds well with the results expected from a synthesis using with ZIF-8 NPs. |
|
|
|
|
|
|
|
|
7753 |
522 |
MIL-88@Pt@MIL-88@sDNA |
250 |
|
nm |
TEM |
After growing MIL-88 shell, the Pt NPs anchored at the MOF core seem to be covered and the size of obtained composites increase to about 250 nm (Fig. 1E and F), |
76.9640 m2 g−1 and 0.2606 cm3 g−1 |
|
|
|
|
|
|
|
7754 |
524 |
Pd@Pt-GOx/hyaluronic acid (HA |
80 |
|
nm |
DLS |
The hydrodynamic size of Pd@Pt was ∼58 nm, which changed to ∼68 nm for Pd@Pt-GOx and ∼80 nm for Pd@Pt-GOx/HA (Figure 1f) |
|
|
|
|
|
|
|
|
7755 |
525 |
Gold and magnetic particles (GoldMag) |
|
|
|
|
|
|
|
|
|
|
|
|
|
7756 |
526 |
Pt2+@g-C3N4 |
|
|
|
|
|
|
|
|
|
|
|
|
|
7759 |
529 |
man-PB |
0.2-0.22 |
|
μm |
DLS |
(b) Particle size distributionof theman-PB nanoparticles. |
|
|
|
|
|
|
|
|
7760 |
530 |
HCS@Pt NPs |
3.96 nm |
|
nm |
TEM |
The surface area of HCS@Pt NPs was about 227.5 m2 /g and the pore size were about 3.96 nm (Table S1). |
227.5 m2 /g |
|
|
|
|
|
|
|
7761 |
531 |
Zn-N-C-800 |
150 |
|
nm |
TEM |
The synthesis yielded characteristic truncated rhombic dodecahedral crystals of size ~150 nm (Fig. 1). |
158m2 /g |
|
|
|
|
|
|
|
7762 |
532 |
FeNGR |
300–400 |
|
nm |
AFM |
The AFM images showed that FeNGR had irregular planar structure with 300–400 nm diameters, and a few atomic monolayers with height of 1.2–1.5 nm, similar to pristine GR (Figure 1A). |
|
|
|
|
|
|
|
|
7763 |
533 |
Ag-CoO NP |
400 |
|
nm |
TEM |
it can be found the flower-like 0.10Ag-CoO NPs are composed of a dense core with a uniform size of about 400 nm |
156.8 cm2 g−1 |
|
|
|
|
|
|
|
7764 |
534 |
Ag@Ag2WO4 NRs |
500 nm in length and 50 nm in width |
|
nm |
SEM |
As is seen, AWNRs-9 was composed of homogeneous nanorods with about 500 nm in length and 50 nm in width, presenting a similar size and structure to AW-9. |
8.56 m2⋅ g−1 |
|
|
|
|
|
|
|
7767 |
537 |
MoS2/C-Au600 |
~93 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7769 |
539 |
GA-NFs |
9 |
|
μm |
TEM |
|
|
|
|
|
|
|
|
|
7770 |
540 |
Fe3O4@CP |
168 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7775 |
546 |
NH2-MIL-101(Fe) |
|
|
|
|
|
|
|
|
|
12 |
|
|
|
7776 |
546 |
MIL-101(Fe) |
600-800 |
|
nm |
TEM |
|
|
|
|
|
5 |
|
|
|
7777 |
546 |
NO2-MIL-101(Fe) |
|
|
|
|
|
|
|
|
|
36 |
|
|
|
7781 |
550 |
magnetite particles |
|
|
|
|
|
|
|
|
|
|
|
|
|
7785 |
555 |
MnO2–Au |
200 |
|
nm |
TEM |
a relatively smooth surface with uniformed size of about 200 nm (Fig. 1(a)). |
|
|
|
|
|
|
|
|
7786 |
556 |
UiO-66 |
200-300 |
|
nm |
SEM |
Figure 3. Scanning electron microscopy (SEM) images of the as-synthesized UiO-66 MOFs (particle size is around 200−300 nm for all the samples). |
861 |
|
|
|
|
|
|
|
7788 |
558 |
Fe3O4@NH2-MIL-101(Fe) |
|
|
|
SEM |
The size and lantern morphology of NH2-MIL-101(Fe) in the composites were not changed, as showed in Fig. S1C, D. |
|
|
|
|
|
|
|
|
7789 |
559 |
Ni/Al–Fe(CN)6 LDH |
30 |
|
nm |
SEM |
The morphology of the Ni/Al–Fe(CN)6 LDH was investigated using FESEM. As can be observed in Fig. 1C, LDH displays aggregate consists of crystallites as uniform spherical shaped particles with particle size of about 30 nm. |
|
|
|
|
|
|
|
|
7792 |
563 |
ficin@PCN-333(Fe) |
4.03 |
0.31 |
μm |
SEM |
SEM images of PCN-333(Fe) (Fig. 1A) and ficin@PCN-333(Fe) (Fig. 1B) show that they are all regular octahedral structures with edge length of 3.25 ± 0.31 μm and 4.03 ± 0.31 μm, respectively |
1434.3 |
|
|
|
|
|
|
|
7794 |
566 |
Cerium Oxide NSs |
|
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
7798 |
570 |
DNA-Cu/Ag NCs |
2.3 |
0.8 |
nm |
TEM |
The corresponding particle size distribution histogram is obtained by statistics, and the average particle size is approximately 2.3 ± 0.8 nm (Figure 2b) |
|
|
|
|
|
|
|
|
7800 |
572 |
CFPN |
300-400 |
|
nm |
SEM |
From the SEM image (Figure 1a), it was found that the as-prepared CFPN had a flower-like morphology and hollow sphere structure, and its diameter was between 300 nm to 400 nm. |
|
|
|
|
|
|
|
|
7801 |
573 |
AgNPs@Fe3O4 |
|
|
nm |
SEM |
The SEM images revealed that the synthesized magnetic nanoparticles and the silver-magnetic nanocomposites are spherical in shape with very narrow particles size distribution. |
|
|
|
|
|
|
|
|
7802 |
574 |
Pt-HMCNs |
255 |
|
nm |
SEM |
After high-temperature carbonization combined with NaOH etching, the obtained HMCNs well preserved the spherical morphology with a slight shrinkage to about 255 nm in particle size (Figures 2c and S1b), |
373 |
|
|
|
|
|
|
|
7804 |
576 |
EMSN-PtNCs |
3 |
|
nm |
TEM |
High resolution transmission electron microscopy (HRTEM) images revealed that the synthesized PtNCs were mostly 3.0 nm in size with spherical morphology (Fig. S2A) |
|
|
|
|
|
|
|
|
7805 |
577 |
Zn-TCPP(Fe) |
|
|
|
TEM |
And the TEM image in Figure S1b clearly reveals the 2D Zn-TCPP(Fe) MOF with well-defined ultrathin sheet-like structures. |
|
|
|
|
|
|
|
|
7810 |
582 |
Ag5PMo12@PPy |
|
|
|
|
Moreover, the SEM technique was employed to inspect the morphologies of PPy, Ag5PMo12, and Ag5PMo12@Ppy (Figure 2c−e) |
|
|
|
|
|
|
|
|
7813 |
585 |
Fe3O4-PAA-PB-AA |
8−10 |
|
nm |
TEM |
TEM image of hydrophobic Fe3O4 nanoparticle shows the particle size of 8−10 nm. SEM image of Fe3O4-PAA-PB-AA/PAA-PB-AA/Fe3O4-PA shows the size in the range of 20−70 nm which also corroborate with dynamic light scattering based hydrodynamic size (Figure 1). |
|
|
|
|
|
|
|
|
7814 |
587 |
CeO2 microcapsule |
2-2.5 |
|
nm |
TEM |
Citrate-stabilised cerium oxide nanoparticles were 2–2.5 nm in size (Figure 1a), with a negative zeta potential (Figure 1c) and a hydrodynamic radius of about 5–7 nm when dispersed in water (Figure 1b). |
|
|
|
|
|
|
|
|
7815 |
588 |
PPy@MoS2@Au |
|
|
|
TEM, SEM |
As shown in Fig. 1(A and B), the MoO3 microrods are ~300 nm in diameter and ~10 μm in length. |
28.57 |
|
|
|
|
|
|
|
7817 |
591 |
TACN AuNPs |
2 |
|
nm |
TEM |
We opted for spherical nanoparticles with a Au core smaller than 2 nm to have a nanoplatform size in the biomolecular scale and to minimize light absorption and scattering by the nanoparticles due to the surface plasmon band, whose intensity depends on the nanoparticle size. |
|
|
|
|
|
|
|
|
7818 |
592 |
Au−Cu2−xS |
|
|
|
TEM |
Fig. 1A and B shows large and small scale transmission electron microscopy (TEM) images of the as-prepared Janus SPs, respectively. There are well dispersed and possess well-defined hybrid and Janus structure due to the contrast difference of Au and Cu2−xS materials |
|
|
|
|
|
|
|
|
7820 |
594 |
Pt/ZnCo2O4 |
|
|
|
TEM, SEM |
Fig. 1B and C show the SEM and TEM images of Pt/ZnCo2O4 , respectively. As displayed in Fig. S2 (ESI†), ZnCo2O4 microspheres with 1.5–2 mm diameter were composed of nanoparticles. |
|
|
|
|
|
|
|
|
7821 |
595 |
ZnO-Pd |
|
|
nm |
TEM |
The TEM micrographs show that the synthesized ZnO-Pd has a sheet-like structure, with the palladium particles incorporated in it (Figure 3a–d), |
|
|
|
|
|
|
|
|
7822 |
596 |
GOx@Pd@ZIF-8 |
|
|
|
SEM |
The average particle size was ca. 130 nm as obtained from SEM measurements, while the value was measured to be 480 nm using the DLS method (Fig. S2, ESI†). |
|
|
|
|
|
|
|
|
7823 |
597 |
PAAC |
|
|
|
TEM |
The free-standing Pd@Pt have average diameter of ~100 nm (Figure 2C). The two regions highlighted in gray indicate the ~20 nm thickness of the Pt shell, almost consistent with Figure 2D. |
|
|
|
|
|
|
|
|
7825 |
599 |
Pdn-GBLP NPs |
|
|
|
TEM |
The sizes of Pd NPs inside of Pdn-GBLP NPs were investigated by TEM. Fig. 2 showed Pd NPs are spherical and monodisperse. The calculated average diameter of Pd NPs was 7.61 ± 1.74 nm for Pd41-GBLP; 9.62 ± 2.53 nm for Pd68-GBLP; 11.10 ± 2.76 nm for Pd91-GBLP and 13.13 ± 2.64 nm for Pd137-GBLP, respectively. The hydrodynamic size and zeta potential of Pdn-GBLP NPs were measured using DLS technology. As shown in Fig. 5a, the hydrodynamic size of Pd41-GBLP NPs was 21.4 nm for Pd41-GBLP NPs; 22.1 nm for Pd68-GBLP NPs; 23.1 nm for Pd91-GBLP NPs and 25.9 nm for Pd137-GBLP NPs. |
|
|
|
|
|
|
|
|
7826 |
600 |
PtNPs@PCs |
|
|
|
TEM, SEM |
The prepared PCs and PtNPs@PCs were characterized by SEM and TEM, and the results were shown in Fig. 1. The SEM image of PCs (Fig. 1A) indicated that the obtained carbon materials were porous structure monolith aer the removal of MgO template. As shown in Fig. 1B, it can be seen that PtNPs were uniformly spread on the surface of the porous of PCs. |
|
|
|
|
|
|
|
|
7827 |
601 |
AuMS |
1 |
|
μm |
TEM |
As shown in Fig. 3a, short bent rod-like structures with a length of about 1 μm can be observed. The particles into the walls are 3.8 ± 0.5 nm in diameter (Fig. 3e) with an average size of 4 nm (Fig. 4). |
|
|
|
|
|
|
|
|
7829 |
603 |
ACP/hemin@Zn-MOF |
|
|
|
AFM |
As measured, pure Zn-MOF nanosheets have a diameter of ~600 nm and a thickness of ~150 nm, and the ACP/hemin@Zn-MOF sheets possess a diameter of approximately 250 nm and a thickness of about 50 nm. |
|
|
|
|
|
|
|
|
7830 |
604 |
GO/AuNPs |
|
|
|
TEM |
From the inserted TEM, it can be seen that the small amount of spherical nanoparticles with the particle size of about 30 nm were uniformly dispersed and embedded on the surface of GO. The graphene sheet is covered with tightly compressed spherical nanoparticles with particle size of about 30 nm, which should be gold nanoparticles. |
|
|
|
|
|
|
|
|
7831 |
605 |
Ce-MOF |
|
|
|
|
|
|
|
|
|
|
|
|
|
7832 |
606 |
Pt NPs-PVP |
|
|
|
|
the average diameter of Pt NPs-PVP is about 3 nm, which is calculated by statistical analysis of hundreds of nanoparticles in TEM image. The average hydrodynamic diameter of Pt NPs-PVP was around 4.5 nm (Fig. 1C) as measured by DLS. |
|
|
|
|
|
|
|
|
7833 |
607 |
Cu-rGO |
5 |
|
nm |
TEM |
he as-synthesized nanoparticles are largely spherical in shape with an average particle size of 5 nm (Fig S3). he marked dotted white circles in Fig. 1c indicates the presence of Cu NPs on the rGO support having a diameter of 5 nm, and the lattice fringes show an inter-planar spacing of 0.209 nm |
|
|
|
|
|
|
|
|
7834 |
609 |
Mn3(PO4)2/MXene |
|
|
|
AFM |
AFM image tells that the Mn3(PO4)2 nanosheets have an average thickness of 1.5 nm. AFM image of the MXene confirms the 2-D nanosheet structure with an average thickness of around 1.5 nm |
|
|
|
|
|
|
|
|
7835 |
610 |
FePc/HNCSs |
|
|
|
|
The as-prepared HNCSs showed a hollow spherical structure with an average diameter of about 100 nm (Figure S1c,d, Supporting Information). Besides, HNCSs possess a high specific surface area and a suitable average pore size of 582.97 m2 g–1 and 4.06 nm, respectively (Figure S2, Supporting Information), which are conducive to supporting FePc and decreasing its aggregation. In addition, FePc/HNCSs displayed a hydrodynamic size of ≈157 nm (Figure 1c) |
582.97 |
|
|
|
|
|
|
|
7837 |
613 |
NH2-MIL-53(Fe) |
300-500 |
|
nm |
SEM |
The average size is approximately 300–500 nm |
|
|
|
|
|
|
|
|
7838 |
614 |
PbS NPs@RGO/NiO NSAs |
~16 |
|
nm |
TEM |
Fig. 1D showed the transmission electron microscopy (TEM) image of PbS NPs, which has a diameter about ~16 nm. |
|
|
|
|
|
|
|
|
7839 |
615 |
Pt-Ce6 |
71.5 |
|
nm |
TEM |
From the TEM image (Fig. 1a), the as-prepared Pt NPs exhibit spherical and porous morphology with a diameter of approximately 71.5 nm (Fig. S1a). |
|
|
|
|
|
|
|
|
7840 |
617 |
LM |
~600 |
|
nm |
SEM |
SEM images of LM nanozymes showed its morphologies and sizes, and LM nanozymes possessed an average diameter of ~600 nm. |
|
|
|
|
|
|
|
|
7842 |
619 |
DFHHP |
|
|
|
|
The constructed HMS was ca. 100 nm in diameter (Fig. 1A and B). The average hydrodynamic particle diameters of HMS and DFHHP were ca. 150 nm with a narrow size distribution (Fig. 1E), indicating good dispersion of these nanomaterials in aqueous media. |
|
|
|
|
|
|
|
|
7844 |
622 |
TiO2/Bi2WO6/Ag heterojunction |
200 |
|
nm |
TEM |
After coating the TiO2 hollow nanostructures on the surfaces of SiO2 microspheres with the sol–gel reaction of TBOT and selective etching processes of NaOH, the average sizes were increased to 370 nm (Fig. 1D, E). Fig. S3 showed a typical TEM image of Ag nanocubes with an average size of about 76.2 nm. |
|
|
|
|
|
|
|
|
7845 |
623 |
MnO2 NSs |
|
|
nm |
TEM |
As presented in Fig. 1A, the synthetic MnO2 NSs exhibited an ultrathin 2D sheetlike structure. |
|
|
|
|
|
|
|
|
7846 |
624 |
AMP-Cu |
|
|
|
|
|
|
|
|
|
|
|
|
|
7848 |
626 |
AuPd @MnO2 |
100-150 |
|
nm |
SEM & TEM |
|
|
|
|
|
|
|
|
|
7849 |
627 |
supramolecular Amino acids |
150 |
|
nm |
SEM & TEM |
|
|
|
|
|
|
|
|
|
7850 |
628 |
MIL-100 |
60 |
|
nm |
SEM |
|
538.2 |
|
|
|
|
|
|
|
7852 |
630 |
POMOFs@PDDA-rGO |
8 |
|
μm |
SEM&TEM |
|
|
|
|
|
|
|
|
|
7854 |
634 |
CeO2@MMT |
3.5 |
0.7 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
7855 |
635 |
NEQC-340 |
70-200 |
|
nm |
TEM |
112 |
|
|
|
|
|
|
|
|
7856 |
636 |
MWCNT@MoS2 NS's |
5 |
|
μm |
TEM |
|
|
|
|
|
|
|
|
|
7860 |
640 |
Pd12 nanocage |
|
|
|
|
|
|
|
|
|
|
|
|
|
7863 |
645 |
styrene, 4-styryldi( pentafluorophenyl)borane and 4-styryl-dimesitylphosphine |
17.6 |
|
nm |
DLS |
Average |
|
|
|
|
|
|
|
|
7866 |
648 |
Au/OMCS |
18.2 |
|
nm |
TEM |
Average |
218 |
|
|
|
|
|
|
|
7871 |
655 |
Cu-Carbon dots |
5 |
|
nm |
DLS |
|
|
|
|
|
|
|
|
|
7876 |
659 |
Mn/Ni(OH)x LDHs |
37 |
|
nm |
TEM |
After the LDHs surface coating, Figure 1f,g; and Figure S6 (Supporting Information) reveals a rough surface for these silica rods. The shell thickness of the LDH coated on the silica rods is highly homogeneous with a value of ≈37 nm (Figure 1f). |
|
|
|
|
|
|
|
|
7875 |
659 |
Mn/Ni(OH)x LDHs |
75.9 |
|
nm |
TEM |
After the coating procedure, transmission electron microscope (TEM) image in Figure 1b reveals a rough surface for the colloids, indicating the successful coating a layer of Mn/Ni-LDH on silica colloids. The thickness of the shell is ≈75.9 nm (Figure S2, Supporting Information). |
|
|
|
|
|
|
|
|
7877 |
660 |
Fe3O4/Au NPs |
20.37 |
0.58 |
nm |
TEM |
The particle size of a single particle increases from 8.3 ± 0.25 nm (Fig. S2a) to 20.37 ± 0.58 nm. |
|
|
|
|
|
|
|
|
7878 |
661 |
Fe-SAzyme |
150 |
|
nm |
TEM |
Fig. 1B revealed that the obtained Fe-SAzyme maintained the dodecahedral structure well after pyrolysis from Fe(acac)3@ZIF-8 NPs, and displayed average size of around 150 nm. |
|
|
|
|
|
|
|
|
7881 |
664 |
Au-Pt/SiO |
|
|
|
TEM |
As shown in Fig. S1A, SiO2 NPs are homogenous with good monodispersity. After conjugating with Au NPs (∼5 nm), small black dots are evenly covered on the surface of SiO2 NPs, resulting with the Au/SiO2 hybrids (Fig. S1B). |
|
|
|
|
|
|
|
|
7890 |
673 |
metallo-nanozymes |
175.8 |
41.7 |
nm |
DLS |
TEM image showed that the formed metallo-nanozymes have a spherical morphology with a size of 170 nm (Fig. 1a), which is in agreement with the result obtained from dynamic light scattering (DLS) (175.8 ± 41.7 nm) (Fig. 1b). |
|
|
|
|
|
|
|
|
7893 |
676 |
PBNPs |
150 |
26 |
nm |
SEM |
PBNPs was characterized by SEM to observe the morphology. As shown in Fig. 2A, the PBNPs were well-prepared and in the shape of cubes with an average diameter of 150 ± 26 nm. |
|
|
|
|
|
|
|
|
7896 |
679 |
R-MnCo2O4 |
|
|
nm |
TEM |
Figure 1a,c shows the typical TEM images of the MnCo2O4 and R-MnCo2O4 nanotubes, respectively. Furthermore, three characteristic d-spacing values of approximately 0.25, 0.30, and 0.48 nm are observed in the HRTEM images of the MnCo2O4 nanotubes, which can be ascribed to the (311), (220), and (111) planes, respectively (Figure 1b). |
|
|
|
|
|
|
|
|
7898 |
682 |
Cu-Cys NLs |
|
|
nm |
TEM |
The enlarged image shows that the NLs are approximately 16.2 nm thick (Fig. 1(b)), 450 nm long and 300 nm wide (Fig. 1(c)). |
|
|
|
|
|
|
|
|
7899 |
683 |
BiVO4 |
|
|
nm |
SEM |
It is clear that the flower-like BiVO4 microspheres with uniform structure were assembled from BiVO4 nanosheets and were basically consistent with the description in the literature [26]. |
|
|
|
|
|
|
|
|
7903 |
689 |
Fe@NCDs |
2.6 |
|
nm |
TEM |
The histogram of the particle size distribution (inset in Fig. 1a) reveals that the particle size of the Fe@NCDs ranged from 1.6 to 4.4 nm with an average diameter of 2.6 nm, which is consistent with previously reported for CQDs |
|
|
|
|
|
|
|
|
7904 |
690 |
Cu2+-NMOFs |
350 |
|
nm |
SEM |
The Cu2+-NMOFs are in a good crystal morphology with a uniform size of around 350 nm |
|
|
|
|
|
|
|
|
7905 |
691 |
Fe-doped g-C3N4 nanoflake |
|
|
|
TEM |
The highresolution TEM (HR-TEM) image showed that the lattice fringes with a spacing of 0.329 nm attributed to the classic (002) plane of g-C3N4 |
|
|
|
|
|
|
|
|
7906 |
692 |
CDs |
5–10 |
|
nm |
TEM |
The representative transmission electron microscope (TEM) images showed that both L-CDs and D-CDs had a size distribution of 5~10 nm and clear crystalline cores (Figure S1) |
|
|
|
|
|
|
|
|
7907 |
693 |
Au-Fe2O3 |
|
|
|
|
|
|
|
|
|
|
|
|
|
7908 |
694 |
graphene/Fe3O4-AuNP |
50-70 |
|
nm |
TEM |
The prepared amine magnetic beads were characterized by TEM, FTIR, and XRD. Figure 3a is the TEM image of the amine magnetic beads. It indicates that the prepared magnetic beads have a particle size of 50 to 70 nm and good dispersibility |
|
|
|
|
|
|
|
|
7910 |
696 |
Fe3O4@MnO2 |
250 |
|
nm |
TEM |
The obtained spherical Fe3O4@MnO2 NPs with a core–shell structure had a diameter of roughly 250 nm, as illustrated in the TEM image |
|
|
|
|
|
|
|
|
7911 |
699 |
MCDs-MnO2 NPs |
242.7 |
|
nm |
TEM |
The typical transmission electron microscopy (TEM) image shows Mn2+-doped MNPs were
well dispersed spherical shape with an average diameter of 242.7 nm |
|
|
|
|
|
|
|
|
7913 |
701 |
Hep-Pd NPs |
3–5 |
|
nm |
TEM |
As the [Na2PdCl4]/[Hep] increases to 5, Hep-Pd exhibits dispersive nanoparticles with the mean diameter of 3.5 nm (Fig. 1b). |
|
|
|
|
|
|
|
|
7914 |
702 |
CSA-based nanoparticles |
~300 |
|
nm |
DLS |
The surface morphology of prepared Dox-loaded nanoparticles was further visualized by the electron microscopy (Fig. 2C and D), which showed that prepared nanoparticles displayed uniform spherical structure with the size of ~300 nm in accordance with that of DLS analysis. The uniform spherical structure of CSA-hemin nanoparticles was also validated as shown in Fig. 3C and D. Note that nanocarriers with the size < 400 nm as previously reported is capable to permeate into the tumor tissue through the enhanced permeability and retention effect |
|
|
|
|
|
|
|
|
7915 |
703 |
GO/Ag |
>500 |
|
nm |
TEM |
Nucleation of Ag nanoparticles on GO sheet was not restricted and the resulting anisotropic nanoparticles measured larger than 500 nm (Fig. 2A–F). |
|
|
|
|
|
|
|
|
7916 |
704 |
Au-hematene |
|
|
|
TEM |
A high-resolution TEM image was showed bi-layer hematene with orientation in the
[001] direction, corresponding to the hexagonal symmetry of hematene with lattice parameters =0.50356 nm, =1.37489 nm |
|
|
|
|
|
|
|
|
7917 |
705 |
ATF |
|
|
|
|
Au@TMV nanowire (AT) complex was obtained with diameter of 4 nm and length between 200 and 300 nm. |
|
|
|
|
|
|
|
|
7918 |
706 |
SPB-Pt |
|
|
|
|
The average sizes of Pt nanoparticles measured by TEM image are 5.0±0.7 nm. |
|
|
|
|
|
|
|
|
7920 |
708 |
Mn-MPSA-PCC |
|
|
|
|
|
|
|
|
|
|
|
|
|
7921 |
709 |
HA-PB NPs |
|
|
|
TEM |
The particle size and zeta potential of HA-PB/ICG were ∼295 nm (Fig. 3B) and −27.1 mV (Fig. 3C), respectively |
|
|
|
|
|
|
|
|
7922 |
710 |
LaMNPs-PEG |
71 |
|
nm |
DLS |
The HD and potential of LaMNPs-PEG were about ~71 nm and ~-27.3 mV by dynamic light scattering (DLS) |
|
|
|
|
|
|
|
|
7923 |
711 |
DhHP-6-c-ZrMOF |
250-300 |
|
nm |
SEM |
the average particle diameter of DhHP-6-c-ZrMOF was observed around 250-300 nm from FE-SEM images |
246.27 |
|
|
|
|
|
|
|
7924 |
712 |
hemin-GroEL |
445 |
|
nm |
DLS |
In concentrated suspensions, the hydrodynamic diameter in the fraction of smaller particles
was 445 nm |
|
|
|
|
|
|
|
|
7925 |
713 |
SOD-Fe0@Lapa-ZRF |
176 |
± 6.3 |
nm |
TEM |
The average diameters of ZIF-8 and SOD-Fe0@Lapa-Z were 149 ± 7.8 nm and 176 ± 6.3 |
1191.9 |
|
|
|
|
|
|
|
7926 |
715 |
gCuHCF |
|
|
|
SEM |
|
|
|
|
|
|
|
|
|
7927 |
717 |
Fe2O3/CNTs |
|
|
|
TEM |
It is obvious that these nanoparticles are uniformly distributed with diameter of around 1 nm. When 15 cycles of Fe2O3 were applied, a higher density of nanoparticles with larger size of around 2 nm on CNTs was observed both in HRTEM (Figure 1E) and HAADF (Figure 1F) images. |
|
|
|
|
24.5 |
|
U/mg |
|
7930 |
719 |
Fe-BTC |
77 |
|
nm |
AFM |
AFM characterization shows that the average thickness of the 2D Fe-BTC nanosheets was about 77 nm |
|
|
|
|
|
|
|
|
7929 |
719 |
Fe-BTC |
|
|
|
SEM |
The size of Fe-BTC was about 2.6 μm × 2.1 μm (length × width |
|
|
|
|
|
|
|
|
7932 |
722 |
PtNPs@MWCNTs |
~3.3 |
|
nm |
TEM |
The solid PtNPs are distributed on the outer surface of MWCNTs (Fig. 1b and d), with an average particle diameter of ∼3.3 nm |
101.4 ± 0.4 |
|
|
|
|
|
|
|
7933 |
723 |
dex-MoSe2 NS |
|
|
|
|
AFM measurement was carried out to confirm the ultrathin structure of dex-MoSe2 (Fig. S1, ESI†). The height of (1–3) nm indicates that the thickness of MoSe2 is nearly one to two single layers (Fig. S1B, ESI†). The TEM images and SAED pattern of dex-MoSe2 in Fig. S2 (ESI†) reveal that the dex-MoSe2 NSs retain a lattice spacing of (0.280 ± 0.005, n = 3) nm, which matches the d-spacing of the (100) plane of 2H-MoSe2, indicating that the inherent 2H phase is still retained after exfoliation and functionalization in the dextran solution.20 The dex-MoSe2 was measured by dynamic light scattering (DLS, Fig. 1B and Fig. S3, ESI†) which shows that the average hydrodynamic size was about (62.8 ± 1.4, n = 3) nm and the zeta potential was −23.70 mV in water. |
|
|
|
|
|
|
|
|
7934 |
724 |
Cu@MOR |
|
|
|
|
Fig. S1 (Supporting information) and Fig. 2 present the SEM images of the samples. The MOR zeolite exhibited morphology of fused crystallites in μm-scale. |
|
|
|
|
|
|
|
|
7935 |
725 |
laccase@Fe-BTC/NiFe2O4-MT |
|
|
|
|
Fig. S7† shows the pore distributions of NiFe2O4-MT, Fe-BTC/NiFe2O4-MT and laccase@Fe-BTC/NiFe2O4-MT (2–10 nm). For laccase@Fe-BTC/NiFe2O4-MT, irregular spherical particles with an average grain size of 100 nm were uniformly grown on the surface of the interlaced NiFe2O4 nanosheets (Fig. 2d–f). As shown in Fig. 3b–f, a large number of tiny nanoparticles with a grain size ranging from 5 to 10 nm were encapsulated in spherical nanoparticles with a mean grain size of 80 nm. Small cavities with a size ranging from 5 to 10 nm were observed. |
160 |
|
|
|
329.2 |
|
U/g |
|
7936 |
726 |
NH2-MIL-88B(Fe)-Ag |
~300 |
|
nm |
SEM |
As shown in Figure 1B, the SEM revealed that NH2-MIL-88B(Fe)-Ag was produced with the morphology of fusiform and length of ∼300 nm, identical to that of NH2- MIL-88B(Fe) in Figure 1A. |
|
|
|
|
|
|
|
|
7938 |
728 |
GOx@MOF |
|
|
|
|
The SEM and TEM images (Fig. 1A and B) showed the plate-like structure of the obtained Cu-MOF, which agreed well with the previous work. |
|
|
|
|
|
|
|
|
7939 |
729 |
Ags-APMSNs |
126.9 |
1.5 |
nm |
DLS |
Pt nanodots with sizes of 2–3 nm formed a nanoisland shell on Au NRs from the transmission electron microscopy (TEM) image (Figure 2B). The average thickness of the mesoporous SiO2 layer surrounding the Au@Pt NR was around 25 nm (Figure 2C). The DLS results revealed that the effective diameter of Au NRs, Au@Pt NRs, and APMSNs with CTAB template were 17.1 ± 0.6, 46.0 ± 0.5, and 100.6 ± 0.7 nm, respectively. Table 1 further showed that the effective diameter of the APMSNs increased evidently from 92.1 to 126.9 nm after antigen conjugation process. |
|
|
|
|
|
|
|
|
7942 |
733 |
Ti3C2 |
103 |
|
nm |
AFM |
The AFM image (Fig. 1D)provides a relatively precise thickness of the Ti3C2nanosheetsat around 5 nm and the diameter is mainly distributed in35–155 nm with the average size of 103 nm (Fig. S1, ESI†). |
|
|
|
|
|
|
|
|
7946 |
737 |
H-MnFe(OH)x |
80 |
|
nm |
TEM |
The as-prepared H-MnFe(OH)x nanocapsules show a particle size of around 80 nm with high uniformity (Figure 2b). Magnifie image reveals the rough surface of H-MnFe(OH)x with a shell thickness of about 10 nm (Figure 2c). |
165.4 |
|
|
|
|
|
|
|
7947 |
738 |
LIPIA |
|
|
|
|
AFM images of the assemblies formed by LIPIA 1 showed left-handed twisted nanoribbons with a regular pitch of 9.1 nm and a height of 8.9 nm, whereas LIPIA 2 assembled into flat nanoribbons with a height of 9.2 nm (Figure 1, A and B). TEM images showed that LIPIA 2 formed flat nanoribbons with an average width of 12.1 nm (Figure 1D). |
|
|
|
|
|
|
|
|
7949 |
739 |
PSMA |
|
|
|
TEM |
As shown in Figure 2C and 2D, PSMA nanofibers with diameters of 660 nm could be produced with a 10 wt% polymeric solution, 15-kV voltage, 1-mL/h feeding rate, and 16-cm working distance. |
|
|
|
|
|
|
|
|
7948 |
739 |
QG |
|
|
|
TEM |
the size of a single QG particle is smaller than 1 nm, which would make a single particle very difficult to observe using high-resolution transmission electron microscopy (HRTEM). |
|
|
|
|
|
|
|
|
7951 |
740 |
SP-SPIO-IR780 |
44.97 |
10.12 |
nm |
TEM |
the diameter of the SP-SPIO-IR780 nanoparticles was 44.97 ± 10.12 nm (PDI = 0.225) |
|
|
|
|
|
|
|
|
7952 |
740 |
SPA-SPIO-IR780 |
53.01 |
9.54 |
nm |
TEM |
it was about 53.01 ± 9.54 nm (PDI = 0.180) for SPA-SPIO-IR780 |
|
|
|
|
|
|
|
|
7950 |
740 |
SPIO |
9.83 |
1.88 |
nm |
TEM |
As shown in Fig. 1A, SPIO nanocrystals were monodispersed with a size around 9.83 ± 1.88 nm and the polydispersity index (PDI) was about 0.191. |
|
|
|
|
|
|
|
|
7954 |
742 |
Pdots |
22.64 |
|
nm |
DLS |
Fig. 1A shows that the PFO Pdots synthesized via a nanoprecipitation method are approximate spheres with an average diamete of 22.64 nm. |
|
|
|
|
|
|
|
|
7955 |
743 |
TM |
390 |
|
nm |
DLS |
The surfaces of TM with an average size of 390 nm were functionalized using the non-ionic surfactant Span60 (Fig. S2, see Experimental Section, ESI†). |
|
|
|
|
|
|
|
|
7956 |
743 |
ADH/GOx@TM |
|
|
|
SEM |
the images showed a hollow interior with a continuous mineral membrane of 8-μm average thickness. The polydispersity in the size of microcapsules was distributed in the range of 90–200 μm, depending on the water/oil volume fraction (Fig. 1h). |
|
|
|
|
|
|
|
|
7958 |
745 |
Pt/WO2.72 |
|
|
|
TEM |
The height and width of the as-formed WO2.72 nanoplates were 10–25 nm and 20–50 nm, respectively. The Pt nanoparticle surfaces were predominantly spherical, with average sizes of 10–15 nm. The high-resolution TEM (HRTEM) image in Fig. 1c revealed distinct lattice fringes of 0.317 nm, 0.378 nm, and 0.294 nm, corresponding to the (010), (004), and (402) lattice planes of WO2.72 nanoplates, respectively. Distinct lattice fringes of 0.226 nm and 0.196 nm corresponded to the (111) and (200) lattice planes of Pt nanoparticles, respectively. |
|
|
|
|
|
|
|
|
7959 |
747 |
2D Co3O4@Rh NC |
4–6 |
|
nm |
TEM |
Rh Nanoparticles |
|
|
|
|
|
|
|
|
7962 |
751 |
BP/Pt-Ce6@PEG NSs |
~84.3 |
|
nm |
TEM |
As shown in Fig. 2a and 2b, BP NSs are observed to be separated nanosheets with ~84.3 nm lateral dimension. According to atomic force microscopy (AFM, Fig. 2c), the average thickness of BP NSs is calculated to be ~1.4 nm. |
|
|
|
|
|
|
|
|
7964 |
753 |
Au/Cu2O |
800 |
|
nm |
SEM |
It can be seen that the Cu2O NMs are made up of numerous regular and well–defined cube–like structures with average size of about 800 nm. |
|
|
|
|
|
|
|
|
7966 |
755 |
COF-AI-ECL |
200-300 |
|
nm |
SEM |
SEM imaging (Fig. 2A) revealed that the microscopic morphology of the COF-AI-ECL material had a cross-linked and hollow frame consisting of vermicular structures with diameters of 200–300 nm |
|
|
|
|
|
|
|
|
7967 |
756 |
MNP-bacteria-MnO2@GOx complexes |
1.2 |
|
μm |
TEM |
As shown in Fig. 2a, the BSA@MnO2 NPs are homogeneous and monodispersed with the average size of ~4 nm.As shown in Fig. 2b, the MnO2@GOx NFs are monodispersed with the average size of ~1.2 μm and have an obvious flower morphology, indicating successful synthesis of the MnO2@GOx NFs. |
|
|
|
|
|
|
|
|
7969 |
759 |
AuNP–CeO2 NP@GO |
|
|
|
SEM |
From the SEM images, we observed a combination of clumped particles of AuNP–CeO2 NPs spread across the surface of crumpled flaky sheets of stacked, folded and wrinkled GO. The observed morphological feature provides a strong affirmation that AuNP–CeO2 NPs were effectively anchored onto GO nanosheets |
|
|
|
|
|
|
|
|
7970 |
760 |
2Arg@FeOOH |
300 |
|
nm |
SEM |
2Arg@FeOOH and 5Arg@FeOOH have sheet-like structure with a diameter of about 300 nm |
|
|
|
|
|
|
|
|
7972 |
763 |
Co3O4-Au polyhedron |
550 |
|
nm |
SEM |
Fig. 3A shows that the obtained ZIF-67 precursor is a uniform diamond-shaped dodecahedron and the average size of it is about 550 nm. |
86.9 |
|
|
|
|
|
|
|
7974 |
766 |
nanoceria-PTA*-AuNPs |
26.77 |
5.1 |
nm |
TEM |
CeO2 |
|
|
|
|
|
|
|
|
7973 |
766 |
nanoceria-PTA*-AuNPs |
59.65 |
30.46 |
nm |
TEM |
PTA-Au NPs |
|
|
|
|
|
|
|
|
7975 |
768 |
Co3O4 HNCs |
100-400 |
|
nm |
TEM |
|
121.2 |
|
|
|
|
|
|
|
7976 |
769 |
UiO-66-Fc |
200 |
|
nm |
TEM |
As shown in Fig. 1b, UiO-66-NH2 exhibits a regular polyhedral shape with an average size of 200 nm. DSL analysis showed that the size distribution is from 100 to 300 nm |
|
|
|
|
|
|
|
|
7979 |
773 |
(CS-Cu-GA NCs |
30 |
|
nm |
TEM |
Further, the microstructure of the fabricated CS-Cu-GA NCs was observed by SEM and TEM (Fig. 1a), and the results revealed their sphere-like structure with a size of about 30 nm. |
|
|
|
|
|
|
|
|
7981 |
775 |
MPBzyme@NCM |
|
|
nm |
TEM |
Transmission electron microscope (TEM) and scanning electron microscope (SEM) images showed angular cube-like irregular morphology |
104.5 |
|
|
|
|
|
|
|
7982 |
776 |
Ti8-Cu2 |
|
|
μm |
SEM |
Transmission electron microscopy (TEM) and scanning electron microscope (SEM) indicated that Ti8-Cu2 maintained the disk-like morphology of Ti8-OH of ∼1 μm in diameter and ∼0.4 μm in thickness |
1245 |
|
|
|
|
|
|
|
7988 |
780 |
CuS-BSA-Cu3(PO4)2 |
10 |
|
nm |
TEM |
Conjugation of Cu3(PO4)2 with CuS-BSA generates CuS-BSA-Cu3(PO4)2 nanoparticles (NPs) of 10 nm in size with high catalytic activity against a peroxidase substrate, 3,3′,5,5′-tetramethylbenzidine (TMB). |
|
|
|
|
|
|
|
|
7992 |
781 |
PtDENs |
21.2 |
0.7 |
nm |
DLS |
Moreover, the size of mAb-PtDEN-GOD (34.3 ± 1.6 nm) (Fig. 1f, bottom) was obviously more than that of PtDENs (21.2 ± 0.7 nm) (Fig. 1f, top) on the basis of DLS data |
|
|
|
|
|
|
|
|
7989 |
781 |
mAb-PtDEN-GOD |
28 |
|
nm |
TEM |
To tackle this shortcoming, the as-prepared mAb-PtDEN-GOD conjugates were characterized by TEM after negative staining with sodium phosphotungstate (2.0 wt%, pH 7.3) (note: not good for negative staining of dendrimers). As seen from Fig. 1d, a layer of translucent structures was coated on the nearly spherical dendrimers, and the mean size was ~ 28 nm in diameter. |
|
|
|
|
|
|
|
|
7990 |
781 |
PtNPs |
2.3 |
|
nm |
TEM |
Figure 1c shows high-resolution transmission electron microscope (HRTEM) of the as-synthesized PtDENs. It is found that many PtNPs were distributed in the dendrimers, and the average size of nanoparticles was ~ 2.3 nm in diameter. |
|
|
|
|
|
|
|
|
7991 |
781 |
mAb-PtDEN-GOD |
34.3 |
1.6 |
nm |
DLS |
Moreover, the size of mAb-PtDEN-GOD (34.3 ± 1.6 nm) (Fig. 1f, bottom) was obviously more than that of PtDENs (21.2 ± 0.7 nm) (Fig. 1f, top) on the basis of DLS data |
|
|
|
|
|
|
|
|
7993 |
782 |
the (420) plane of the MnO2 |
0.219 |
|
nm |
TEM |
The distinct lattice fringe with interplanar spacing of 0.219 nm in high-resolution transmission electron microscope (HRTEM), which was consistent with the (420) plane of the MnO2 |
|
|
|
|
|
|
|
|
7994 |
783 |
CeO2/CePO4 |
8 |
|
nm |
SEM |
However, the low crystallite size of CeO2 (~2 nm) and the particle size of the nanocomposite (~8 nm) observed in the SEM image (Fig. 1b) resemble that polycrystalline growth might be favored upon annealing of the as-synthesized nanocomposites [47]. |
|
|
|
|
|
|
|
|
7995 |
784 |
AuPt@SF (APS) |
|
|
|
|
In addition, the hydrodynamic size and polydispersity index (PDI) of the nanozyme were 120.3 nm and 0.259, respectively, which is within the valid size range (50-200 nm) for the enhanced permeation and retention (EPR) effect |
97.254 |
|
|
|
|
|
|
|
7997 |
785 |
Cu-hemin MOF |
|
|
|
|
|
27.13 |
|
|
|
|
|
|
|
7996 |
785 |
GOD@ Cu-hemin MOFs |
|
|
μm |
SEM |
The diameter of GOD@Cu-hemin MOF ranges from 6.75 to 7.75 μm (Inset). Furthermore, there are lots of large pores with different size in the GOD@Cu-hemin MOF, which is benefit for the mass transfer. |
50.06 |
|
|
|
|
|
|
|
8000 |
789 |
NiMn LDH |
23 |
|
nm |
TEM |
The lateral size of the LDH nanosheets estimated from the TEM image ranges from 10 to 36 nm with a mean value of 23 nm |
|
|
|
|
|
|
|
|
8001 |
790 |
FePOs |
|
|
nm |
DLS |
The average hydrodynamic diameter (Dh) of FePOs measured by DLS was approximately 420 ∼ 430 nm |
|
|
|
|
|
|
|
|
8003 |
792 |
Dex-IONP-GOx |
7.3 |
0.9 |
nm |
TEM |
Their average core diameter was found to be 7.3 ± 0.9 nm (Fig. 2a). |
|
|
|
|
|
|
|
|
8004 |
793 |
g-C3N4/hemin/Au |
180 |
|
nm |
TEM |
The bare g-C3N4 has thin nanosheets with irregular shapes in Fig. S1, and the average size of nanosheets is around 180 nm. |
|
|
|
|
|
|
|
|
8006 |
796 |
CuS-BSA-Cu3(PO4)2 |
54-143 |
|
nm |
DLS |
Indeed, the surface charge of CuS-BSA changed from −26 ± 2.8 mV to −29 ± 2.6 mV upon incorporation of Cu3(PO4)2, while the diameter increased from 54 nm up to 143 nm. |
|
|
|
|
|
|
|
|
8007 |
797 |
Au25(p-MBSA)18 |
4.2 |
|
nm |
DLS |
In a pH 9 aqueous solution, the hydrodynamic diameter of Au25(p-MBSA)18 is about 4.2 nm, which is larger than that of Au25(p-MBA)18 (about 3.0 nm). |
|
|
|
|
|
|
|
|
8009 |
799 |
Ce/ZnCo2O4 |
500 |
|
nm |
SEM |
Clearly, the size of Ce/ZnCo2O4 (ca. 500 nm) is slightly larger than that of pure ZnCo2O4 (ca. 320 nm), due to the Ce-doping in the synthesis process of Ce/ZnCo2O4 nanocomposites. |
|
|
|
|
|
|
|
|
8011 |
801 |
CSPQ@CM |
3 |
0.3 |
nm |
TEM |
The obtained Cu2–xSe nanoparticles were 3.0 ± 0.3 nm in size (Figure S1a–b of the Supporting Information) and exhibited excellent colloidal stability. |
|
|
|
|
|
|
|
|
8013 |
806 |
CD44MMSN/AuNPs |
|
|
|
|
|
417.39 |
|
|
|
|
|
|
|
8019 |
814 |
AuNPs/Cu-TCPP(Fe) |
|
|
|
|
We have optimized the uniformity of gold nanoparticles and calculated the size distribution histogram of AuNPs (as shown in Figure S3). Through the histogram, we found that the size of the collected AuNPs was mainly in the range from 2.4 to 4.8 nm, possessing superior glucose oxidase (GOx)-like activity. |
318 |
|
|
|
|
|
|
|
8020 |
815 |
PANI@MoS2@Fe3O4/Ag, Au, Pd |
|
|
|
|
|
39.2 |
|
|
|
|
|
|
|
8021 |
816 |
Fe3O4@Cu/GMP–GOx |
242 |
23 |
nm |
SEM |
After the formation of Cu/GMP–GOx on its surface, Fe3O4@Cu/GMP–GOx still maintained the spherical structure with a smooth surface, and the mean diameter was 242 ± 23 nm (Figure 1a). |
|
|
|
|
|
|
|
|
8025 |
825 |
Cu-hemin-MOF |
6 |
|
μm |
SEM |
As shown in Fig. 2a, Cu-hemin-MOF presents 3D ball-flower shape with the dimension of about 6 μm. |
|
|
|
|
|
|
|
|
8027 |
827 |
NDs |
5.5 |
|
nm |
TEM |
TEM images indicated that the original NDs and the two kinds of oxygenated O-NDs were highly homogeneous, and the size of nanoparticles was 2–10 nm with an average size of 5.5 nm |
|
|
|
|
|
|
|
|
8028 |
828 |
Pt/CoFe2O4 |
34 |
|
nm |
TEM |
As can be seen from Fig. 3a, Pt/CoFe2O4 nanospheres with 34 nm in dimeter, which are composed of much smaller nanoparticles with size of 4.5 nm. |
|
|
|
|
|
|
|
|
8029 |
829 |
NiMn2O4/C NLM |
|
|
|
SEM |
Fig. 1c, the thickness of the NiMn2O4 layer on the carbon surface is about 200 nm. |
|
|
|
|
|
|
|
|
8032 |
833 |
Pt/CdS |
|
|
|
TEM |
It is found that the rod-like morphology of Pt/CdS with the width range from 20 to 70 nm. |
|
|
|
|
|
|
|
|
8033 |
835 |
AuVCs |
26.5 |
0.80 |
nm |
TEM |
The morphology of VLPs and AuVCs were first characterized using transmission electron microscopy (TEM); no obvious difference in morphology was observed between them, but the diameter of the AuVCs was slightly decreased to 26.50 ± 0.80 nm compared with VLPs (28.90 ± 0.90 nm). |
|
|
|
|
|
|
|
|
8035 |
837 |
FeSe2/Dox@Chi@Gel NCs |
220 |
|
nm |
TEM |
The obtained FeSe2 hedgehogs are uniform in size, and the mean diameter is about ∼220 nm. Each FeSe2 hedgehog possesses dozens of hollow branches/spikes radially extending from the particle center to the exterior.The spikes are ∼70–100 nm in length, 10–15 nm in diameter, and ∼2 nm in wall thickness. The size of FeSe2 hedgehogs can be effectively tuned in the range of about 220–1300 nm. |
438 |
|
|
|
|
|
|
|
8034 |
837 |
FeSe2/Dox@Chi@Gel NCs |
220 |
|
nm |
SEM |
The obtained FeSe2 hedgehogs are uniform in size, and the mean diameter is about ∼220 nm. Each FeSe2 hedgehog possesses dozens of hollow branches/spikes radially extending from the particle center to the exterior.The spikes are ∼70–100 nm in length, 10–15 nm in diameter, and ∼2 nm in wall thickness. The size of FeSe2 hedgehogs can be effectively tuned in the range of about 220–1300 nm. |
438 |
|
|
|
|
|
|
|
8037 |
839 |
Fe@ZIF-8@GOx NRs |
635 |
180 |
nm |
DLS |
The obtained Fe@ZIF-8@GOx NRs showed an average size of 635 ± 180 nm in DMEM/10%FBS, which is larger than that measured from SEM images. |
|
|
|
|
|
|
|
|
8038 |
841 |
Fe3O4/MGO |
4 |
|
nm |
TEM |
The prepared Fe3O4 crystals shows the feature of irregular particles with ca. 4 nm size. |
1.47 |
|
|
|
|
|
|
|
8039 |
843 |
GOx–Fe3O4@SHS |
3 |
1 |
μm |
DLS |
The hydrodynamic particle size distribution was in the range of 2–4 μm. |
270.138 |
|
|
|
|
|
|
|
8040 |
843 |
GOx–Fe3O4@SHC |
3 |
1 |
μm |
DLS |
The DLS study showed the size distribution of the particle in the range 2–4 μm. |
302.561 |
|
|
|
|
|
|
|
8042 |
845 |
CuS QDs/Co3O4 Polyhedra |
5 |
|
nm |
TEM |
The CuS QDs had a uniform distribution on the Co3O4 polyhedra surface (Figure 2A, B) with a diameter of 5 nm.The ZIF-67 exhibited a regular rhombic dodecahedral structure with a smooth surface over the whole particle and had an average size of 450 nm. The Co3O4 presented a very rough polyhedra shape, and the size average reduces to 300 nm due to the slight contraction caused by the calcination process. |
487.67 |
|
|
|
|
|
|
|
8044 |
848 |
sulfuration-engineered CoOx |
|
|
|
|
|
32.85 |
|
|
|
|
|
|
|
8045 |
849 |
DMNF/DMNS and MNFPPL |
315 |
15 |
nm |
TEM |
MNF was spiny nanoparticle (about 300 nm ~ 330 nm) assembled by 3D-stacking nanosheets with porous structure. |
|
|
|
|
|
|
|
|
8046 |
850 |
PCN-222(Mn) |
|
|
|
|
|
2217 |
|
|
|
|
|
|
|
8047 |
853 |
Fe-CDs |
2.1 |
0.7 |
nm |
DLS |
All the particle sizes are less than 10 nm, which is a typical characteristic of CD size, and the particle sizes are mainly distributed in the range of 1.6–2.8 nm, so the Fe-CDs have a large specific surface area. |
|
|
|
|
|
|
|
|
8048 |
854 |
CeO2/Pt@cZVs |
58 |
|
nm |
TEM |
The additional TEM image disclosed the maintenance of cZVs in morphology with an average size of ∼58.0 nm by DLS measurement. |
|
|
|
|
|
|
|
|
8049 |
855 |
FeS2@C NSs |
107 |
12 |
nm |
DLS |
According to the size distribution of the FeS2 NPs shown in Figure S1e (Supporting Information), the diameters of the nanoparticles lied in the range of 94–120 nm. |
91.93 |
|
|
|
|
|
|
|
8051 |
857 |
Fe3O4@Au@cDNA@H-GN |
250 |
125 |
nm |
SEM |
The particle size of the Fe3O4 MNPs ranges from 125 to 375 nm. It is obvious that Au NPs (~4 nm, Fig. 1C inset) attach and distribute densely on the surface of Fe3O4 NPs. |
|
|
|
|
|
|
|
|
8052 |
858 |
ZnCd QDs |
4 |
1 |
nm |
DLS |
Size distribution of ZnCd QDs in range 3–5 nm after 2 (blue), 4 (red) and 8 (green) min UV irradiation and respective zeta potential in range the −20 to −40 mV |
|
|
|
|
|
|
|
|
8053 |
859 |
Co3O4-g-C3N4 |
115 |
85 |
nm |
SEM |
The SEM images of higher magnification (Figs. S2e and f) reveal that the xCo3O4-g-C3N4 samples are with particle sizes ranging from 30 to 200 nm, and are higher than g-C3N4 in terms of sheet number and surface area. |
|
|
|
|
|
|
|
|
8054 |
860 |
Au–Ag–GOx HTNs |
60 |
|
nm |
TEM |
As shown in TEM image and scanning electron microscopy (SEM) image (Fig. 1(a) and Fig. S1 in the Electronic Supplementary Material (ESM)), well-distributed Ag nanoprisms were prepared successfully with the thickness of around 10 nm (inserted image). Next, the Au–Ag HTNs were prepared by galvanic replacement reaction. The as-prepared Au–Ag HTNs displayed well-maintained shape of Ag nanotemplates with the average size of 60 nm. |
|
|
|
|
|
|
|
|
8055 |
861 |
g-CNOX |
|
|
|
XRD |
The strong XRD peak at 27.1° (2θ), corresponding to an interlayer distance of d = 0.328 nm |
|
|
|
|
|
|
|
|
8058 |
863 |
NER |
125 |
|
nm |
DLS |
Its size and zeta potential were about 125 nm ( Supporting Information Figure S2, black curve) and −27.9 mV (Figure 1d, black curve), as measured by DLS. |
|
|
|
|
|
|
|
|
8059 |
864 |
2D Cu-TCPP nanofilm |
|
|
μm |
TEM, SEM |
|
|
|
|
|
|
|
|
|
8060 |
865 |
Fe3O4@PPy MIPs |
25-35 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8064 |
869 |
Ag-Pt/rGO |
20 |
|
nm |
TEM |
spherical Ag-Pt NPs with the size of about 20 nm (n = 50) are well dispersed on the surface of rGO. |
|
|
|
|
|
|
|
|
8066 |
871 |
Cu-MOF |
|
|
|
TEM, SEM |
The morphology of prepared Cu-MOF NPs was characterized by TEMand SEManalysis. As displayed in Fig. 2a, b, the Cu- MOF NPs have a spherical shape with uniform particle distribution. |
|
|
|
|
|
|
|
|
8069 |
874 |
IONPs |
80 |
|
nm |
TEM,DLS |
DLS and NTA measurements showed that the Dh of the dispersion was approximately 80 nm with a broad particle size distribution. |
|
|
|
|
|
|
|
|
8070 |
875 |
DMSN-Au NP |
17.7 |
|
nm |
TEM |
|
407.8875 |
|
|
|
|
|
|
|
8071 |
876 |
Co4S3/Co(OH)2 HNTs |
|
|
|
TEM, SEM |
|
|
|
|
|
|
|
|
|
8072 |
877 |
ZIF-67/Cu0.76Co2.24O4 NSs |
100 to 250 |
|
nm |
TEM |
SEM and TEM images are shown in Figure 1B,C with the size range of about 100−250 nm |
|
|
|
|
|
|
|
|
8073 |
878 |
N/Cl-CDs |
2 to 6 |
|
nm |
TEM |
All the particles appeared in a quasispherical shape within a diameter of 2 to 6 nm |
|
|
|
|
|
|
|
|
8075 |
880 |
Fe3O4@PAA/TMC/PEG |
100 |
|
nm |
TEM |
Figure 1 showed the TEM images of Fe3O4 NPs, Fe3O4@PAA/PEG/CS NPs and Fe3O4@PAA/TMC/PEG NPs. The Fe3O4 NPs (Figure 1(A)) exhibited a rough surface with the diameter of 100 nm, |
|
|
|
|
|
|
|
|
8079 |
884 |
NL-MnCaO2 |
|
|
nm |
TEM, SEM |
morphological studies of the prepared oxides were carried out using SEM and TEM. The SEM and TEM images are shown in Fig. 1C and 1D. These images represent aggregated nanoparticles and morphology similar to a crumpled paper. |
|
|
|
|
|
|
|
|
8080 |
885 |
HGNs-Apt |
|
|
|
SEM |
shows the morphology of HGNs-Apt immobilized on the surface of SPCE. A decrease in spherical particles is observed, indicating that HGNs-Apt are successfully formed. |
|
|
|
|
|
|
|
|
8081 |
886 |
Co3Fe-MMOF |
3.4 |
|
μm |
SEM |
he length size of the Co3Fe-MMOF nanodiamond is about 3.4 µm, |
|
|
|
|
|
|
|
|
8083 |
888 |
GLAD Ni film |
610 |
|
nm |
SEM |
The final thickness of the Ni GLAD film was 610 nm as measured on a cleaved sample in a cross-sectional view by scanning electron microscopy (SEM, Hitachi S-4800). |
|
|
|
|
|
|
|
|
8085 |
890 |
ML-MoOx |
500 |
|
nm |
TEM |
As shown in Figure 1b−d, the as-prepared MoOx appears to be ultrathin roseshaped flowers with an average size of 500 nm which are different from the bulk MoO3 (labeled as b-MoO3) with traditional rectangle-like nanobelt morphology |
15m2 g−1 |
|
|
|
|
|
|
|
8086 |
892 |
PB@Cyt c composite |
50 |
|
nm |
SEM |
Scanning electron microscopy (SEM) images of PB itself exhibited as nanocubes with a size of ~ 50 nm (Figure 1e), which is consistent with the previous report |
|
|
|
|
|
|
|
|
8091 |
899 |
hemin@UiO-66-NH2 |
100―190 |
|
nm |
TEM |
Fig.2 SEM(A, B) and TEM images(C, D) of UiO-66- NH2(A, C) and hemin@UiO-66-NH2(B, D) |
|
|
|
|
|
|
|
|
8093 |
901 |
DHPC@CS-AgNPs |
|
|
|
SEM |
The electron microscopy scanning results of DMC, DHPC andDHPC@CS are shown inFig. 2. The pores of DMC are evenly dis-tributed and the size is large. |
|
|
|
|
|
|
|
|
8096 |
904 |
Niosome-MnO-DTPA-PP(IX) |
78.33 |
19.59 |
nm |
DLS |
78.33 19.59 for Niosome-MnO-DTPA-PP(IX) as shown in Figure 2 and Table 1. |
|
|
|
|
|
|
|
|
8097 |
905 |
biochar-based carbonaceous materials |
<100 |
|
nm |
|
The biochar peroxidase-like activity also depends on the particle size, as documented in Fig. 2b for maize cob (MC) biochar. As expected, smaller biochar particles exhibit higher activity. A similar situation was also observed in the case of nanomaterials mimicking peroxidases; this phenomenon may be due to the smaller particles having a greater surfaceto-volume ratio to interact with their substrates. This observation suggests that selective fabrication of peroxidase-like materials with diferent size and shape is very important to modulate their catalytic activities (Jv et al. 2010; Peng et al. 2015). |
|
|
|
|
|
|
|
|
8098 |
906 |
MNPs |
10 |
3 |
nm |
TEM |
The analysis of particles via TEM and SEM proved a narrow particle size distribution with the diameter of crystallites 10 ± 3 nm. (Figure 2B,C). |
|
|
|
|
|
|
|
|
8101 |
909 |
Tungsten Disulfide Quantum Dots |
4.0-6.0 |
|
nm |
TEM |
The inset of Figure 1a shows the high-resolution transmission electron microscopy (HR-TEM) image of functionalized quantum dots, which shows nearly spherical-shaped & well-dispersed quantum dots having an average particle size of 4–6 nm. |
|
|
|
|
|
|
|
|
8102 |
910 |
hollow mesoporous silica nanosphere-supported nanosized platinum oxide |
150 |
|
nm |
TEM |
The TEM images of PtOx@MMT-2 (Fig. 1b and c) revealed that MMT-2 were ~150 nm in size and that PtOx NPs with dark image contrast were well dispersed in the thin mesoporous silica shell |
|
|
|
|
|
|
|
|
8106 |
914 |
MnO2@Au |
100 |
|
nm |
TEM |
The transmission electron microscope (TEM) images demonstrated Au nanoparticles (Au NPs) in situ grown in ∼100 nm of MnO2 nanosheets (Fig. 1B). The elemental mapping images of MnO2@Au confirmed the coexistence of Mn, O, C, N and Au elements (Fig. 1C). |
|
|
|
|
|
|
|
|
8107 |
915 |
UiO-66(Fe/Zr)-NH2 |
2.0-3.0 |
|
μm |
SEM |
|
|
|
|
|
|
|
|
|
8109 |
917 |
BSA-MnO2/IR820@OCNC |
100 |
|
nm |
TEM |
Transmission electron microscopy (TEM) was used to confirm the structures of the various nanomaterials. The CNCs appeared as hollow nanoscale structures, which explains their high loading capacity (Fig. 1B). Furthermore, significant particle aggregation was observed in the TEM image; this was attributed to their poor hydrophilicity. BSA-MnO2 nanoparticles were generally spherical and well dispersed, with a uniform particle size (Fig. 1C). After attaching abundant carboxyl groups to the surface of the CNCs, loading with IR820, and decorating with BSA-MnO2, the BMIOC nanosystem was successfully obtained (Fig. 1D and E). |
|
|
|
|
|
|
|
|
8110 |
918 |
Prussian blue (PB) |
|
|
|
|
|
|
|
|
|
|
|
|
|
8114 |
922 |
Ru/PC |
1.46 |
|
nm |
TEM |
This has been firmly demonstrated by the transmission electron microscopy (TEM) image (Fig. 1b), in which plenty of Ru NPs with a small size (1.46 nm, Fig. 1c) are highly dispersed on the surface of the PC without obvious aggregation after the electroless deposition process. |
|
|
|
|
|
|
|
|
8117 |
925 |
AuNPs |
30 |
|
nm |
TEM |
As shown in Fig. 2C, the red-colored AuNP@β-CD with an average diameter of ∼30 nm and distinct lattice showed unique dispersion performance in the absence of Hg2+. |
|
|
|
|
|
|
|
|
8121 |
1058 |
MoS2@CoFe2O4 |
450-650 |
|
nm |
DLS |
Besides, the particle size distribution assay demonstrated the diameter of the MoS2@CoFe2O4 mainly focuses on 450~650 nm, which is equal to the sum of the main diameters of MoS2 and CoFe2O4 (Fig. S4). |
|
|
|
|
|
|
|
|
8122 |
1059 |
MAF-5-CoII NS |
|
|
|
|
|
1155 |
|
|
|
|
|
|
|
8124 |
1061 |
apt-Fe3O4/MnO2 |
175.57 |
|
nm |
TEM |
apt-Fe3O4/MnO2 probes are uniformly distributed spherical with an average diameter of 175.57 nm |
|
|
|
|
|
|
|
|
8125 |
1062 |
MnO2 Fenozymes |
|
|
|
TEM |
Transmission electron microscopy (TEM) revealed the uniform diameter of the hollow structure of FTn was ≈12 nm after protein negative staining (Figure 1b). The diameter of FTn inner cavity is 8 nm, and the incorporated MnO2 nanozymes within the FTn core (MnO2 Fenozymes) were observed by TEM. The MnO2 Fenozymes showed monodispersed spherical morphology (Figure 1c) with mean diameters of ≈6.5 nm, which did not change after TPP conjugation (Figure 1d). |
|
|
|
|
|
|
|
|
8127 |
1063 |
Se NPs |
|
|
|
|
|
546.470 |
|
|
|
|
|
|
|
8126 |
1063 |
MSe NPs |
150 |
|
nm |
TEM |
The transmission electron microscope (TEM) (Fig. 1A) and high-resolution TEM (HRTEM) (Fig. S1B) showed that the mesochannels distributed on the spheres throughout the MSe NPs with average size of 150 nm, which proved we have prepared the porous Se NPs. |
1160.195 |
|
|
|
|
|
|
|
8128 |
1063 |
MSe NPs |
17.7 |
|
nm |
Others |
Then, the N2 adsorption and desorption isotherms showed that MSe NPs has obvious hysteresis loop (Fig. 1E) with an average pore size of 17.7 nm (Fig. 1F), indicating that MSe NPs were typical mesoporous nanoparticles [42,47], whereas the solid Se NPs without corresponding performance (Fig. 1G). |
|
|
|
|
|
|
|
|
8129 |
1064 |
Pt-LNT NCs |
1.2 |
0.29 |
nm |
TEM |
the size of Pt-LNT NCs was 1.20 ± 0.29 nm |
116.6 |
|
|
|
|
|
|
|
8130 |
1065 |
GCDs |
|
|
|
TEM |
As shown in Fig. 2(a), pure Au NPs are spherical with good dispersion and their size is about 15 nm. Pure CDs is also good dispersion with the size about 5 nm as shown in Fig. 2(b). Fig. 2(d) exhibits obvious CDs about 20 nm as shown in Fig. 2(d). |
|
|
|
|
|
|
|
|
8132 |
1066 |
polyzymes |
80 |
|
nm |
DLS |
Transmission electron microscopy (TEM, Figure S7, Supporting Information) indicated a diameter of ≈30 nm (dry). Dynamic light scattering (DLS, Figure S7, Supporting Information) showed that the size of the self-assemblies was ≈80 nm in solution, indicating some degree of swelling of self-assembled NP in aqueous media. |
|
|
|
|
|
|
|
|
8131 |
1066 |
polyzymes |
30 |
|
nm |
TEM |
Transmission electron microscopy (TEM, Figure S7, Supporting Information) indicated a diameter of ≈30 nm (dry). Dynamic light scattering (DLS, Figure S7, Supporting Information) showed that the size of the self-assemblies was ≈80 nm in solution, indicating some degree of swelling of self-assembled NP in aqueous media. |
|
|
|
|
|
|
|
|
8133 |
1067 |
PN-CeO2 |
2~4 |
|
nm |
TEM |
And the TEM of PN-CeO2 shows that the surface of rod-like structure become rough relative to pristine precursor, meanwhile, a porous feature is observed with diameter of 2∼4 nm (Fig. 1C). |
147.70 |
|
|
|
|
|
|
|
8134 |
1067 |
BNQDs/CeO2 |
|
|
|
TEM |
the synthesized BNQDs display a uniformly spherical shape and its average lateral size is about 2 nm (inset of Fig. 1A). Fig. 1B shows that CeO2/Ce(OH)3 precursor is non-porous rod-like morphology with length ranging from 60 to 80 nm and diameter of ∼8 nm. According to the high-resolution TEM (HRTEM) image of BNQDs/CeO2 (inset in Fig. 1D), the lattice fringes with 0.32 nm was attribute to typical (111) facet of CeO2, while the interplanar spacing of 0.21 nm corresponded to (100) crystal plane of BNQDs, further revealing the presence of BNQDs [39]. |
130.93 |
|
|
|
|
|
|
|
8135 |
1068 |
SiO2@Pt NPs |
|
|
|
TEM |
the silica seed nanoparticles exhibited excellent dispersity with a mean size of 53 ± 1.5 nm, and with the further growth of silica on the surface of seed nanoparticles, the resulting SiO2 nanoparticles reached a size of approximately 114 ± 3.4 nm (Fig. 1b). TEM illustrated that the mean size of the as-prepared Pt NPs was 3.0 ± 0.3 nm (Fig. S1). HRTEM showed that the lattice spacing of the Pt NPs was 0.23 nm (inset in Fig. S1), which corresponds to the (111) lattice facet of Pt crystals [37]. |
|
|
|
|
|
|
|
|
8137 |
1070 |
Fe(II)- and Fe(III)-doped poly-L-DOPA |
|
|
|
|
Sample size is relatively unchanged after Fe replacement (davg = 143 and 153 nm). DLS results corroborate the uniform size distribution and demonstrate aqueous stability for 1-Mn(II) (dH = 261.8 nm, polydispersity index (PDI) = 0.101, ζ = −23.1 mV) and 1-Fe (dH = 306.3 nm, PDI = 0.138, ζ = −29.2 mV) |
58.92 |
|
|
|
|
|
|
|
8138 |
1072 |
Co(OH)2/FeOOH/WO3 |
20 |
|
nm |
SEM |
The nanoflowersare are composed of multilayer self-assembled nanosheets with a thickness of 20 nm, indicating its hierarchical structure. |
|
|
|
|
|
|
|
|
8140 |
1074 |
azidomethyl-EDOT |
130-300 |
|
nm |
SEM |
Varying the number of cycles from 10 to 30 allows electrodeposition of continuous polymer layers with thickness from 130 to 300 nm. |
|
|
|
|
|
|
|
|
8141 |
1075 |
W-POM NCs |
|
|
|
|
After a rapid reduction and stabilization process under the optimal reaction factors, W-POM NCs (2.0 ± 0.1 nm) were successfully obtained as evidenced by the transmission electron microscopy (TEM) characterization (Fig. 1a and S1). The slight increase in hydrated diameter (7.41 ± 0.67 nm) is attributed to the existence of hydrophilic gallic acid stabilizers which could further confirmed by their negative charged surface of around −27.2 mV (Fig. 1b and c). |
|
|
|
|
|
|
|
|
8147 |
1082 |
G3.0-he(1:2.5) |
17.2 |
0.8 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8149 |
1082 |
G3.0-he(1:7.5) |
78.2 |
1.8 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8146 |
1082 |
G3.0-he(1:1.0) |
13.4 |
1.2 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8148 |
1082 |
G3.0-he(1:5.0) |
48.7 |
1.3 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8150 |
1083 |
MFNCDs |
2-2.25 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8151 |
1084 |
CuMnFe-ATP |
5-10 |
|
nm |
TEM |
The specific surface area and pore-size distribution of CuMnFe-ATP were calculated based on nitrogen adsorption–desorption results. As Fig. 3C shows, the CuMnFe-ATP NPs exhibited a type IV isotherm, which possessed significant hysteresis at the range of 0.4–1.0 P/P0. The surface area was calculated as 37.31 m2 g− 1 , according to the Brunauer-EmmettTeller model. The large surface area may be induced by the collapse of the CuMnFe-ATP NP structures after drying in vacuum. From Fig. 3D, although the pore-size distribution of CuMnFe-ATP NPs was majorly in the range of 5–10 nm, some pore sizes were about 27.5 nm. The generation of larger pores suggests the collapse of the CuFeMn-ATP NPs. Also, the SEM micrograph indicates the existence of large pores in the CuMnFe-ATP NPs, which also proves the structure collapse. |
37.31 |
|
|
|
|
|
|
|
8152 |
1085 |
Ni3S2/Cu1.8S@HA |
82.1 |
29.7 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8155 |
1088 |
PAN/FeNPs/NFs |
120 |
|
nm |
TEM |
Fe文章里没写 自己量的 |
|
|
|
|
|
|
|
|
8157 |
1092 |
SnO2/GCN |
160 |
|
nm |
DLS |
|
|
|
|
|
|
|
|
|
8158 |
1093 |
Pt |
5 |
|
nm |
TEM |
Pt NPs |
|
|
|
|
|
|
|
|
8159 |
1094 |
Cu(II)-rGO |
|
|
|
TEM |
TEM给的是大片石墨烯的一小块 |
|
|
|
|
|
|
|
|
8160 |
1095 |
GOQD-q-CuO |
|
|
nm |
TEM |
Typical TEM images are displayed in Fig. 1A and S1A, which show well-dispersed, uniform, and spherical GOQD and q-CuO with an average diameters of ~4–7 nm (Fig. 1B) and ~3–5 nm, respectively, which are consistent with previous reports [21,27]. The q-CuO are surrounded by GOQD, forming GOQD-q-CuO composites (Fig. S1B) because of the presence of GOQD surface functional groups, such as peripheral carboxylic groups [28]. The q-CuO are not spindle-shaped as reported elsewhere because precipitation from alcohol enables direct formation of CuO, unlike precipitation from aqueous solution that initially results in Cu(OH)2 formation [29,30]. The high resolution TEM image of GOQD-q-CuO (Fig. 1C) shows a 0.25 nm distance between neighboring lattice fringes, corresponding to the [002] planes of monoclinic CuO. The Energy dispersive spectra (EDS) and elemental mapping results of CuO/PCN nanocomposite further demonstrate the presence of C, O and Cu elements (Fig. 1D–G). |
|
|
|
|
|
|
|
|
8161 |
1096 |
CDs@ZIF-8 |
200 |
|
nm |
SEM |
|
|
|
|
|
|
|
|
|
8163 |
1101 |
A/A-ES |
3 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8164 |
1102 |
Pt/UiO-66 |
3.8 |
|
nm |
Others |
Pt,计算得到 |
1327 |
|
|
|
|
|
|
|
8168 |
1106 |
UCZN |
120 |
|
nm |
SEM |
The SEM (Figure 1(b)) and TEM (Figure 1(c, d)) imagesdemonstrated that UCZN exhibited a uniform size of ap-proximately 120 nm |
|
|
|
|
|
|
|
|
8174 |
1109 |
NPC |
|
|
|
|
|
2225 |
|
|
|
|
|
|
|
8176 |
1111 |
MoSe2/CoSe2@PEG |
|
|
|
|
The MoSe2/CoSe2@PEG heterostructures were prepared via a simple coprecipitation strategy. As shown in Figure 1A, the as-prepared sample reveals nanosheets with nearly 30–50 nm in size with the thickness about 3–4 nm (Figure S1, Supporting Information). And dynamic light scattering (DLS) also indicates the hydration size centers at about 69.2 nm |
|
|
|
|
|
|
|
|
8178 |
1113 |
PdPtNPs |
10 |
|
nm |
TEM |
PdPtNPs with a mean size of 10 nm are evenly loaded on the H-Gr surface. |
|
|
|
|
|
|
|
|
8179 |
1117 |
CCN |
|
|
|
TEM |
the nanoparticles (NPs) of CCN clickases were nearly spherical, and had a diameter ranging from 30 to 80 nm, and the sizes of CCN clickases are suitable for use as labels for the immunoassay. |
8.8679 |
|
|
|
|
|
|
|
8181 |
1119 |
carbon dot |
3.48 |
|
nm |
TEM |
the carbon dot particles are almost spherical, with an average size of 3.48 nm |
|
|
|
|
|
|
|
|
8182 |
1119 |
I-CDs |
|
|
nm |
TEM |
The diameter of I-CDs is mainly distributed in a narrow range of 2.2–4.6 nm |
|
|
|
|
|
|
|
|
8183 |
1120 |
ZnCo-ZIF |
230 |
|
nm |
SEM |
the parent ZnCo-ZIF nanocrystals are monodispersed with an average size of ~ 230 nm. |
|
|
|
|
|
|
|
|
8184 |
1121 |
CPMP |
330 |
|
nm |
TEM |
It can be seen from Figure S3, Supporting Information, that 9.5% CPMP had an average particle size of about 330 nm with good dispersity (the polydispersity index of 9.5% CPMP in water and phosphate buffer solution [PBS], as well as cell medium is 0.221, 0.213, and 0.116, respectively), which is suitable for biological applications and can achieve good therapeutic results. |
|
|
|
|
|
|
|
|
8185 |
1122 |
V-POD-M |
1.43 |
|
nm |
TEM |
To simplify the calculation model, we first create a penetration simulation model using the cytomembrane surrounded by H2O molecules and nanostructures with a flat surface (size: 12.53 nm ×12.53 nm) and epitaxial nanotubes-based spiky surface (diameter: 1.43 nm), respectively. |
|
|
|
|
|
|
|
|
8188 |
1128 |
ZnSA-AuAMP hydrogel |
2.48 ± 0.54 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
The as-prepared AuAMP NCs are approximately 2.48 ± 0.54 nm in diameter with benign dispersion and uniformity |
8189 |
1129 |
Co–Fe@hemin |
80 |
|
nm |
TEM |
As shown in Fig. 1A and B, the Co–Fe@hemin nanozymes resemble spherical particles, characterized by an average diameter of approx. 80 nm. DLS analysis showed that the mean hydrated diameter of our nanozyme spheres was approx. 100 nm (Fig. 1C). |
|
|
|
|
|
|
|
|
8191 |
1130 |
CuS/h-BN |
38.8 ± 1.66 |
|
nm |
TEM |
|
25.792 |
|
|
|
|
|
|
|
8190 |
1130 |
CuS/g-C3N4 |
3.68 ± 0.14 |
|
nm |
TEM |
|
16.902 |
|
|
|
|
|
|
|
8192 |
1133 |
NH2-MIL-101(Fe) |
1 |
|
μm |
SEM |
the prepared NH2-MIL-101(Fe) has a relatively uniform spindle-shaped shape with a length of several micrometers and a width of about 1 μm |
|
|
|
|
|
|
|
|
8194 |
1137 |
Se@Me@MnO2 NPs |
150 |
|
nm |
TEM |
the average size of the Se@Me@MnO2 is about 150 nm (Fig. 1(b) and Fig. S2 in the
ESM). |
|
|
|
|
|
|
|
|
8195 |
1138 |
CF-H-Au |
200 |
|
μm |
SEM |
The formation of Au on the surface of CF fragments with a size up to 200 μm (obtained by pre-ultrasonic treatment) is much more efficient (light areas) compared to larger CF fragments (dark areas) (see figs2, figs3). |
|
|
|
|
|
|
|
|
8197 |
1141 |
Cu-BTL |
6.6 |
|
nm |
TEM |
Thus, in the case of BTL, although it is a slightly larger protein than CALB, Cu(II) nanoparticles of 6.6 nm were obtained (Figure 2c). |
|
|
|
|
|
|
|
|
8196 |
1141 |
Cu-CALB |
6 |
|
nm |
TEM |
we can clearly see that the size of nanoparticles increased from 3.9 (for CALB, Figure 2a) to around 6 nm because of the protein size (Figure 2). |
|
|
|
|
|
|
|
|
8200 |
1149 |
SrTiO3/DHB |
50 |
|
nm |
TEM |
The synthesized SrTiO3 is a cubic phase crystal (JCPDS no. 01-079-0176) with sheet-like morphology having size around 50 nm, as confirmed by the X-ray diffraction (XRD) pattern and the transmission electron microscopy (TEM) image (Fig. 1). |
|
|
|
|
|
|
|
|
8201 |
1150 |
Cu(II)-Based Nanofibrous Metallogel |
|
|
|
SEM |
The fibers are several micrometers long and have an approximate width of ∼100 nm. |
|
|
|
|
|
|
|
|
8202 |
1151 |
Fe-CoO NCs |
|
|
|
|
the CoO NPs consist of a loose core of 400–500 nm and a graphene-like shell of about 100 nm |
205.4 |
|
|
|
|
|
|
|
8204 |
1157 |
MOF-199 |
110 |
|
nm |
TEM |
the average diameter was approximately 110 nm with a narrow size distribution and highly crystalline morphology. |
1674.3 |
|
|
|
|
|
|
|
8206 |
1159 |
CeO2@C |
|
|
|
|
|
|
|
|
|
|
|
|
|
8207 |
1161 |
SF@Rsg-Mn |
1.5 |
|
μm |
SEM |
a 1.5 μm width and a 20 μm length |
|
|
|
|
|
|
|
|
8209 |
1164 |
GOx@Fe-MMPG-5 |
|
|
|
|
|
the Brunauer–Emmett–Teller (BET) surface areas vary from 454 up to 857 m2 g−1 (Fig. 2e) |
|
|
|
|
|
|
|
8214 |
1168 |
Ln-CuPNFs |
70 |
50 |
μm |
SEM |
The micrographs given in Fig. 3 support that the petal density and the diameter of the flower increases from 20 to 120 μm. Fig. 2a–e gives a comparative analysis among the SEM micrographs of CuPNFs synthesized using different Ln derivatives. While the simple CuPNFs are of 25 μm in size, the average size of the NFs changes to 8.5 μm for Ln possessing the phenyl group (Fig. 2b), which suggests the marginal effect of the Ph-group as a glue to hold the flower-like morphology of copper phosphate. |
54.98 |
|
|
|
|
|
|
Based on the BET analysis, the surface area for simple CuPNF given in Fig. 1d is 83.28 m2 g−1 while the organic derivatized ones exhibited 54.98, 51.88, 39.24, and 25.92 m2 g−1 for Ln-CuPNF (n = 1, 2, 3, 4), respectively. |
8215 |
1169 |
GK-Pd NPs |
8.4 |
3.6 |
nm |
TEM |
TEM analysis suggested that the synthesized nanoparticles were spherical, poly-dispersed and of 8.4 ± 3.6 nm in size |
|
|
|
|
|
|
|
|
8218 |
1172 |
FIOMPs |
2 |
|
μm |
SEM |
the core thickness of FIOMPs is 2 µm with petals of 50 nm in size |
|
|
|
|
|
|
|
|
8217 |
1172 |
CNPs |
50 |
|
nm |
SEM |
the FESEM images reveal that the CNPs are spherical with a diameter less than 50 nm |
|
|
|
|
|
|
|
|
8219 |
1174 |
AS1411-PtNPs |
38.1 |
14.9 |
nm |
TEM |
Ascorbic acid-stabilized platinum nanoparticles (PtNPs) with a size of 38.1 ± 14.9 nm were firstly synthesized |
|
|
|
|
|
|
|
|
8220 |
1175 |
Fe3O4@MnO2 |
125.6 |
1.8 |
nm |
TEM |
After being decorated with MnO2 NPs, the average size of NPs slightly increased from 112.0 ± 1.4 nm to 125.6 ±1.8 nm. |
|
|
|
|
|
|
|
|
8221 |
1177 |
COMP |
175 |
25 |
nm |
SEM |
The lateral size of COMP was in the 150–200 nm range |
|
|
|
|
|
|
|
|
8222 |
1178 |
nano-Pt/VP@Mlipo |
140 |
|
nm |
DLS |
Hydrodynamic size of nano-Pt/VP@MLipo was ≈140 nm measured by dynamic light scattering |
|
|
|
|
|
|
|
|
8223 |
1179 |
CeOx@fMIL |
112 |
|
nm |
DLS |
After coating with MIL, the dynamic light scattering (DLS) of CeOx indicated an increase in the mean hydrodynamic diameter particle size from 17 to 112 nm. |
|
|
|
|
|
|
|
|
8224 |
1182 |
Az@MOF |
|
|
|
|
Scanning electron microscopy (SEM) imaging indicated the extremely homogeneous morphology with a length of 200 nm and a width of 75 nm (Fig. 1a). Furthermore, transmission electron microscopy (TEM) images of Mn-MOFs in Fig. 1b directly displayed a pore size of 1.25 nm, which is in accordance with the result of N2 adsorption–desorption (1.25 nm) in Fig. S7.† The pore size of 1.25 nm permitted the encapsulation and release of AcManNAz (MW = 430). |
|
|
|
|
|
|
|
|
8225 |
1183 |
Gd@PANs |
36.72 |
|
nm |
DLS |
The average size of Gd@ANs and Gd@PANs was 33.92 and 36.72 nm, respectively |
1021.48 |
|
|
|
|
|
|
|
8226 |
1184 |
PINMH |
200 |
|
nm |
DLS |
After the modification of HA, the size of PINMH was found to increase by about 200 nm, as compared to that of PINM, PDA@MnO2, and PDA. |
|
|
|
|
|
|
|
|
8228 |
1187 |
Ag-PBA |
225 |
25 |
nm |
SEM |
Scanning electron microscopy (SEM) images (Fig. 2) of Ag-PBAs and PBAs showed essentially the same cubic morphology, with a diameter of 200–250 nm, confirming the successful synthesis of Ag-PBA nanoparticles that retained a cubic crystalline structure and a similar size to PBA. |
|
|
|
|
|
|
|
|
8229 |
1190 |
ATP-HCNPs@Ce6 |
165 |
95 |
nm |
DLS |
The ceria shell thickness also could be controlled to better promote drug diffusion. Unexpectedly, different nitric acid concentrations could adjust HCNPs size from 70 to 260 nm in a concentration-dependent manner. |
|
|
|
|
|
|
|
|
8230 |
1191 |
PdCo@MSNs |
225 |
25 |
nm |
TEM |
As shown in the TEM images, MSNs have an average particle diameter of 200–250 nm |
240.8 |
|
|
|
|
|
|
|
8231 |
1193 |
rGO/CMCNs |
487.5 |
287.5 |
nm |
SEM |
The width of the CMCNs was obtained to be between 100 and 190 nm whereas the length was 200–775 nm (Fig. S2†). The plates' thickness was obtained to be between 100- and 115 nm, with an average length of ∼700 nm and width of ∼375 nm, respectively. |
4.133 |
|
|
|
|
|
|
|
8232 |
1197 |
CoOOH NSs |
80-100 |
|
nm |
TEM |
the CoOOH nanozyme was mainly hexagonal ultrathin nanosheets
with the average size of 80–100 nm, which was consistent
with the structural characterization of the two-dimensional (2D)
nanosheets |
|
|
|
|
|
|
|
|
8233 |
1198 |
Pbzyme |
60 |
|
nm |
TEM |
PBzyme displayed a uniform sphere-like
structure with a ~60-nm average diameter and
~110-nm average hydrodynamic size |
|
|
|
|
|
|
|
|
8234 |
1200 |
Au/CeO2 core/shell NPs |
12.2 |
0.4 |
nm |
TEM |
The
Au/CeO2 hybrid NPs (cf. Figure 1b) consist of an Au core with a diameter of dc
=5.7±0.4 nm, which is surrounded by a porous, grainy, and inhomogeneous CeO2 shell,
resulting in an overall diameter of the inorganic NPs of dc =12.2±0.4 nm. |
|
|
|
|
|
|
|
|
8235 |
1201 |
UMONs-LA-Au |
2.4 |
|
nm |
TEM |
After ultrasmall gold capping, the average pore size of UMONs–Au was decreased to approximately 2.4 nm, accompanied by the decrease of BET surface area from 873.2 m2 g−1 to 489.5 m2 g−1 |
489.5 |
|
|
|
|
|
|
|
8236 |
1203 |
Cu-MOGs |
|
|
|
|
|
|
|
|
|
|
|
|
|
8237 |
1205 |
Hem@Gel |
18.7 |
|
nm |
DLS |
With the same concentration of hemin, Hem@Gel showed a hydrodynamic diameter (Dh) of 18.7 nm, whereas an increased number-average size was observed for Hem/Gel (49.6 nm), suggesting that some degree of hemin aggregation had occurred |
|
|
|
|
|
|
|
|
8238 |
1206 |
Cu–Ru/LIG |
50-500 |
|
nm |
SEM |
The Cu–Ru NPs appeared as polyhedral of varying sizes (50–500 nm in dia.) which has been randomly distributed over the surface of LIG. The polyhedral shape shows high reactive surfaces which exhibit much higher catalytic activity than the other shapes. |
|
|
|
|
|
|
|
|
8239 |
1207 |
Hemin-doped HKUST-1/rGO |
100 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8244 |
1217 |
Fe@BC-600 |
|
|
|
TEM |
Fig. 1c shows that the Fe nanoparticles are covered by over ten layers of B-doped carbon shells. The interplanar spacings of 0.2 and 0.34 nm belong to the (110) plane of Fe (Fig. 1d) and the (002) plane of graphite carbon (Fig. 1e), respectively.16 |
|
|
|
|
|
|
|
|
8245 |
1219 |
MnO2 NSs–TMB |
50 |
|
nm |
TEM |
With increasing dosage of BSA from 0.1 mg to 1 mg and the content of MnO2 fixed at 0.02 M, the lateral dimension of MnO2 NSs decreased from above 100 nm (Fig. 2c) to about 50 nm (Fig. 2d). |
|
|
|
|
|
|
|
|
8247 |
1222 |
Vo-CNPLs with P-Ce3+ ions |
|
|
|
|
|
|
|
|
|
|
|
|
|
8250 |
1225 |
CuO NPs |
50 |
nm |
|
TEM |
|
|
|
|
|
|
|
|
|
8252 |
1228 |
Pt@PDA |
2 |
|
nm |
TEM |
Pt NPs was about 2 nm |
|
|
|
|
|
|
|
|
8253 |
1229 |
MIL-53(Fe) |
|
|
|
|
|
|
|
|
|
|
|
|
|
8258 |
1239 |
Ni-Fe PBA |
120 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8259 |
1240 |
Cu-CDs |
5 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8260 |
1241 |
Au@NH2-MIL-125(Ti) |
0.53 |
|
nm |
TEM |
Fig. 1. TEM (a, b) and image SEM (c, d) and EDXS mapping images (e, f) of Au@NH2-MIL-125(Ti) |
671.0 |
|
|
|
|
|
|
|
8261 |
1242 |
MoS2@Au |
100 |
|
nm |
TEM |
Fig. 1A showed the original monolayer MoS2 characterized by TEM with a diameter of about 100 nm. A large amount of uniform AuNPs with diameters of 10−20 nm were observed and distributed over the surface of monolayer MoS2 (Fig. 1B), |
|
|
|
|
|
|
|
|
8263 |
1244 |
Au-MCM-41 hybrids |
50 |
|
nm |
TEM |
Figure 1. Synthesis and characterization of the Au-mesoporous silica hybrids: (a) Schematic description of the different synthesis stages including (i) the synthesis of the Au NPs with the aid of THPC [59,62]; (ii) the synthesis of the MCM-41 ordered mesoporous spheres and the amino-grafting step with APTES [49,65,66]; (iii) the gold seeding attachment by electrostatic attraction; (b–c) HAADF-STEM images of the individual Au NPs; (d–e) TEM images at different magnifications of the mesoporous silica supports showing the ordered organization of the mesochannels; (f–g) TEM and STEM images displaying the correct gold seeding process via electrostatic attraction and the formation of the Au-silica hybrid nanoparticles. |
|
|
|
|
|
|
|
|
8265 |
1248 |
Fe3O4@PDA@Pd/Pt |
177.2 |
|
nm |
DLS |
The
size distribution of Fe3O4@PDA@Pd/Pt is shown in Figure
S4. The hydration size (Figure 1c) of Fe3O4@PDA@Pd/Pt
was 177.2 nm (PDI = 0.033), which was approximate to the
average diameter of 143.4 nm (Figure 1bVII) and was the ideal
size of an ICA probe. |
|
|
|
|
|
|
|
|
8267 |
1251 |
BiOBr/PtRu |
25.7 |
5 |
nm |
TEM |
The average particle size of the PtRu NPs was 25.7 ± 5 nm. |
|
|
|
|
|
|
|
|
8268 |
1253 |
CuxO@EM-K |
78.2-165.3 |
|
nm |
TEM |
The average hydrodynamic diameter of CuxO-K increased from 78.2 ± 1.5 to 165.3 ± 3.9 nm (Figure S12A) due to formation of protein coronas around CuxO-K. |
|
|
|
|
|
|
|
|
8269 |
1255 |
Prussian Blue nanoparticles |
|
40 |
nm |
SEM |
For investigation of their mechanism of action, the
nanozymes with diameter of ∼40 nm have been chosen. The
catalytically synthesized nanozymes are of spherical shape
according to their scanning electron microscopy images
(Figure S1, inset). |
|
|
|
|
|
|
|
|
8270 |
1256 |
IONPs (iron oxide nanoparticles) |
7.3 |
0.4 |
nm |
TEM |
The transmission electron microscopy (TEM) image in Fig. 1b shows that the as-prepared IONPs (iron oxide nanoparticles) dispersed quite uniformly, and we observed that the mean particle size was approximately 7.3 nm (mean diameter, 7.3 ± 0.4 nm (s.d.), n = 321 particles) in Fig. 1c. |
|
|
|
|
|
|
|
|
8276 |
1261 |
GOx@Fe-ZIF-8 |
91-633 |
|
|
SEM |
The scanning electron microscopy (SEM) images (Figure S3A) showed that when the ratio was between 1:0.25 and 1:2, the Fe-ZIF-8 nanoparticles all grew into a typical ZIF-8-like rhombohedron dodecahedron morphology with the average particle size from 91 to 633 nm (Figure S3B) |
|
|
|
|
|
|
|
|
8277 |
1262 |
PDA-Fe(III) NPs |
150 |
|
nm |
SEM |
As seen in Figure 1A, the scanning electron microscopy (SEM) image of PDA-Fe(III) NPs showed the characteristics of a spherical surface with a uniform surface, with a diameter of about 150 nm, and the corresponding element mapping analysis (1−4) also confirmed the uniform distribution of N, C, O, and Fe elements. |
|
|
|
|
|
|
|
|
8278 |
1263 |
USPBNPs |
3.4 |
|
nm |
TEM |
Transmission electron microscopy (TEM) image (Figure 1a) shows that when the ethanol concentration was 75% in volume, USPBNPs with sizes of about 3.4 nm were obtained (Figure 1b) |
|
|
|
|
466 |
|
U/mg |
|
8280 |
1265 |
C-AuNPs |
30-40 |
|
nm |
Others |
The peak indicated that the average size of these nanoparticles is in this range between 30-40 nm The hydrodynamic radius of these nanoparticles as evaluated by DLS was 33 nm. |
|
|
|
|
|
|
|
|
8281 |
1266 |
BC@DNA-Mn3(PO4)2 |
|
|
|
TEM |
The graphene-like thin sheets of BC@DNA-Mn3(PO4)2 were further confirmed by TEM (Figure 1E). |
97.8 |
|
|
|
|
|
|
|
8282 |
1268 |
H2TCPP/ZnS/CoS |
|
|
|
TEM, SEM |
Figure S2 shows one ZnS/CoS nanosphere with a size of 300−500 nm that has a rough surface and is composed of many small nanoparticles |
|
|
|
|
|
|
|
|
8283 |
1269 |
Ab-GNPs-Cu(II) |
<20 |
|
nm |
TEM |
the size and morphology of Ab-GNPs-Cu(II) nanocomposites. These particles displayed a nearly spherical shape with an average diameter of less than 20 nm |
|
|
|
|
|
|
|
|
8284 |
1274 |
IrO2/MnO2 |
|
|
|
TEM |
Figure 2a displays that IrO2 NPs can be uniformly dispersed on MnO2 NSs after ultrasonic treatment. |
|
|
|
|
|
|
|
|
8286 |
1276 |
MnO2- and SiO2@Fe3O4 |
|
|
|
TEM |
For more precise on both size and structure of the as-prepared MnO2 nanozymes, the TEM image of these nanozymes was recorded, the results are shown in Fig. 1B, showing a semi-spherical structure and a size distribution over 40.0-200.0 nm for the as-synthesized MnO2 nanozymes. |
|
|
|
|
|
|
|
|
8287 |
1277 |
Cu2+/PPy NTs |
30-70 |
|
nm |
TEM |
Under a hydrothermal reaction, PPy NTs with a thickness ranging from 30 to 70 nm have been achieved (Fig. 1a and 1b). |
|
|
|
|
|
|
|
|
8288 |
1278 |
Pt/CeO2/NCNFs |
|
|
|
TEM, SEM |
From the SEM and TEM images of Pt/CeO 2 /NCNFs (Fig. 2a and Fig. 2b), it could be noticed that CeO2 nanoplates were embedded uniformly in NCNFs. |
336.4 |
|
|
|
|
|
|
|
8290 |
1281 |
CD N/Au |
8 |
|
nm |
TEM |
TEMs of CD N and CD N1Au show in Fig. 3C and D, with an average size of 8 and 10 nm respectively. |
|
|
|
|
|
|
|
|
8291 |
1281 |
CD N1/Au |
10 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8296 |
1285 |
Bi NPs |
120 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8297 |
1285 |
PVP@AuPt NPs |
44624 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8299 |
1289 |
GOx@CuBDC |
221 |
|
nm |
SEM |
Average |
|
|
|
|
|
|
|
|
8300 |
1292 |
0.10CeO2/CoO NCs |
600-700 |
|
nm |
SEM |
Average |
|
|
|
|
|
|
|
|
8313 |
1304 |
Ag2S@Fe2C-DSPE-PEG-iRGD |
10 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8315 |
1306 |
PN-CeO2-PSS |
12 |
|
nm |
TEM |
diameter |
|
|
|
|
|
|
|
|
8316 |
1306 |
PN-CeO2 |
60 |
|
nm |
TEM |
Length |
|
|
|
|
|
|
|
|
8317 |
1306 |
PN-CeO2 |
8 |
|
nm |
TEM |
diameter |
|
|
|
|
|
|
|
|
8321 |
1312 |
Hb |
5.2 |
|
nm |
DLS |
Size |
|
|
|
|
|
|
|
|
8322 |
1312 |
PDA-coated Hb |
7 |
|
nm |
DLS |
Size |
|
|
|
|
|
|
|
|
8323 |
1313 |
Hollow manganese silicate (HMnOSi) |
15 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8324 |
1314 |
Pt NPs |
20 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8326 |
1315 |
BP nanosheets |
8.5 |
|
nm |
AFM |
thickness |
|
|
|
|
|
|
|
|
8325 |
1315 |
BP nanosheets |
500 |
|
nm |
AFM |
diameter |
|
|
|
|
|
|
|
|
8331 |
1324 |
PBBA |
45 |
|
nm |
SEM |
|
|
|
|
|
|
|
|
|
8337 |
1328 |
Fe-MIL-88NH2 nanozyme |
0.1~3 |
|
μm |
SEM |
width |
|
|
|
|
|
|
|
|
8336 |
1328 |
Fe-MIL-88NH2 nanozyme |
1~2 |
|
μm |
SEM |
length |
|
|
|
|
|
|
|
|
8338 |
1329 |
ZnTazs |
1.5~3.5 |
|
μm |
DLS |
|
|
|
|
|
|
|
|
|
8340 |
1330 |
CWNSs |
500 |
|
nm |
SEM |
In size |
67.06 |
|
|
|
|
|
|
|
8339 |
1330 |
CWNSs |
50 |
|
nm |
SEM |
Thickness |
67.06 |
|
|
|
|
|
|
|
8342 |
1334 |
Fe3O4 |
|
|
|
|
|
25.8 |
|
|
|
|
|
|
|
8341 |
1334 |
MIL-101(Fe)@Fe3O4 |
243 |
|
nm |
TEM |
the nanoparticles are spherical with a diameter of ~ 243 nm. The shell thickness of the MOF layer was approximately 25 nm. |
726.8 |
|
|
|
|
|
|
|
8343 |
1336 |
Eu-pydc |
1~2 |
|
μm |
SEM |
the MOF shows regular particles with a size of about 1–2 μm which depended on the regulation of the new method |
|
|
|
|
|
|
|
|
8344 |
1337 |
Au@CeO2 |
102.8 |
2.3 |
nm |
DLS |
The final hydrodynamic particle size increased from 45.6 ± 1.5 nm of AuNRs to 102.8 ± 2.3 nm of PEGylated Au@CeO2, further indicating the successful coating of CeO2 on the surface of AuNRs. |
|
|
|
|
|
|
|
|
8345 |
1340 |
Mt. |
1.27 |
|
nm |
XRD |
The sharp peak at 2θ =5.7° in Fig. 1a was attributed to the characteristic peak of Mt., corresponding to the plane (001) with the d001 value to be 1.27 nm. |
|
|
|
|
|
|
|
|
8347 |
1342 |
AgNPs@GQDs |
14-24 |
|
nm |
TEM |
In comparison, AgNPs without the assembly of GQDs show the morphology with a little aggregation (Fig. S1 in Supporting information), which are smaller than that of AgNPs@GQDs (14−24 nm). Upon treating with H2O2, the characteristic nanoparticles of AgNPs@GQDs disappear, and the monodisperse nanodots with the average diameter of 6.7 nm are observed in TEM image |
25.3479 |
|
|
|
|
|
|
|
8346 |
1342 |
GQDs |
6.4 |
|
nm |
TEM |
Transmission electron microscopy (TEM) images of GQDs demonstrate a good monodispersity with the average diameter of 6.4 nm in lateral size (Fig. 1B). |
|
|
|
|
|
|
|
|
8349 |
1345 |
BSA-MnO2 NPs |
12 |
8 |
nm |
TEM |
TEM images suggest the formation of monodispersed and homogenous NPs in the range of 4–20 nm with most of the particles in the size range of 10–12 nm |
|
|
|
|
|
|
|
|
8351 |
1346 |
Cu-MOF |
90 |
10 |
nm |
SEM |
Uniform octahedral crystalline structures with average particle sizes about 80–100 nm were observed according to the SEM and TEM images. |
|
|
|
|
|
|
|
|
8350 |
1346 |
Cu-MOF |
90 |
10 |
nm |
TEM |
Uniform octahedral crystalline structures with average particle sizes about 80–100 nm were observed according to the SEM and TEM images. |
|
|
|
|
|
|
|
|
8353 |
1347 |
Fe3O4@PDA |
100 |
|
nm |
SEM |
|
|
|
|
|
|
|
|
|
8354 |
1347 |
Fe3O4@PDA |
40 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8352 |
1347 |
ZIF-67 nanosheets |
400 |
|
nm |
SEM |
The morphology of ZIF-67 nanosheets shows irregular flakes that are 400 nm in diameter. Modification of dopamine on the surface of ZIF-67 nanosheets did not change its morphology. |
|
|
|
|
|
|
|
|
8355 |
1348 |
NG@NC |
41.4 |
1.6 |
nm |
DLS |
Fig. 2B shows the particle size distribution with an average hydrodynamic diameter of 41.4 ± 1.6 nm. |
|
|
|
|
|
|
|
|
8359 |
1353 |
CoSe2 hollow microspheres |
15 |
|
nm |
TEM |
TEM image of the CoSe2 hollow microsphere. Inset shows the enlarged image of CoSe2 with ~15 nm. |
172.46 |
|
|
|
|
|
|
|
8361 |
1355 |
Au–PtNCs-GMP |
1.7 |
|
nm |
TEM |
The average diameter was evaluated to be 1.70 nm by the statistic on the sizes of more than 200 particles obtained from the TEM image, where most of them were located between 1.10 and 2.30 nm. |
|
|
|
|
|
|
|
|
8362 |
1356 |
PB@Ti3C2Tx |
20 |
|
nm |
TEM |
PB nanoparticles can be uniformly distributed on the surface and the gap between the Ti3C2Tx nanolayers (Figure 1c). The diameter of PB nanoparticles is approximately 20 nm from TEM analysis |
|
|
|
|
|
|
|
|
8363 |
1357 |
SA-PtNPs |
5.9 |
0.6 |
nm |
TEM |
The size distribution of SA-PtNPs determined from 100 random nanoparticles is shown in Supplementary Figure 2A with an average diameter of 5.9 ± 0.6 nm. |
|
|
|
|
3 |
|
|
|
8368 |
1361 |
R-MnCo2O4/Au NTs |
20 |
|
nm |
TEM |
文献里没写,自己量的 |
|
|
|
|
|
|
|
|
8369 |
1362 |
MSF nanostructures |
50 |
|
nm |
SEM |
average |
|
|
|
|
|
|
|
|
8370 |
1363 |
FePPOPEPA |
|
|
|
TEM |
没写 |
460.1 |
|
|
|
|
|
|
|
8371 |
1364 |
PPy@CoO/NiO NTs |
44.4 |
|
nm |
TEM |
thin wall thickness |
59.9 |
|
|
|
|
|
|
|
8372 |
1365 |
Fe3O4@C/Ni |
170-300 |
|
nm |
TEM |
The scanning electron microscopy (SEM) image in Figure 1B showed a highly uniform 1D smooth tubular morphology, which was 170–300 nm in diameter with a length of several micrometers. |
77.1 |
|
|
|
|
|
|
|
8373 |
1366 |
CeO2 NPs |
<10 |
|
nm |
TEM |
uniform |
|
|
|
|
|
|
|
|
8374 |
1366 |
Gd(OH)3 |
20 |
|
nm |
TEM |
with an average width of 20 nm and length of 150 nm |
|
|
|
|
|
|
|
|
8375 |
1366 |
Gd(OH)3 |
150 |
|
nm |
TEM |
with an average width of 20 nm and length of 150 nm |
|
|
|
|
|
|
|
|
8376 |
1367 |
AgNPs |
18-30 |
|
nm |
TEM |
Ag NPs |
|
|
|
|
|
|
|
|
8377 |
1368 |
Ag3PO4 |
2 |
|
μm |
SEM |
It can be clearly seen that the samples were composed of uniform microcubes with an average size of about 2 μm. |
16.91 |
|
|
|
|
|
|
|
8382 |
1371 |
RF Resin |
450 |
|
nm |
TEM |
The average particle size of RF from TEM was found to be ∼450 nm. |
|
|
|
|
|
|
|
|
8384 |
1373 |
PS@ Fe3 O4 |
124.3 |
9.6 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8385 |
1373 |
hellow Fe3 O4 |
123.6 |
7.5 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8386 |
1373 |
Fe3 O4 -PB |
127.3 |
11.4 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8383 |
1373 |
PS |
93.5 |
7.5 |
nm |
TEM |
|
|
|
|
|
|
|
|
|
8394 |
1378 |
PAA-Cnp |
10 |
|
nm |
TEM |
The scanning electron microscopy (SEM) images of the nanomaterials showed agglomerated particles, which upon sonication in acetone revealed a particle-like morphology (size ∼10 nm) in the transmission electron microscopy (TEM) images |
|
|
|
|
|
|
|
|
8396 |
1380 |
GI-Au NZ |
25 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8397 |
1382 |
Cu-MOP hydrogel |
20 |
|
nm |
SEM |
a typical fibrous morphology with a width of about 20 nm |
|
|
|
|
|
|
|
|
8398 |
1386 |
PDI/CeO2 NR |
|
|
nm |
TEM |
It can be observed that the morphology and size of PDI/CeO2 NR are similar to that of CeO2 NR with a less-uniform length within 30−250 nm and uniform diameter in 6.62−13.23 nm. |
|
|
|
|
|
|
|
|
8401 |
1389 |
Fe3O4@CuO |
|
|
|
|
|
45.8 |
|
|
|
|
|
|
|
8400 |
1389 |
Fe3O4@Cu/C |
|
|
|
|
|
112.1 |
|
|
|
|
|
|
|
8403 |
1391 |
Ag/PANI |
2 |
|
μm |
SEM |
相比之下Au/PANI纳米复合材料颗粒较大, 大多呈现棒状, 少量呈现椭圆状, 大小约在2 μm左右。 |
|
|
|
|
|
|
|
|
8410 |
1400 |
PBNPs |
73 |
|
nm |
SEM |
mean |
|
|
|
|
|
|
U/mg |
|
8409 |
1400 |
PBNPs |
68 |
|
nm |
TEM |
mean |
|
|
|
|
|
|
|
|
8411 |
1401 |
PEI/ZIF |
60 |
|
nm |
TEM |
the average thickness of the flakes |
|
|
|
|
|
|
|
|
8412 |
1402 |
Hb–Cu3(PO4)2 NFs |
15 |
|
μm |
SEM |
mean |
|
|
|
|
|
|
|
|
8414 |
1403 |
AuNP cores |
13 |
|
nm |
TEM |
|
|
|
|
|
|
|
|
|
8413 |
1403 |
Au@FeP |
56 |
|
nm |
TEM |
mean |
|
|
|
|
|
|
|
|
8415 |
1405 |
NF |
200-250 |
|
nm |
SEM |
average diameter |
|
|
|
|
|
|
|
|
8416 |
1406 |
P(VCL-co-NMAM) nanohydrogels |
983 |
|
nm |
TEM |
Average |
|
|
|
|
|
|
|
|
8417 |
1407 |
Fe3O4@C7 MNPs |
10.05 |
|
nm |
TEM |
average diameter |
|
|
|
|
|
|
|
|
8418 |
1408 |
Cu-MOF(3) |
220 |
|
nm |
DLS |
hydrodynamic diameter |
|
|
|
|
|
|
|
|
8420 |
1410 |
Fe3O4,CaO2@DMSN/C |
110 |
|
nm |
SEM |
average size |
|
|
|
|
|
|
|
|
8421 |
1411 |
CeGONRs |
44626 |
|
nm |
TEM |
By measuring 174 particles, the diameter was determined to range from 3 to 6 nm. |
267 |
|
|
|
|
|
|
|
8422 |
1412 |
BP QDs |
2.25 |
|
nm |
TEM |
Average |
|
|
|
|
|
|
|
|
8426 |
1418 |
SiO2 shell |
25 |
|
nm |
TEM |
Thickness |
|
|
|
|
|
|
|
|
8427 |
1418 |
Polymer shell |
8.5 |
|
nm |
DLS |
Thickness |
|
|
|
|
|
|
|
|
8425 |
1418 |
Fe3O4 NPs |
200 |
|
nm |
TEM |
average diameter |
|
|
|
|
|
|
|
|
8428 |
1421 |
Hemin@MI |
10 |
|
μm |
SEM |
|
|
|
|
|
|
|
|
|
8429 |
1422 |
Fe–N–S Co-Doped Porous Carbons |
2 |
|
μm |
|
All samples consisted of colloidal microparticles about ~2 µm in size (the image of the Fe- and N-co-doped carbon is shown as a representative example). |
|
|
|
|
|
|
|
|
8430 |
1423 |
Fe3O4 NPs |
12 |
|
nm |
TEM |
As shown in Fig. 1(b), irregular Fe3O4 NPs with an average size of 12 nm were observed. For Fe3O4@GO MNCs shown in Fig. 1(c), a large amount of Fe3O4 NPs were observed on sheet like GO. TEM images confirmed the successful assembly of Fe3O4 onto GO to form Fe3O4@GO MNCs. |
|
|
|
|
|
|
|
|
8432 |
1427 |
Cu-CuFe2O4 |
480 |
|
nm |
TEM |
For these nanosheets, the length is about 480 nm and the width is in the range of 28–55 nm, as shown in the inset. |
|
|
|
|
|
|
|
|
8437 |
1432 |
MIL-53(Fe) |
1 |
|
μm |
SEM |
The average |
|
|
|
|
|
|
|
|
8439 |
1434 |
Au-CDs |
4.3 |
0.4 |
nm |
TEM |
GNP@CDs were evenly dispersed with a uniform size and the diameter was about 4.3 ± 0.4 nm. |
|
|
|
|
|
|
|
|
8442 |
1439 |
GOx & AuNCs@ZIF-8) |
1 |
|
μm |
SEM |
The average |
|
|
|
|
|
|
|
|
8448 |
1443 |
hPBNCs |
80 |
|
nm |
TEM |
the cube-like hPBNCs were monodisperse with an average diameter of 80 nm |
|
|
|
|
|
|
|
|
8453 |
1454 |
MIL-47(V)-X |
|
|
|
TEM, SEM |
As shown in Figure S2 with different magnifications, the synthesized MOF particles are discrete with different sizes of 20–1000 nm. |
|
|
|
|
|
|
|
|