5941 |
48 |
Fe-NC nanozymes |
POD |
TMB |
|
|
14.9 |
|
-7 |
M |
6.2 |
|
-7 |
M/s |
|
|
|
|
48 |
|
|
48 |
5945 |
54 |
Fe3C/N–C |
POD |
TMB |
|
|
3.108 |
|
-2 |
mM |
3.463 |
|
-8 |
M/s |
|
|
|
|
54 |
|
|
54 |
5944 |
54 |
Fe3C/N–C |
POD |
H2O2 |
|
|
2.269 |
|
-4 |
mM |
1.924 |
|
-10 |
M/s |
|
|
|
|
54 |
|
|
54 |
5977 |
82 |
PNCNzyme |
POD |
TMB |
|
|
0.07915 |
|
|
mM |
22.82 |
|
-8 |
M/s |
|
|
|
|
82 |
|
|
82 |
5978 |
82 |
PNCNzyme |
POD |
H2O2 |
|
|
154.8 |
|
|
mM |
54.22 |
|
-8 |
M/s |
|
|
|
|
82 |
|
|
82 |
6006 |
128 |
BNS-CDs |
POD |
TMB |
|
|
0.435 |
|
|
mM |
9.467 |
|
-8 |
M/s |
|
|
|
|
128 |
|
|
|
6005 |
128 |
BNS-CDs |
POD |
H2O2 |
|
|
0.0233 |
|
|
mM |
1.255 |
|
-8 |
M/s |
|
|
|
|
128 |
|
|
|
6017 |
142 |
CDs |
Isomerase |
pDNA |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
142 |
|
|
|
6054 |
166 |
CB-CQDs |
POD |
H2O2 |
4.5 |
RT |
0.7 |
|
|
mM |
4.09 |
|
-8 |
M/s |
|
|
|
|
166 |
|
|
|
6055 |
166 |
CB-CQDs |
POD |
TMB |
4.5 |
RT |
0.83 |
|
|
mM |
5.13 |
|
-8 |
M/s |
|
|
|
|
166 |
|
|
166 |
6113 |
216 |
GO |
hydrolase |
DNA |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
216 |
|
|
|
6190 |
309 |
GDYO |
POD |
H2O2 |
|
|
2.59 |
|
|
mM |
1.06 |
|
|
μM/min |
|
|
|
|
309 |
|
|
|
6191 |
309 |
GDYO |
POD |
TMB |
|
|
0.62 |
|
|
mM |
1.15 |
|
|
μM/min |
|
|
|
|
309 |
|
|
309 |
6234 |
337 |
QG |
POD |
H2O2 |
|
|
0.12 |
|
|
mM |
4.96 |
|
-9 |
M/s |
|
|
|
|
337 |
|
|
|
6231 |
337 |
N-QG |
POD |
TMB |
|
|
0.51 |
|
|
mM |
18.21 |
|
-9 |
M/s |
|
|
|
|
337 |
|
|
|
6232 |
337 |
N-QG |
POD |
H2O2 |
|
|
0.069 |
|
|
mM |
6.54 |
|
-9 |
M/s |
|
|
|
|
337 |
|
|
337 |
6233 |
337 |
QG |
POD |
TMB |
|
|
0.38 |
|
|
mM |
4.39 |
|
-9 |
M/s |
|
|
|
|
337 |
|
|
|
6241 |
363 |
SNC |
POD |
H2O2 |
|
|
1.2 |
|
|
mM |
1.42 |
|
-6 |
M/s |
|
|
|
|
363 |
|
|
363 |
6242 |
364 |
Fe, N-CDs |
POD |
H2O2 |
|
|
0.207 |
|
|
mM |
7.487 |
|
-7 |
M/s |
|
|
|
|
364 |
|
|
364 |
6243 |
364 |
Fe, N-CDs |
POD |
TMB |
|
|
0.434 |
|
|
mM |
1 |
|
-7 |
M/s |
|
|
|
|
364 |
|
|
|
6257 |
377 |
A-PCM |
OXD |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
377 |
|
|
|
6260 |
379 |
EPC-900 |
POD |
TMB |
|
|
0.259 |
|
|
mM |
1.75 |
|
-8 |
mM/s |
|
|
|
|
379 |
|
|
|
6261 |
379 |
EPC-900 |
POD |
H2O2 |
|
|
0.012 |
|
|
mM |
3.33 |
|
-8 |
mM/s |
|
|
|
|
379 |
|
|
379 |
6262 |
379 |
EPC-900 |
OXD |
TMB |
|
|
0.106 |
|
|
mM |
5.1 |
|
-8 |
mM/s |
|
|
|
|
379 |
|
|
379 |
6369 |
506 |
Fe–N4 pero-nanozysome |
cascade reaction |
UA |
8.0 |
25 |
16.64 |
|
|
μM |
1.36 |
|
-3 |
μM/min |
|
|
|
|
506 |
|
|
506 |
6370 |
506 |
Fe–N4 pero-nanozysome |
POD |
H2O2 |
4.5 |
37 |
175.5 |
|
|
mM |
567.9 |
|
|
nM/s |
|
|
|
|
506 |
|
|
pero-nanozysome exhibited higher enzymatic activity as evaluated by the values for KM and Vmax (Table S5, Supporting Information). |
6371 |
506 |
Fe–N4 pero-nanozysome |
POD |
TMB |
4.5 |
37 |
0.18 |
|
|
mM |
299.8 |
|
|
nM/s |
|
|
|
|
506 |
|
|
pero-nanozysome exhibited higher enzymatic activity as evaluated by the values for KM and Vmax (Table S5, Supporting Information). |
6372 |
506 |
Fe–N4 pero-nanozysome |
OXD |
TMB |
4.5 |
37 |
0.55 |
|
|
mM |
45.27 |
|
|
nM/s |
|
|
|
|
506 |
|
|
In addition, pero-nanozysome also possessed higher catalytic efficiency than that of N-nanozyme (Figure 3e and Table S6, Supporting Information). |
6373 |
506 |
Fe–N4 pero-nanozysome (单位无法填写) |
CAT |
H2O2 |
7.0 |
RT |
0.09 |
|
|
M |
2.34 |
|
|
|
|
|
|
|
506 |
|
|
The KM value of pero-nanozysome was about four times lower than that of N-nanozyme (Table S3, Supporting Information), |
6414 |
545 |
NSP-CQDs |
POD |
H2O2 |
|
|
32.61 |
|
|
mM |
6950.68 |
|
-8 |
M/s |
|
|
|
|
545 |
|
|
545 |
6415 |
545 |
NSP-CQDs |
POD |
TMB |
|
|
0.47 |
|
|
mM |
18.81 |
|
-8 |
M/s |
|
|
|
|
545 |
|
|
545 |
6450 |
571 |
N/Cl-CDs |
POD |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
571 |
|
|
571 |
6463 |
581 |
Fe–N–C |
POD |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
581 |
|
|
581 |
6544 |
662 |
g-C3N4 |
POD |
|
|
|
0.159 |
|
|
mM |
1.3 |
|
-8 |
M/s |
|
|
|
|
662 |
|
|
|
6545 |
663 |
S-rGO |
POD |
TMB |
4.0 |
45 |
0.374 |
|
|
mM |
2.89 |
|
-8 |
M/s |
|
|
|
|
663 |
|
|
|
6546 |
663 |
S-rGO |
POD |
H2O2 |
4.0 |
45 |
0.594 |
|
|
mM |
9.42 |
|
-8 |
M/s |
|
|
|
|
663 |
|
|
|
6548 |
665 |
GO-UO22+ NPs |
POD |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
665 |
|
|
|
6556 |
669 |
GNR |
POD |
H2O2 |
4.0 |
35 |
3.52 |
|
|
mM |
3.09 |
|
-8 |
M/s |
|
|
|
|
669 |
|
|
|
6555 |
669 |
GNR |
POD |
TMB |
4.0 |
35 |
0.42 |
|
|
mM |
1.58 |
|
-8 |
M/s |
|
|
|
|
669 |
|
|
|
6569 |
675 |
AIronNPs+AMF |
POD |
H2O2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
675 |
|
|
|
6570 |
675 |
AIronNPs |
POD |
H2O2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
675 |
|
|
|
6573 |
678 |
g-C3N4 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
678 |
|
|
|
6771 |
872 |
OAC |
SOD |
OAC |
|
|
12.7 |
|
|
mM |
|
|
|
|
1.7 |
|
-5 |
1/s |
872 |
|
|
|
6767 |
873 |
H-GNs |
OXD |
H2O2 |
|
|
1.25 |
|
|
mM |
16.7 |
|
-8 |
M/s |
|
|
|
|
873 |
|
|
|
6772 |
873 |
H-GNs |
OXD |
TMB |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
873 |
|
|
|
6795 |
887 |
PEI-600-Fe C-dots |
POD |
H2O2 |
4.55 |
RT |
0.02827 |
0.00873 |
|
mM |
36.3782 |
5.24999 |
|
M/s |
|
|
|
|
887 |
|
|
|
6818 |
913 |
Cu-HCSs |
multi-functionalities |
DNA /proteins |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
913 |
|
|
|
6833 |
930 |
CQDs |
POD |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
930 |
|
|
|
6865 |
963 |
N@GQDs |
POD |
H2O2 |
6.5 |
RT |
5.25 |
|
|
mM |
|
|
|
|
|
|
|
|
963 |
|
|
|
6876 |
974 |
GQD |
POD |
TMB |
|
|
4.175 |
|
-2 |
mM |
13.55 |
|
-8 |
M/s |
|
|
|
|
974 |
|
|
|
7009 |
1060 |
LSG |
OXD |
HX |
|
|
58.52 |
|
|
μM |
|
|
|
|
|
|
|
|
1060 |
|
|
1060 |
7010 |
1060 |
LSG |
OXD |
XT |
|
|
72.49 |
|
|
μM |
|
|
|
|
|
|
|
|
1060 |
|
|
1060 |
7011 |
1060 |
LSG |
OXD |
HX |
|
|
66.84 |
|
|
μM |
|
|
|
|
|
|
|
|
1060 |
|
|
1060 |
7012 |
1060 |
LSG |
OXD |
XT |
|
|
81.35 |
|
|
μM |
|
|
|
|
|
|
|
|
1060 |
|
|
原文数据即有两个小数点,存疑 |
7093 |
1126 |
g-CNQDs |
POD |
H2O2 |
|
|
10.788 |
|
|
mM |
1.717 |
|
-8 |
M/s |
|
|
|
|
1126 |
|
|
|
7094 |
1126 |
g-CNQDs |
POD |
TMB |
|
|
0.079 |
|
|
mM |
1.461 |
|
-8 |
M/s |
|
|
|
|
1126 |
|
|
|
7156 |
1214 |
Cu2+-HCNSs-COOH |
POD |
H2O2 |
|
|
0.88 |
|
|
mM |
|
|
|
|
|
|
|
|
1214 |
|
|
|
7157 |
1216 |
g-C3N4 + Fe(III)+ Cu(II) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
1216 |
|
|
|
7179 |
1243 |
carbon polymer hollow spheres (CPHSs) |
POD |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
1243 |
|
|
|
7203 |
1284 |
CQDs |
POD |
TMB |
|
|
0.6 |
|
|
mM |
2.15 |
|
-8 |
nM/s |
|
|
|
1/s |
1284 |
|
M-1 s-1 |
1284 |
7204 |
1284 |
CQDs |
POD |
H2O2 |
|
|
0.16 |
|
|
mM |
4.38 |
|
-8 |
nM/s |
|
|
|
1/s |
1284 |
|
M-1 s-1 |
1284 |
7235 |
1325 |
GOQD-MPS |
POD |
H2O2 |
|
|
1.7 |
|
|
mM |
7.5 |
|
-7 |
M/s |
|
|
|
|
1325 |
|
|
1325 |
7236 |
1325 |
GOQD |
POD |
H2O2 |
|
|
0.61 |
|
|
mM |
6.8 |
|
-9 |
M/s |
|
|
|
|
1325 |
|
|
1325 |
7282 |
1369 |
fNP C |
POD |
|
|
|
10.49 |
|
|
mM |
17.25 |
|
-4 |
μM/min |
|
|
|
|
1369 |
|
|
1369 |
7283 |
1369 |
fNP B |
POD |
|
|
|
7.01 |
|
|
mM |
22.62 |
|
-4 |
μM/min |
|
|
|
|
1369 |
|
|
1369 |
7309 |
1399 |
CeCDs |
hydrolase |
BNPP |
|
|
8.66 |
|
-4 |
M |
1.58 |
|
-4 |
M/s |
2.00 |
|
-3 |
1/min |
1399 |
|
|
1399 |